Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release

Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian; Bi, Xuanxuan; Lu, Jun; Bak, Seongmin; Nam, Kyung-Wan; Xin, Huolin L.; Jaye, Cherno; Fischer, Daniel A.; Amine, Kahlil; Yang, Xiao-Qing

doi:10.1038/s41560-018-0207-z

Title: Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release

Journal Article · Mon Jul 30 00:00:00 EDT 2018 · Nature Energy

DOI:https://doi.org/10.1038/s41560-018-0207-z· OSTI ID:1467843

^[1];

^[2]; Lin, Ruoqian ^[3]; Bi, Xuanxuan ^[4];

^[4]; Bak, Seongmin ^[1];

^[5];

^[6]; Jaye, Cherno ^[7]; Fischer, Daniel A. ^[7]; Amine, Kahlil ^[4]; Yang, Xiao-Qing ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division; Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics and Inst. of Physics
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division and Center for Functional Nanomaterials (CFN)
Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
Dongguk Univ., Seoul (Korea, Republic of). Dept. of Energy and Materials Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Material Measurement Lab.

Here, voltage fade is a major problem in battery applications for high-energy Lithium- and Manganese-rich (LMR) layered materials. Because of the complexity in the LMR structure, the voltage fade mechanism is not well understood. Here we conduct in situ and ex situ studies on a typical LMR material (Li_1.2Ni_0.15Co_0.1Mn_0.55O₂) during charge-discharge cycling, using multi-length-scale X-ray spectroscopic and 3D electron microscopic imaging techniques. Through probing from surface to bulk, from individual to the whole ensembles of particles, we show that the average valence states of each type of transition metal cations are continuously reduced, which is attributed to the oxygen release from LMR.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES); Chinese Academy of Sciences (CAS); National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC); National Research Foundation of Korea (NRF)

Grant/Contract Number:: AC02-06CH11357; SC0012704; 2016YFA0202500; 51421002; NRF-2017M1A2A2044502; AC02-98CH10886

OSTI ID:: 1467843

Alternate ID(s):: OSTI ID: 1460715

Report Number(s):: BNL-207813-2018-JAAM; 144252

Journal Information:: Nature Energy, Vol. 3, Issue 8; ISSN 2058-7546

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 552 works

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Enhanced Electrochemical Properties of LiNi _0.8 Co _0.1 Mn _0.1 O ₂ at Elevated Temperature by Simultaneous Structure and Interface Regulating Feng, Ze; Huang, Xiaobing; Rajagopalan, Ranjusha Journal of The Electrochemical Society, Vol. 166, Issue 8 https://doi.org/10.1149/2.0331908jes	journal	January 2019
Unveiling the Effect of Voltage Regulation System on the Structure and Electrochemical Properties of Lithium-Rich Cathode Materials Yang, Zhe; Zhong, Jianjian; Liu, Yanying Journal of The Electrochemical Society, Vol. 166, Issue 8 https://doi.org/10.1149/2.0371908jes	journal	January 2019
Slightly Fluorination of Al ₂ O ₃ ALD Coating on Li _1.2 Mn _0.54 Co _0.13 Ni _0.13 O ₂ Electrodes: Interface Reaction to Create Stable Solid Permeable Interphase Layer Yu, Han; Gao, Yan; Liang, Xinhua Journal of The Electrochemical Society, Vol. 166, Issue 10 https://doi.org/10.1149/2.0951910jes	journal	January 2019
High-Performance Lithium-Rich Layered Oxide Material: Effects of Preparation Methods on Microstructure and Electrochemical Properties Liu, Qiming; Zhu, Huali; Liu, Jun Materials, Vol. 13, Issue 2 https://doi.org/10.3390/ma13020334	journal	January 2020
Stabilizing the Oxygen Lattice and Reversible Oxygen Redox Chemistry through Structural Dimensionality in Lithium‐Rich Cathode Oxides Zhao, Enyue; Li, Qinghao; Meng, Fanqi Angewandte Chemie, Vol. 131, Issue 13 https://doi.org/10.1002/ange.201900444	journal	February 2019
Structural insights into the formation and voltage degradation of lithium- and manganese-rich layered oxides. Hua, Weibo; Wang, Suning; Knapp, Michael Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.47412	text	January 2019
Structural insights into the formation and voltage degradation of lithium- and manganese-rich layered oxides Hua, Weibo; Wang, Suning; Knapp, Michael Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2019-04472	text	January 2019
Structural insights into the formation and voltage degradation of lithium- and manganese-rich layered oxides Hua, Weibo; Wang, Suning; Knapp, Michael Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.60446	text	January 2019
Surface Chemistry Dependence on Aluminum Doping in Ni-rich LiNi0.8Co0.2-yAlyO2 Cathodes. Lebens-Higgins, Zachary W.; Halat, David M.; Faenza, Nicholas V. Springer Science and Business Media LLC https://doi.org/10.17863/cam.48738	journalarticle	January 2019
Enhanced Cycling Stability of Cation Disordered Rock-Salt Li1.2Ti0.4Mn0.4O2 Material by Surface Modification With Al2O3 Huang, Baojun; Wang, Rui; Gong, Yansheng Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00107	journal	March 2019

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