Stabilizing a Vanadium Oxide Catalyst by Supporting on a Metal-Organic Framework

Cui, Yuexing; Rimoldi, Martino; Platero-Prats, Ana E.; Chapman, Karena W.; Hupp, Joseph T.; Farha, Omar K.

doi:10.1002/cctc.201701658

Title: Stabilizing a Vanadium Oxide Catalyst by Supporting on a Metal-Organic Framework

Journal Article · Mon Nov 20 00:00:00 EST 2017 · ChemCatChem

DOI:https://doi.org/10.1002/cctc.201701658· OSTI ID:1470250

Cui, Yuexing ^[1]; Rimoldi, Martino ^[1]; Platero-Prats, Ana E. ^[2]; Chapman, Karena W. ^[2]; Hupp, Joseph T. ^[1];

^[3]

Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)

Abstract NU‐1000 is a robust and highly porous Zr‐based metal–organic framework (Zr‐MOFs) that has been proven to be an excellent catalyst support because of its well‐defined crystal structure, protonic grafting sites on its nodes, and thermal stability, all of which advantageously offer the possibility to study the nature of the catalytic reactive sites. Herein, we present a vanadium‐oxide catalyst supported on NU‐1000 synthesized by solvothermal deposition in MOFs (SIM), namely, V‐NU‐1000. The catalytic activity of V‐NU‐1000 was investigated by studying the oxidation of 4‐methoxybenzyl alcohol under an O ₂ atmosphere; this catalyst showed higher conversion and higher selectivity than vanadium‐oxide supported on high‐surface‐area zirconia (V‐ZrO ₂ ). The stability of V‐NU‐1000 was confirmed by recyclability and leaching tests, in which recycled V‐NU‐1000 had catalytic ability comparable to that of the fresh catalyst, and no loss in the metal loading was found in recollected V‐NU‐1000.

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Research Organization:: Univ. of Minnesota, Minneapolis, MN (United States). Energy Frontier Research Center (EFRC) Inorganometallic Catalyst Design (ICDC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012702; AC0206CH11357

OSTI ID:: 1470250

Alternate ID(s):: OSTI ID: 1419597

Journal Information:: ChemCatChem, Vol. 10, Issue 8; Related Information: ICDC partners with University of Minnesota(lead); Argonne National Laboratory; Clemson University; Dow Chemical Company; Northwestern University; Pacific Northwest National Laboratory; University of California Davis; University of Washington; ISSN 1867-3880

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
heterogeneous catalysis
metal–organic frameworks
oxidation
vanadium
zirconium

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