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Title: An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/C8EE01085D· OSTI ID:1464284
ORCiD logo [1];  [2];  [3]; ORCiD logo [4];  [5];  [6];  [7]; ORCiD logo [8];  [6]; ORCiD logo [9];  [10];  [5]; ORCiD logo [11]; ORCiD logo [8];  [12]; ORCiD logo [5];  [13]; ORCiD logo [4]; ORCiD logo [1]; ORCiD logo [14] more »; ORCiD logo [12]; ORCiD logo [13] « less
  1. Energy & Transport Technology Center, Sandia National Laboratories, Livermore, USA
  2. Fuel Cell Technologies Office, U.S. Department of Energy Office of Energy Efficiency and Renewable Energy, Washington, USA, Oak Ridge Institute for Science and Education
  3. Department of Chemistry, Colorado School of Mines, Golden, USA, National Renewable Energy Laboratory
  4. Mechanical Engineering Department, University of Michigan, Ann Arbor, USA
  5. Pacific Northwest National Laboratory, Richland, USA
  6. Computational Research Division, Lawrence Berkeley National Laboratory, Berkeley, USA
  7. Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), Korea
  8. Department of Chemistry, University of California, Berkeley, USA, Materials Sciences Division
  9. Department of Chemistry, University of California, Berkeley, USA, Chemical Sciences Division
  10. Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Molecular Foundry
  11. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, USA
  12. Department of Chemistry, University of California, Berkeley, USA
  13. Lawrence Livermore National Laboratory, Livermore, USA
  14. Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, USA
+ Show Author Affiliations

Here, nanoporous adsorbents are a diverse category of solid-state materials that hold considerable promise for vehicular hydrogen storage. Although impressive storage capacities have been demonstrated for several materials, particularly at cryogenic temperatures, materials meeting all of the targets established by the U.S. Department of Energy have yet to be identified. In this Perspective, we provide an overview of the major known and proposed strategies for hydrogen adsorbents, with the aim of guiding ongoing research as well as future new storage concepts. The discussion of each strategy includes current relevant literature, strengths and weaknesses, and outstanding challenges that preclude implementation. We consider in particular metal–organic frameworks (MOFs), including surface area/volume tailoring, open metal sites, and the binding of multiple H2 molecules to a single metal site. Two related classes of porous framework materials, covalent organic frameworks (COFs) and porous aromatic frameworks (PAFs), are also discussed, as are graphene and graphene oxide and doped porous carbons. We additionally introduce criteria for evaluating the merits of a particular materials design strategy. Computation has become an important tool in the discovery of new storage materials, and a brief introduction to the benefits and limitations of computational predictions of H2 physisorption is therefore presented. Finally, considerations for the synthesis and characterization of hydrogen storage adsorbents are discussed.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Argonne National Laboratory (ANL), Argonne, IL (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office (HFTO)
Grant/Contract Number:
AC05-76RL01830; AC04-94AL85000; AC36-08-GO28308; AC02-05CH11231; AC52-07NA27344; EE0007046; EE0008093; AC02-06CH11357; AC3608GO28308
OSTI ID:
1464284
Alternate ID(s):
OSTI ID: 1467459; OSTI ID: 1487123; OSTI ID: 1489439; OSTI ID: 1491362; OSTI ID: 1491718; OSTI ID: 1507292
Report Number(s):
SAND-2018-4538J; LLNL-JRNL-755042; PNNL-SA-132915; NREL/JA-5900-73671; EESNBY
Journal Information:
Energy & Environmental Science, Journal Name: Energy & Environmental Science Vol. 11 Journal Issue: 10; ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 128 works
Citation information provided by
Web of Science

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6,6′-(Perfluoropropane-2,2-diyl)bis(2,3-dihydrophthalazine-1,4-dione)-based coordination polymers and their sensing properties towards Cr 2 O 7 2− journal January 2019
Optimization of the Pore Structures of MOFs for Record High Hydrogen Volumetric Working Capacity journal March 2020
Balancing volumetric and gravimetric uptake in highly porous materials for clean energy journal April 2020
Complex Hydrides for Energy Storage, Conversion, and Utilization journal July 2019
Design Rules for Metal‐Organic Framework Stability in High‐Pressure Hydrogen Environments journal March 2019
Molecular modelling and machine learning for high-throughput screening of metal-organic frameworks for hydrogen storage journal April 2019
Highly Porous Organic Polymers for Hydrogen Fuel Storage journal April 2019

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