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Title: Stabilizing a Vanadium Oxide Catalyst by Supporting on a Metal-Organic Framework

Abstract

Abstract NU‐1000 is a robust and highly porous Zr‐based metal–organic framework (Zr‐MOFs) that has been proven to be an excellent catalyst support because of its well‐defined crystal structure, protonic grafting sites on its nodes, and thermal stability, all of which advantageously offer the possibility to study the nature of the catalytic reactive sites. Herein, we present a vanadium‐oxide catalyst supported on NU‐1000 synthesized by solvothermal deposition in MOFs (SIM), namely, V‐NU‐1000. The catalytic activity of V‐NU‐1000 was investigated by studying the oxidation of 4‐methoxybenzyl alcohol under an O 2 atmosphere; this catalyst showed higher conversion and higher selectivity than vanadium‐oxide supported on high‐surface‐area zirconia (V‐ZrO 2 ). The stability of V‐NU‐1000 was confirmed by recyclability and leaching tests, in which recycled V‐NU‐1000 had catalytic ability comparable to that of the fresh catalyst, and no loss in the metal loading was found in recollected V‐NU‐1000.

Authors:
 [1];  [1];  [2];  [2];  [1]; ORCiD logo [3]
  1. Northwestern Univ., Evanston, IL (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)
Publication Date:
Research Org.:
Univ. of Minnesota, Minneapolis, MN (United States). Energy Frontier Research Center (EFRC) Inorganometallic Catalyst Design (ICDC)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1470250
Alternate Identifier(s):
OSTI ID: 1419597
Grant/Contract Number:  
SC0012702; AC0206CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemCatChem
Additional Journal Information:
Journal Volume: 10; Journal Issue: 8; Related Information: ICDC partners with University of Minnesota(lead); Argonne National Laboratory; Clemson University; Dow Chemical Company; Northwestern University; Pacific Northwest National Laboratory; University of California Davis; University of Washington; Journal ID: ISSN 1867-3880
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; heterogeneous catalysis; metal–organic frameworks; oxidation; vanadium; zirconium

Citation Formats

Cui, Yuexing, Rimoldi, Martino, Platero-Prats, Ana E., Chapman, Karena W., Hupp, Joseph T., and Farha, Omar K. Stabilizing a Vanadium Oxide Catalyst by Supporting on a Metal-Organic Framework. United States: N. p., 2017. Web. doi:10.1002/cctc.201701658.
Cui, Yuexing, Rimoldi, Martino, Platero-Prats, Ana E., Chapman, Karena W., Hupp, Joseph T., & Farha, Omar K. Stabilizing a Vanadium Oxide Catalyst by Supporting on a Metal-Organic Framework. United States. https://doi.org/10.1002/cctc.201701658
Cui, Yuexing, Rimoldi, Martino, Platero-Prats, Ana E., Chapman, Karena W., Hupp, Joseph T., and Farha, Omar K. 2017. "Stabilizing a Vanadium Oxide Catalyst by Supporting on a Metal-Organic Framework". United States. https://doi.org/10.1002/cctc.201701658. https://www.osti.gov/servlets/purl/1470250.
@article{osti_1470250,
title = {Stabilizing a Vanadium Oxide Catalyst by Supporting on a Metal-Organic Framework},
author = {Cui, Yuexing and Rimoldi, Martino and Platero-Prats, Ana E. and Chapman, Karena W. and Hupp, Joseph T. and Farha, Omar K.},
abstractNote = {Abstract NU‐1000 is a robust and highly porous Zr‐based metal–organic framework (Zr‐MOFs) that has been proven to be an excellent catalyst support because of its well‐defined crystal structure, protonic grafting sites on its nodes, and thermal stability, all of which advantageously offer the possibility to study the nature of the catalytic reactive sites. Herein, we present a vanadium‐oxide catalyst supported on NU‐1000 synthesized by solvothermal deposition in MOFs (SIM), namely, V‐NU‐1000. The catalytic activity of V‐NU‐1000 was investigated by studying the oxidation of 4‐methoxybenzyl alcohol under an O 2 atmosphere; this catalyst showed higher conversion and higher selectivity than vanadium‐oxide supported on high‐surface‐area zirconia (V‐ZrO 2 ). The stability of V‐NU‐1000 was confirmed by recyclability and leaching tests, in which recycled V‐NU‐1000 had catalytic ability comparable to that of the fresh catalyst, and no loss in the metal loading was found in recollected V‐NU‐1000.},
doi = {10.1002/cctc.201701658},
url = {https://www.osti.gov/biblio/1470250}, journal = {ChemCatChem},
issn = {1867-3880},
number = 8,
volume = 10,
place = {United States},
year = {Mon Nov 20 00:00:00 EST 2017},
month = {Mon Nov 20 00:00:00 EST 2017}
}

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Works referenced in this record:

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Works referencing / citing this record:

The effects of active site and support on hydrogen elimination over transition-metal-functionalized yttria-decorated metal–organic frameworks
journal, January 2019


Metal–Organic Framework Hybrid Materials and Their Applications
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