Fundamentals of hydrogen storage in nanoporous materials

Zhang, Linda; Allendorf, Mark D.; Balderas-Xicohténcatl, Rafael; Broom, Darren P.; Fanourgakis, George S.; Froudakis, George E.; Gennett, Thomas; Hurst, Katherine E.; Ling, Sanliang; Milanese, Chiara; Parilla, Philip A.; Pontiroli, Daniele; Riccò, Mauro; Shulda, Sarah; Stavila, Vitalie; Steriotis, Theodore A.; Webb, Colin J.; Witman, Matthew; Hirscher, Michael

doi:10.1088/2516-1083/ac8d44

Fundamentals of hydrogen storage in nanoporous materials

Journal Article · Wed Sep 14 00:00:00 EDT 2022 · Progress in Energy

DOI:https://doi.org/10.1088/2516-1083/ac8d44· OSTI ID:1887302

; ; ; ; ; ; ; ; ; ; ; Pontiroli, Daniele; Riccò, Mauro; ; ; ; ; ;

Abstract

Physisorption of hydrogen in nanoporous materials offers an efficient and competitive alternative for hydrogen storage. At low temperatures (e.g. 77 K) and moderate pressures (below 100 bar) molecular H ₂ adsorbs reversibly, with very fast kinetics, at high density on the inner surfaces of materials such as zeolites, activated carbons and metal–organic frameworks (MOFs). This review, by experts of Task 40 ‘Energy Storage and Conversion based on Hydrogen’ of the Hydrogen Technology Collaboration Programme of the International Energy Agency, covers the fundamentals of H ₂ adsorption in nanoporous materials and assessment of their storage performance. The discussion includes recent work on H ₂ adsorption at both low temperature and high pressure, new findings on the assessment of the hydrogen storage performance of materials, the correlation of volumetric and gravimetric H ₂ storage capacities, usable capacity, and optimum operating temperature. The application of neutron scattering as an ideal tool for characterising H ₂ adsorption is summarised and state-of-the-art computational methods, such as machine learning, are considered for the discovery of new MOFs for H ₂ storage applications, as well as the modelling of flexible porous networks for optimised H ₂ delivery. The discussion focuses moreover on additional important issues, such as sustainable materials synthesis and improved reproducibility of experimental H ₂ adsorption isotherm data by interlaboratory exercises and reference materials.

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Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003525; AC36-08GO28308; AC36-08GO28308; AC05-00OR22725

OSTI ID:: 1887302

Alternate ID(s):: OSTI ID: 1883630
OSTI ID: 1887391
OSTI ID: 1901942

Journal Information:: Progress in Energy, Journal Name: Progress in Energy Journal Issue: 4 Vol. 4; ISSN 2516-1083

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (158)

MFU-4 - A Metal-Organic Framework for Highly Effective H ₂ /D ₂ Separation Teufel, Julia; Oh, Hyunchul; Hirscher, Michael Advanced Materials, Vol. 25, Issue 4 https://doi.org/10.1002/adma.201203383	journal	November 2012
High-resolution adsorption isotherms of supercritical carbon dioxide on activated carbon Humayun, Raashina; Tomasko, David L. AIChE Journal, Vol. 46, Issue 10 https://doi.org/10.1002/aic.690461017	journal	October 2000
Measurement of gibbsian surface excess Sircar, S. AIChE Journal, Vol. 47, Issue 5 https://doi.org/10.1002/aic.690470522	journal	May 2001
Functional Porous Coordination Polymers Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375 https://doi.org/10.1002/anie.200300610	journal	April 2004
Chemical and Physical Solutions for Hydrogen Storage Eberle, Ulrich; Felderhoff, Michael; Schüth, Ferdi Angewandte Chemie International Edition, Vol. 48, Issue 36 https://doi.org/10.1002/anie.200806293	journal	August 2009
Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena Angewandte Chemie International Edition, Vol. 53, Issue 23 https://doi.org/10.1002/anie.201310004	journal	May 2014
Physical Adsorption Characterization of Nanoporous Materials Thommes, M. Chemie Ingenieur Technik, Vol. 82, Issue 7 https://doi.org/10.1002/cite.201000064	journal	June 2010
Heat of Adsorption for Hydrogen in Microporous High-Surface-Area Materials Schmitz, Barbara; Müller, Ulrich; Trukhan, Natalia ChemPhysChem, Vol. 9, Issue 15 https://doi.org/10.1002/cphc.200800463	journal	October 2008
An International Laboratory Comparison Study of Volumetric and Gravimetric Hydrogen Adsorption Measurements Hurst, Katherine E.; Gennett, Thomas; Adams, Jesse ChemPhysChem, Vol. 20, Issue 15 https://doi.org/10.1002/cphc.201900166	journal	June 2019
Improving Reproducibility in Hydrogen Storage Material Research Broom, Darren P.; Hirscher, Michael ChemPhysChem, Vol. 22, Issue 21 https://doi.org/10.1002/cphc.202100508	journal	August 2021
High Volumetric Hydrogen Storage Capacity using Interpenetrated Metal-Organic Frameworks Balderas-Xicohténcatl, Rafael; Schmieder, Phillip; Denysenko, Dmytro Energy Technology, Vol. 6, Issue 3 https://doi.org/10.1002/ente.201700608	journal	December 2017
Volumetric Hydrogen Storage Capacity in Metal-Organic Frameworks Balderas-Xicohténcatl, R.; Schlichtenmayer, Maurice; Hirscher, Michael Energy Technology, Vol. 6, Issue 3 https://doi.org/10.1002/ente.201700636	journal	December 2017
Perturbation for a rigid rotator in an electric field Requena, A.; Peña, R.; Serna, A. International Journal of Quantum Chemistry, Vol. 22, Issue 6 https://doi.org/10.1002/qua.560220609	journal	December 1982
Adsorption of hydrogen on porous Vycor glass Huber, T. E.; Huber, C. A. Journal of Low Temperature Physics, Vol. 80, Issue 5-6 https://doi.org/10.1007/BF00683637	journal	September 1990
Density of He adsorbed in micropores at 4.2K Setoyama, N.; Kaneko, K. Adsorption, Vol. 1, Issue 2 https://doi.org/10.1007/BF00705003	journal	January 1995
Zur Theorie und Systematik der Molekularkr�fte London, F. Zeitschrift f�r Physik, Vol. 63, Issue 3-4 https://doi.org/10.1007/BF01421741	journal	March 1930
Model for the hydrogen adsorption on carbon nanostructures Züttel, A.; Sudan, P.; Mauron, P. Applied Physics A, Vol. 78, Issue 7 https://doi.org/10.1007/s00339-003-2412-1	journal	April 2004
Isosteric heat of hydrogen adsorption on MOFs: comparison between adsorption calorimetry, sorption isosteric method, and analytical models Kloutse, A. F.; Zacharia, R.; Cossement, D. Applied Physics A, Vol. 121, Issue 4 https://doi.org/10.1007/s00339-015-9484-6	journal	September 2015
An international multi-laboratory investigation of carbon-based hydrogen sorbent materials Hurst, Katherine E.; Parilla, Philip A.; O’Neill, Kevin J. Applied Physics A, Vol. 122, Issue 1 https://doi.org/10.1007/s00339-015-9537-x	journal	January 2016
Outlook and challenges for hydrogen storage in nanoporous materials Broom, D. P.; Webb, C. J.; Hurst, K. E. Applied Physics A, Vol. 122, Issue 3 https://doi.org/10.1007/s00339-016-9651-4	journal	February 2016
Recommended volumetric capacity definitions and protocols for accurate, standardized and unambiguous metrics for hydrogen storage materials Parilla, Philip A.; Gross, Karl; Hurst, Katherine Applied Physics A, Vol. 122, Issue 3 https://doi.org/10.1007/s00339-016-9654-1	journal	February 2016
The usable capacity of porous materials for hydrogen storage Schlichtenmayer, Maurice; Hirscher, Michael Applied Physics A, Vol. 122, Issue 4 https://doi.org/10.1007/s00339-016-9864-6	journal	March 2016
Hydrogen adsorption on microporous materials at ambient temperatures and pressures up to 50 MPa Voskuilen, Tyler G.; Pourpoint, Timothée L.; Dailly, Anne M. Adsorption, Vol. 18, Issue 3-4 https://doi.org/10.1007/s10450-012-9397-z	journal	August 2012
Physical adsorption of gases: the case for absolute adsorption as the basis for thermodynamic analysis Myers, Alan L.; Monson, Peter A. Adsorption, Vol. 20, Issue 4 https://doi.org/10.1007/s10450-014-9604-1	journal	March 2014
A reference high-pressure CO2 adsorption isotherm for ammonium ZSM-5 zeolite: results of an interlaboratory study Nguyen, H. G. T.; Espinal, L.; van Zee, R. D. Adsorption, Vol. 24, Issue 6 https://doi.org/10.1007/s10450-018-9958-x	journal	July 2018
A reference high-pressure CH4 adsorption isotherm for zeolite Y: results of an interlaboratory study Nguyen, H. G. T.; Sims, C. M.; Toman, B. Adsorption, Vol. 26, Issue 8 https://doi.org/10.1007/s10450-020-00253-0	journal	September 2020
Extracting adsorbate information from manometric uptake measurements of hydrogen at high pressure and ambient temperature Naheed, L.; Lamb, K. E.; Gray, E. MacA. Adsorption, Vol. 27, Issue 8 https://doi.org/10.1007/s10450-020-00289-2	journal	January 2021
Extremely randomized trees Geurts, Pierre; Ernst, Damien; Wehenkel, Louis Machine Learning, Vol. 63, Issue 1 https://doi.org/10.1007/s10994-006-6226-1	journal	March 2006
Investigation of the optimum conditions for adsorptive hydrogen storage Glante, Stephan; Fischer, Marcus; Hartmann, Martin Emergent Materials, Vol. 4, Issue 5 https://doi.org/10.1007/s42247-021-00258-7	journal	July 2021
Virial-type thermal equation of gas—solid adsorption Czepirski, Leszek; JagieŁŁo, Jacek Chemical Engineering Science, Vol. 44, Issue 4, p. 797-801 https://doi.org/10.1016/0009-2509(89)85253-4	journal	January 1989
Molecular transport in subnanometer pores: zero-point energy, reduced dimensionality and quantum sieving Beenakker, J. J. M.; Borman, V. D.; Krylov, S. Yu. Chemical Physics Letters, Vol. 232, Issue 4 https://doi.org/10.1016/0009-2614(94)01372-3	journal	January 1995
Interaction of hydrogen with solid surfaces Christmann, K. Surface Science Reports, Vol. 9, Issue 1-3 https://doi.org/10.1016/0167-5729(88)90009-X	journal	July 1988
Absolute scale determination for photoabsorption spectra and the calculation of molecular properties using dipole sum-rules Olney, Terry N.; Cann, N. M.; Cooper, Glyn Chemical Physics, Vol. 223, Issue 1 https://doi.org/10.1016/S0301-0104(97)00145-6	journal	October 1997
Hydrogen adsorption in zeolites A, X, Y and RHO Langmi, H. W.; Walton, A.; Al-Mamouri, M. M. Journal of Alloys and Compounds, Vol. 356-357 https://doi.org/10.1016/S0925-8388(03)00368-2	journal	August 2003
Materials for hydrogen storage Züttel, Andreas Materials Today, Vol. 6, Issue 9 https://doi.org/10.1016/S1369-7021(03)00922-2	journal	September 2003
Preparation and gas storage of high surface area microporous carbon derived from biomass source cornstalks Zhang, Feng; Ma, Hua; Chen, Jun Bioresource Technology, Vol. 99, Issue 11 https://doi.org/10.1016/j.biortech.2007.09.052	journal	July 2008
The rotational and translational dynamics of molecular hydrogen physisorbed in activated carbon: A direct probe of microporosity and hydrogen storage performance Georgiev, P. A.; Ross, D. K.; Albers, P. Carbon, Vol. 44, Issue 13 https://doi.org/10.1016/j.carbon.2006.04.023	journal	November 2006
Interpenetration control in metal–organic frameworks for functional applications Jiang, Hai-Long; Makal, Trevor A.; Zhou, Hong-Cai Coordination Chemistry Reviews, Vol. 257, Issue 15-16 https://doi.org/10.1016/j.ccr.2013.03.017	journal	August 2013
Determining the specific surface area of Metal Organic Frameworks based on a computational approach Karozis, S.; Charalambopoulou, G.; Steriotis, Th. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 526 https://doi.org/10.1016/j.colsurfa.2016.12.016	journal	August 2017
Hydrogen storage tanks for vehicles: Recent progress and current status Jorgensen, Scott W. Current Opinion in Solid State and Materials Science, Vol. 15, Issue 2 https://doi.org/10.1016/j.cossms.2010.09.004	journal	April 2011
Enthalpy–entropy correlation for hydrogen adsorption on zeolites Garrone, E.; Bonelli, B.; Otero Areán, C. Chemical Physics Letters, Vol. 456, Issue 1-3 https://doi.org/10.1016/j.cplett.2008.03.014	journal	April 2008
Nuclear quantum effects on adsorption of H2 and isotopologues on metal ions Savchenko, Ievgeniia; Gu, Bing; Heine, Thomas Chemical Physics Letters, Vol. 670 https://doi.org/10.1016/j.cplett.2016.12.069	journal	February 2017
A Round Robin characterisation of the hydrogen sorption properties of a carbon based material Zlotea, Claudia; Moretto, Pietro; Steriotis, Theodore International Journal of Hydrogen Energy, Vol. 34, Issue 7 https://doi.org/10.1016/j.ijhydene.2009.01.079	journal	April 2009
High-density automotive hydrogen storage with cryogenic capable pressure vessels Aceves, Salvador M.; Espinosa-Loza, Francisco; Ledesma-Orozco, Elias International Journal of Hydrogen Energy, Vol. 35, Issue 3 https://doi.org/10.1016/j.ijhydene.2009.11.069	journal	February 2010
Hydrogen physisorption in high SSA microporous materials – A comparison between AX-21_33 and MOF-177 at cryogenic conditions Schlichtenmayer, Maurice; Streppel, Barbara; Hirscher, Michael International Journal of Hydrogen Energy, Vol. 36, Issue 1 https://doi.org/10.1016/j.ijhydene.2010.09.057	journal	January 2011
Development of high pressure gaseous hydrogen storage technologies Zheng, Jinyang; Liu, Xianxin; Xu, Ping International Journal of Hydrogen Energy, Vol. 37, Issue 1 https://doi.org/10.1016/j.ijhydene.2011.02.125	journal	January 2012
A Round Robin Test exercise on hydrogen absorption/desorption properties of a magnesium hydride based material Moretto, P.; Zlotea, C.; Dolci, F. International Journal of Hydrogen Energy, Vol. 38, Issue 16 https://doi.org/10.1016/j.ijhydene.2013.03.118	journal	May 2013
Analysis of the uncertainties in gas uptake measurements using the Sieverts method Webb, C. J.; Gray, E. MacA. International Journal of Hydrogen Energy, Vol. 39, Issue 1 https://doi.org/10.1016/j.ijhydene.2013.09.155	journal	January 2014
Melaleuca bark based porous carbons for hydrogen storage Xiao, Yong; Dong, Hanwu; Long, Chao International Journal of Hydrogen Energy, Vol. 39, Issue 22 https://doi.org/10.1016/j.ijhydene.2014.05.134	journal	July 2014
Hydrogen cryo-adsorption by hexagonal prism monoliths of MIL-101 Blanita, Gabriela; Coldea, Ioan; Misan, Ioan International Journal of Hydrogen Energy, Vol. 39, Issue 30 https://doi.org/10.1016/j.ijhydene.2014.08.038	journal	October 2014
Pitfalls in the characterisation of the hydrogen sorption properties of materials Broom, D. P.; Webb, C. J. International Journal of Hydrogen Energy, Vol. 42, Issue 49 https://doi.org/10.1016/j.ijhydene.2017.10.028	journal	December 2017
Concepts for improving hydrogen storage in nanoporous materials Broom, D. P.; Webb, C. J.; Fanourgakis, G. S. International Journal of Hydrogen Energy, Vol. 44, Issue 15 https://doi.org/10.1016/j.ijhydene.2019.01.224	journal	March 2019
Estimation of system-level hydrogen storage for metal-organic frameworks with high volumetric storage density Purewal, Justin; Veenstra, Mike; Tamburello, David International Journal of Hydrogen Energy, Vol. 44, Issue 29 https://doi.org/10.1016/j.ijhydene.2019.04.082	journal	June 2019
The storage performance of automotive cryo-compressed hydrogen vessels Moreno-Blanco, Julio; Petitpas, Guillaume; Espinosa-Loza, Francisco International Journal of Hydrogen Energy, Vol. 44, Issue 31 https://doi.org/10.1016/j.ijhydene.2019.04.189	journal	June 2019
Sieverts apparatus and methodology for accurate determination of hydrogen uptake by light-atom hosts Blach, T. P.; Gray, E. MacA. Journal of Alloys and Compounds, Vol. 446-447 https://doi.org/10.1016/j.jallcom.2006.12.061	journal	October 2007
Inelastic neutron scattering of H2 adsorbed in HKUST-1 Liu, Y.; Brown, C. M.; Neumann, D. A. Journal of Alloys and Compounds, Vol. 446-447 https://doi.org/10.1016/j.jallcom.2006.12.106	journal	October 2007
Post consumer PET waste as potential feedstock for metal organic frameworks No authors listed Materials Letters, Vol. 106 https://doi.org/10.1016/j.matlet.2013.05.058	journal	September 2013
High pressure adsorption of hydrogen, nitrogen, carbon dioxide and methane on the metal–organic framework HKUST-1 Moellmer, J.; Moeller, A.; Dreisbach, F. Microporous and Mesoporous Materials, Vol. 138, Issue 1-3 https://doi.org/10.1016/j.micromeso.2010.09.013	journal	February 2011
Theoretical study of hydrogen adsorption in oxygen functionalized carbon slit pores Gotzias, A.; Tylianakis, E.; Froudakis, G. Microporous and Mesoporous Materials, Vol. 154 https://doi.org/10.1016/j.micromeso.2011.10.011	journal	May 2012
Interpretation of net and excess adsorption isotherms in microporous adsorbents Pini, Ronny Microporous and Mesoporous Materials, Vol. 187 https://doi.org/10.1016/j.micromeso.2013.12.005	journal	March 2014
Predicting hydrogen storage in MOFs via machine learning Ahmed, Alauddin; Siegel, Donald J. Patterns, Vol. 2, Issue 7 https://doi.org/10.1016/j.patter.2021.100291	journal	July 2021
Preparation of value-added metal-organic frameworks (MOFs) using waste PET bottles as source of acid linker Dyosiba, Xoliswa; Ren, Jianwei; Musyoka, Nicholas M. Sustainable Materials and Technologies, Vol. 10 https://doi.org/10.1016/j.susmat.2016.10.001	journal	December 2016
Materials Genome in Action: Identifying the Performance Limits of Physical Hydrogen Storage Thornton, Aaron W.; Simon, Cory M.; Kim, Jihan Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.6b04933	journal	March 2017
Development of a Cambridge Structural Database Subset: A Collection of Metal–Organic Frameworks for Past, Present, and Future Moghadam, Peyman Z.; Li, Aurelia; Wiggin, Seth B. Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.7b00441	journal	March 2017
Record High Hydrogen Storage Capacity in the Metal–Organic Framework Ni ₂ ( m -dobdc) at Near-Ambient Temperatures Kapelewski, Matthew T.; Runčevski, Tomče; Tarver, Jacob D. Chemistry of Materials, Vol. 30, Issue 22 https://doi.org/10.1021/acs.chemmater.8b03276	journal	October 2018
Development of Biochar-Based Functional Materials: Toward a Sustainable Platform Carbon Material Liu, Wu-Jun; Jiang, Hong; Yu, Han-Qing Chemical Reviews, Vol. 115, Issue 22 https://doi.org/10.1021/acs.chemrev.5b00195	journal	October 2015
Feasibility of Varied Polyethylene Terephthalate Wastes as a Linker Source in Metal–Organic Framework UiO-66(Zr) Synthesis Dyosiba, Xoliswa; Ren, Jianwei; Musyoka, Nicholas M. Industrial & Engineering Chemistry Research, Vol. 58, Issue 36 https://doi.org/10.1021/acs.iecr.9b02205	journal	August 2019
Advances, Updates, and Analytics for the Computation-Ready, Experimental Metal–Organic Framework Database: CoRE MOF 2019 Chung, Yongchul G.; Haldoupis, Emmanuel; Bucior, Benjamin J. Journal of Chemical & Engineering Data, Vol. 64, Issue 12 https://doi.org/10.1021/acs.jced.9b00835	journal	November 2019
Fast Screening of Large Databases for Top Performing Nanomaterials Using a Self-Consistent, Machine Learning Based Approach Fanourgakis, George S.; Gkagkas, Konstantinos; Tylianakis, Emmanuel The Journal of Physical Chemistry C, Vol. 124, Issue 36 https://doi.org/10.1021/acs.jpcc.0c05491	journal	August 2020
Rational Design of a Low-Cost, High-Performance Metal–Organic Framework for Hydrogen Storage and Carbon Capture Witman, Matthew; Ling, Sanliang; Gladysiak, Andrzej The Journal of Physical Chemistry C, Vol. 121, Issue 2 https://doi.org/10.1021/acs.jpcc.6b10363	journal	January 2017
Structural Transitions in the MIL-53(Al) Metal–Organic Framework upon Cryogenic Hydrogen Adsorption Mota, José P. B.; Martins, Daniel; Lopes, Diogo The Journal of Physical Chemistry C, Vol. 121, Issue 43 https://doi.org/10.1021/acs.jpcc.7b06861	journal	October 2017
A Generic Machine Learning Algorithm for the Prediction of Gas Adsorption in Nanoporous Materials Fanourgakis, George S.; Gkagkas, Konstantinos; Tylianakis, Emmanuel The Journal of Physical Chemistry C, Vol. 124, Issue 13 https://doi.org/10.1021/acs.jpcc.9b10766	journal	March 2020
Tolerance of Flexible MOFs toward Repeated Adsorption Stress Bon, Volodymyr; Kavoosi, Negar; Senkovska, Irena ACS Applied Materials & Interfaces, Vol. 7, Issue 40 https://doi.org/10.1021/acsami.5b05456	journal	October 2015
Understanding Volumetric and Gravimetric Hydrogen Adsorption Trade-off in Metal–Organic Frameworks Gómez-Gualdrón, Diego A.; Wang, Timothy C.; García-Holley, Paula ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b01190	journal	April 2017
Benchmark Study of Hydrogen Storage in Metal–Organic Frameworks under Temperature and Pressure Swing Conditions García-Holley, Paula; Schweitzer, Benjamin; Islamoglu, Timur ACS Energy Letters, Vol. 3, Issue 3 https://doi.org/10.1021/acsenergylett.8b00154	journal	February 2018
Theoretical Limits of Hydrogen Storage in Metal–Organic Frameworks: Opportunities and Trade-Offs Goldsmith, Jacob; Wong-Foy, Antek G.; Cafarella, Michael J. Chemistry of Materials, Vol. 25, Issue 16 https://doi.org/10.1021/cm401978e	journal	August 2013
Gibbsian Surface Excess for Gas AdsorptionRevisited Sircar, S. Industrial & Engineering Chemistry Research, Vol. 38, Issue 10 https://doi.org/10.1021/ie9900871	journal	October 1999
Vibrational spectroscopy of porous Vycor glass: surface hydroxyl perturbations upon adsorption of hydrogen Huber, T. E.; Huber, C. A. The Journal of Physical Chemistry, Vol. 94, Issue 6 https://doi.org/10.1021/j100369a053	journal	March 1990
The Anomalous Monolayer Adsorption of Helium. Singh, Rudra Pal; Band, William The Journal of Physical Chemistry, Vol. 59, Issue 7 https://doi.org/10.1021/j150529a021	journal	July 1955
Heat of Adsorption of Parahydrogen and Orthodeuterium on Graphon Pace, E. L.; Siebert, A. R. The Journal of Physical Chemistry, Vol. 63, Issue 9 https://doi.org/10.1021/j150579a014	journal	September 1959
The Adsorption of Helium on Carbon Black at Liquid Helium Temperatures Schaeffer, W. D.; Smith, W. R.; Wendell, C. B. Journal of the American Chemical Society, Vol. 71, Issue 3 https://doi.org/10.1021/ja01171a027	journal	March 1949
Characterization of H₂ Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering Rowsell, Jesse L. C.; Eckert, Juergen; Yaghi, Omar M. Journal of the American Chemical Society, Vol. 127, Issue 42, p. 14904-14910 https://doi.org/10.1021/ja0542690	journal	October 2005
Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn ²⁺ Coordination Sites Dincǎ, Mircea; Dailly, Anne; Liu, Yun Journal of the American Chemical Society, Vol. 128, Issue 51 https://doi.org/10.1021/ja0656853	journal	December 2006
Neutron Powder Diffraction Study of D ₂ Sorption in Cu ₃ (1,3,5-benzenetricarboxylate) ₂ Peterson, Vanessa K.; Liu, Yun; Brown, Craig M. Journal of the American Chemical Society, Vol. 128, Issue 49 https://doi.org/10.1021/ja0660857	journal	December 2006
M₂(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H₂ Binding at the Open Metal Sites Kapelewski, Matthew T.; Geier, Stephen J.; Hudson, Matthew R. Journal of the American Chemical Society, Vol. 136, Issue 34, p. 12119-12129 https://doi.org/10.1021/ja506230r	journal	August 2014
Broadly Hysteretic H ₂ Adsorption in the Microporous Metal−Organic Framework Co(1,4-benzenedipyrazolate) Choi, Hye Jin; Dincă, Mircea; Long, Jeffrey R. Journal of the American Chemical Society, Vol. 130, Issue 25 https://doi.org/10.1021/ja8024092	journal	June 2008
Specific Isotope-Responsive Breathing Transition in Flexible Metal–Organic Frameworks Kim, Jin Yeong; Park, Jaewoo; Ha, Junsu Journal of the American Chemical Society, Vol. 142, Issue 31 https://doi.org/10.1021/jacs.0c04277	journal	July 2020
Ambient-Temperature Hydrogen Storage via Vanadium(II)-Dihydrogen Complexation in a Metal–Organic Framework Jaramillo, David E.; Jiang, Henry Z. H.; Evans, Hayden A. Journal of the American Chemical Society, Vol. 143, Issue 16 https://doi.org/10.1021/jacs.1c01883	journal	April 2021
The Influence of Intrinsic Framework Flexibility on Adsorption in Nanoporous Materials Witman, Matthew; Ling, Sanliang; Jawahery, Sudi Journal of the American Chemical Society, Vol. 139, Issue 15 https://doi.org/10.1021/jacs.7b01688	journal	April 2017
Quantum Effects on Hydrogen Adsorption in Internal Nanospaces of Single-Wall Carbon Nanohorns Tanaka, Hideki; Kanoh, Hirofumi; El-Merraoui, Mustapha The Journal of Physical Chemistry B, Vol. 108, Issue 45 https://doi.org/10.1021/jp048603a	journal	November 2004
Kinetic Trapping of D ₂ in MIL-53(Al) Observed Using Neutron Scattering Pollock, Rachel A.; Her, Jae-Hyuk; Brown, Craig M. The Journal of Physical Chemistry C, Vol. 118, Issue 31 https://doi.org/10.1021/jp504870n	journal	July 2014
Investigation of the Hydrogen State in IRMOF-1 from Measurements and Modeling of Adsorption Isotherms at High Gas Densities Poirier, Eric; Dailly, Anne The Journal of Physical Chemistry C, Vol. 112, Issue 33 https://doi.org/10.1021/jp800981f	journal	August 2008
Isosteric Heat of Adsorption: Theory and Experiment Sircar, S.; Mohr, R.; Ristic, C. The Journal of Physical Chemistry B, Vol. 103, Issue 31 https://doi.org/10.1021/jp9903817	journal	August 1999
On the Enhancement of Molecular Hydrogen Interactions in Nanoporous Solids for Improved Hydrogen Storage Klontzas, Emmanouel; Tylianakis, Emmanuel; Froudakis, George E. The Journal of Physical Chemistry Letters, Vol. 2, Issue 14 https://doi.org/10.1021/jz2005368	journal	June 2011
Adsorption in Porous Materials at High Pressure: Theory and Experiment Myers, A. L.; Monson, P. A. Langmuir, Vol. 18, Issue 26 https://doi.org/10.1021/la026399h	journal	December 2002
Optimum Conditions for Adsorptive Storage Bhatia, Suresh K.; Myers, Alan L. Langmuir, Vol. 22, Issue 4 https://doi.org/10.1021/la0523816	journal	February 2006
High Uptakes of CO ₂ and CH ₄ in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101 Llewellyn, Philip L.; Bourrelly, Sandrine; Serre, Christian Langmuir, Vol. 24, Issue 14 https://doi.org/10.1021/la800227x	journal	July 2008
On the Nature of the Adsorbed Hydrogen Phase in Microporous Metal−Organic Frameworks at Supercritical Temperatures Poirier, Eric; Dailly, Anne Langmuir, Vol. 25, Issue 20 https://doi.org/10.1021/la901680p	journal	September 2009
Examination of the Approximations Used in Determining the Isosteric Heat of Adsorption from the Clausius−Clapeyron Equation Pan, Huanhua; Ritter, James A.; Balbuena, Perla B. Langmuir, Vol. 14, Issue 21 https://doi.org/10.1021/la9803373	journal	October 1998
Methane storage in flexible metal–organic frameworks with intrinsic thermal management Mason, Jarad A.; Oktawiec, Julia; Taylor, Mercedes K. Nature, Vol. 527, Issue 7578 https://doi.org/10.1038/nature15732	journal	October 2015
De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim Nature Chemistry, Vol. 2, Issue 11, p. 944-948 https://doi.org/10.1038/nchem.834	journal	September 2010
Transformation of metal-organic frameworks for molecular sieving membranes Li, Wanbin; Zhang, Yufan; Zhang, Congyang Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11315	journal	April 2016
Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites Weinrauch, I.; Savchenko, I.; Denysenko, D. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14496	journal	March 2017
Exceptional hydrogen storage achieved by screening nearly half a million metal-organic frameworks Ahmed, Alauddin; Seth, Saona; Purewal, Justin Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09365-w	journal	April 2019
Chemically intuited, large-scale screening of MOFs by machine learning techniques Borboudakis, Giorgos; Stergiannakos, Taxiarchis; Frysali, Maria npj Computational Materials, Vol. 3, Issue 1 https://doi.org/10.1038/s41524-017-0045-8	journal	October 2017
Formation of a super-dense hydrogen monolayer on mesoporous silica Balderas-Xicohténcatl, Rafael; Lin, Hung-Hsuan; Lurz, Christian Nature Chemistry https://doi.org/10.1038/s41557-022-01019-7	journal	August 2022
Biomass waste utilisation in low-carbon products: harnessing a major potential resource Tripathi, Nimisha; Hills, Colin D.; Singh, Raj S. npj Climate and Atmospheric Science, Vol. 2, Issue 1 https://doi.org/10.1038/s41612-019-0093-5	journal	October 2019
Hydrogen adsorption on magnesium-exchanged zeolites Turnes Palomino, G.; Llop Carayol, M. R.; Otero Areán, C. J. Mater. Chem., Vol. 16, Issue 28 https://doi.org/10.1039/B607261E	journal	January 2006
Materials for hydrogenstorage: current research trends and perspectives van den Berg, Annemieke W. C.; Areán, Carlos Otero Chem. Commun., Issue 6 https://doi.org/10.1039/B712576N	journal	January 2008
BET specific surface area and pore structure of MOFs determined by hydrogen adsorption at 20 K Streppel, Barbara; Hirscher, Michael Phys. Chem. Chem. Phys., Vol. 13, Issue 8 https://doi.org/10.1039/C0CP01873B	journal	January 2011
Energy storage applications of activated carbons: supercapacitors and hydrogen storage Sevilla, Marta; Mokaya, Robert Energy Environ. Sci., Vol. 7, Issue 4 https://doi.org/10.1039/C3EE43525C	journal	January 2014
Experimental assessment of physical upper limit for hydrogen storage capacity at 20 K in densified MIL-101 monoliths Oh, Hyunchul; Lupu, Dan; Blanita, Gabriela RSC Adv., Vol. 4, Issue 6 https://doi.org/10.1039/C3RA46233A	journal	January 2014
Diffusive and rotational dynamics of condensed n-H ₂ confined in MCM-41 Prisk, T. R.; Bryan, M. S.; Sokol, P. E. Phys. Chem. Chem. Phys., Vol. 16, Issue 33 https://doi.org/10.1039/C4CP02281E	journal	January 2014
Flexible metal–organic frameworks Schneemann, A.; Bon, V.; Schwedler, I. Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00101J	journal	January 2014
The materials genome in action: identifying the performance limits for methane storage Simon, Cory M.; Kim, Jihan; Gomez-Gualdron, Diego A. Energy & Environmental Science, Vol. 8, Issue 4 https://doi.org/10.1039/C4EE03515A	journal	January 2015
Ultimate H₂ and CH₄ adsorption in slit-like carbon nanopores at 298 K: a molecular dynamics study Poirier, Eric RSC Adv., Vol. 4, Issue 44 https://doi.org/10.1039/C4RA02553A	journal	January 2014
Irreproducibility in hydrogen storage material research Broom, D. P.; Hirscher, M. Energy & Environmental Science, Vol. 9, Issue 11 https://doi.org/10.1039/C6EE01435F	journal	January 2016
The rotational dynamics of H ₂ adsorbed in covalent organic frameworks Pham, Tony; Forrest, Katherine A.; Mostrom, Matthew Physical Chemistry Chemical Physics, Vol. 19, Issue 20 https://doi.org/10.1039/C7CP00924K	journal	January 2017
An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage Allendorf, Mark D.; Hulvey, Zeric; Gennett, Thomas Energy & Environmental Science, Vol. 11, Issue 10 https://doi.org/10.1039/C8EE01085D	journal	January 2018
Energy-based descriptors to rapidly predict hydrogen storage in metal–organic frameworks Bucior, Benjamin J.; Bobbitt, N. Scott; Islamoglu, Timur Molecular Systems Design & Engineering, Vol. 4, Issue 1 https://doi.org/10.1039/C8ME00050F	journal	January 2019
Emerging applications of biochar-based materials for energy storage and conversion Liu, Wu-Jun; Jiang, Hong; Yu, Han-Qing Energy & Environmental Science, Vol. 12, Issue 6 https://doi.org/10.1039/C9EE00206E	journal	January 2019
A practical guide to calculate the isosteric heat/enthalpy of adsorption via adsorption isotherms in metal–organic frameworks, MOFs Nuhnen, Alexander; Janiak, Christoph Dalton Transactions, Vol. 49, Issue 30 https://doi.org/10.1039/D0DT01784A	journal	January 2020
Design principles for the ultimate gas deliverable capacity material: nonporous to porous deformations without volume change Witman, Matthew; Ling, Sanliang; Stavila, Vitalie Molecular Systems Design & Engineering, Vol. 5, Issue 9 https://doi.org/10.1039/D0ME00122H	journal	January 2020
Green synthesis of a large series of bimetallic MIL-100(Fe,M) MOFs Steenhaut, Timothy; Hermans, Sophie; Filinchuk, Yaroslav New Journal of Chemistry, Vol. 44, Issue 10 https://doi.org/10.1039/D0NJ00257G	journal	January 2020
High-density monolithic pellets of double-sided graphene fragments based on zeolite-templated carbon Gabe, Atsushi; Ouzzine, Mohammed; Taylor, Erin E. Journal of Materials Chemistry A, Vol. 9, Issue 12 https://doi.org/10.1039/D0TA11625D	journal	January 2021
Toward sustainable syntheses of Ca-based MOFs Crickmore, Tom S.; Sana, Haamidah Begum; Mitchell, Hannah Chemical Communications, Vol. 57, Issue 81 https://doi.org/10.1039/D1CC04032D	journal	January 2021
Structural resolution and mechanistic insight into hydrogen adsorption in flexible ZIF-7 Klein, Ryan A.; Shulda, Sarah; Parilla, Philip A. Chemical Science, Vol. 12, Issue 47 https://doi.org/10.1039/D1SC04618G	journal	January 2021
Hydrogen liquefaction: a review of the fundamental physics, engineering practice and future opportunities Al Ghafri, Saif ZS.; Munro, Stephanie; Cardella, Umberto Energy & Environmental Science, Vol. 15, Issue 7 https://doi.org/10.1039/D2EE00099G	journal	January 2022
Structure and dynamics of hydrogen sorption in mesoporous MCM-41 Edler, Karen J.; Reynolds, Phillip A.; Branton, Peter J. Journal of the Chemical Society, Faraday Transactions, Vol. 93, Issue 8 https://doi.org/10.1039/a607878h	journal	January 1997
Cubic Ia3d large mesoporous silica: synthesis and replication to platinum nanowires, carbon nanorods and carbon nanotubesElectronic supplementary information (ESI) available: TEM images of mesoporous cubic silica and Pt networks, XRD patterns during formation of the cubic phase. See http://www.rsc.org/suppdata/cc/b3/b306504a/ Kleitz, Freddy; Hei Choi, Shin; Ryoo, Ryong Chemical Communications, Issue 17 https://doi.org/10.1039/b306504a	journal	January 2003
Computational studies of molecular hydrogen binding affinities: The role of dispersion forces, electrostatics, and orbital interactions Lochan, Rohini C.; Head-Gordon, Martin Physical Chemistry Chemical Physics, Vol. 8, Issue 12 https://doi.org/10.1039/b515409j	journal	January 2006
Hydrogen storage in metal–organic frameworks Murray, Leslie J.; Dincă, Mircea; Long, Jeffrey R. Chemical Society Reviews, Vol. 38, Issue 5, p. 1294-1314 https://doi.org/10.1039/b802256a	journal	January 2009
Adsorption and desorption of hydrogen on metal–organic framework materials for storage applications: comparison with other nanoporous materials Thomas, K. Mark Dalton Transactions, Issue 9 https://doi.org/10.1039/b815583f	journal	January 2009
Thermodynamic study of the adsorbed hydrogen phase in Cu-based metal-organic frameworks at cryogenic temperatures Poirier, Eric; Dailly, Anne Energy & Environmental Science, Vol. 2, Issue 4 https://doi.org/10.1039/b818393g	journal	January 2009
Volumetric hydrogen sorption capacity of monoliths prepared by mechanical densification of MOF-177 Zacharia, Renju; Cossement, Daniel; Lafi, Lyubov Journal of Materials Chemistry, Vol. 20, Issue 11 https://doi.org/10.1039/b922991d	journal	January 2010
Characterisation of porous hydrogen storage materials: carbons, zeolites, MOFs and PIMs Tedds, Steven; Walton, Allan; Broom, Darren P. Faraday Discussions, Vol. 151 https://doi.org/10.1039/c0fd00022a	journal	January 2011
Nanosponges for hydrogen storage Schlichtenmayer, Maurice; Hirscher, Michael Journal of Materials Chemistry, Vol. 22, Issue 20 https://doi.org/10.1039/c2jm15890f	journal	January 2012
Novel alkali and alkaline earth metal coordination polymers based on 1,4-naphthalenedicarboxylic acid: synthesis, structural characterization and properties Raja, Duraisamy Senthil; Luo, Jheng-Hong; Yeh, Chun-Ting CrystEngComm, Vol. 16, Issue 10 https://doi.org/10.1039/c3ce42208a	journal	January 2014
Hydrogen Plasma — Phase Diagram and Properties Ebeling, W.; Kraeft, W. D.; Kremp, D. Europhysics News, Vol. 17, Issue 4 https://doi.org/10.1051/epn/19861704052	journal	January 1986
Concerning a Theory of Multilayer Adsorption, with Particular Reference to Adsorbed Helium Steele, William A. The Journal of Chemical Physics, Vol. 25, Issue 5 https://doi.org/10.1063/1.1743130	journal	November 1956
An accurate H2–H2 interaction potential from first principles Diep, Phong; Johnson, J. Karl The Journal of Chemical Physics, Vol. 112, Issue 10 https://doi.org/10.1063/1.481009	journal	March 2000
Feynman-Hibbs potentials and path integrals for quantum Lennard-Jones systems: Theory and Monte Carlo simulations Sesé, Luis M. Molecular Physics, Vol. 85, Issue 5 https://doi.org/10.1080/00268979500101571	journal	August 1995
Hydrogen adsorption on graphite and in carbon slit pores from path integral simulations Wang, Qinyu; Johnson, J. Karl Molecular Physics, Vol. 95, Issue 2 https://doi.org/10.1080/00268979809483162	journal	October 1998
iRASPA: GPU-accelerated visualization software for materials scientists Dubbeldam, David; Calero, Sofía; Vlugt, Thijs J. H. Molecular Simulation, Vol. 44, Issue 8 https://doi.org/10.1080/08927022.2018.1426855	journal	January 2018
Hydrides formed from intermetallic compounds of two transition metals: a special class of ternary alloys Buschow, K. H. J.; Bouten, P. C. P.; Miedema, A. R. Reports on Progress in Physics, Vol. 45, Issue 9 https://doi.org/10.1088/0034-4885/45/9/001	journal	September 1982
Phase separation in confined systems Gelb, Lev D.; Gubbins, K. E.; Radhakrishnan, R. Reports on Progress in Physics, Vol. 62, Issue 12 https://doi.org/10.1088/0034-4885/62/12/201	journal	December 1999
Thermodynamics of hydrogen adsorption in MOF-177 at low temperatures: measurements and modelling Poirier, Eric; Dailly, Anne Nanotechnology, Vol. 20, Issue 20 https://doi.org/10.1088/0957-4484/20/20/204006	journal	April 2009
Cohesion Lennard-Jones, J. E. Proceedings of the Physical Society, Vol. 43, Issue 5 https://doi.org/10.1088/0959-5309/43/5/301	journal	September 1931
Repulsive Interaction Potentials between Rare-Gas Atoms. Homonuclear Two-Center Systems Abrahamson, Adolf A. Physical Review, Vol. 130, Issue 2 https://doi.org/10.1103/PhysRev.130.693	journal	April 1963
Experimental compressions for normal hydrogen and normal deuterium to 25 kbar at 4.2 K Anderson, M. S.; Swenson, C. A. Physical Review B, Vol. 10, Issue 12 https://doi.org/10.1103/PhysRevB.10.5184	journal	December 1974
Direct Observation of Hydrogen Adsorption Sites and Nanocage Formation in Metal-Organic Frameworks Yildirim, T.; Hartman, M. Physical Review Letters, Vol. 95, Issue 21 https://doi.org/10.1103/PhysRevLett.95.215504	journal	November 2005
Van der waals forces Margenau, H. Reviews of Modern Physics, Vol. 11, Issue 1 https://doi.org/10.1103/RevModPhys.11.1	journal	January 1939
The solid molecular hydrogens in the condensed phase: Fundamentals and static properties Silvera, Isaac F. Reviews of Modern Physics, Vol. 52, Issue 2 https://doi.org/10.1103/RevModPhys.52.393	journal	April 1980
Municipal solid waste generation, composition, and management: the global scenario Sharma, Kapil Dev; Jain, Siddharth Social Responsibility Journal, Vol. 16, Issue 6 https://doi.org/10.1108/SRJ-06-2019-0210	journal	June 2020
Fingerprinting diverse nanoporous materials for optimal hydrogen storage conditions using meta-learning Sun, Yangzesheng; DeJaco, Robert F.; Li, Zhao Science Advances, Vol. 7, Issue 30 https://doi.org/10.1126/sciadv.abg3983	journal	July 2021
Balancing volumetric and gravimetric uptake in highly porous materials for clean energy Chen, Zhijie; Li, Penghao; Anderson, Ryther Science, Vol. 368, Issue 6488 https://doi.org/10.1126/science.aaz8881	journal	April 2020
Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) Thommes, Matthias; Kaneko, Katsumi; Neimark, Alexander V. Pure and Applied Chemistry, Vol. 87, Issue 9-10 https://doi.org/10.1515/pac-2014-1117	journal	October 2015
High-density hydrogen monolayer formation and isotope diffusion in porous media Balderas-Xicohténcatl, Rafael Universität Stuttgart https://doi.org/10.18419/opus-10792	collection	January 2019

Fundamentals of hydrogen storage in nanoporous materials

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Fundamentals of hydrogen storage in nanoporous materials

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