Mechanism of the First Lithiation/Delithiation Process in the Anode Material CoFeOPO4 @C for Li-Ion Batteries
- Materials Science and Nanoengineering, Mohammed VI Polytechnic University, Lot 660 Hay Moulay Rachid, Ben Guerir, Morocco; LCME, Faculty of Science and Technology - Cadi Ayyad University, Av. A. El Khattabi, P.B. 549 Marrakesh, Morocco; X-ray Science Division, Advanced Photon Sources, Argonne National Laboratory, Argonne, Illinois 60439, United States
- Materials Science and Nanoengineering, Mohammed VI Polytechnic University, Lot 660 Hay Moulay Rachid, Ben Guerir, Morocco
- X-ray Science Division, Advanced Photon Sources, Argonne National Laboratory, Argonne, Illinois 60439, United States
- Materials Science Division, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, Illinois 60439, United States; Chemical Engineering Department, University of Illinois at Chicago, Chicago, Illinois 60607, United States
- Materials Science and Nanoengineering, Mohammed VI Polytechnic University, Lot 660 Hay Moulay Rachid, Ben Guerir, Morocco; Université Hassan 1er, Laboratoire des Sciences des Matériaux, Des Milieux et de la Modélisation (LS3M), 25000 Khouribga, Morocco
- Chemical Science &, Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States
- Chemical Science &, Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States; Materials Science and Engineering, Stanford University, Stanford, California 94305, United States; RMC, Imam Abdulrahman Bin Faisal University (IAU), Dammam, Saudi Arabia
- Materials Science and Nanoengineering, Mohammed VI Polytechnic University, Lot 660 Hay Moulay Rachid, Ben Guerir, Morocco; LCME, Faculty of Science and Technology - Cadi Ayyad University, Av. A. El Khattabi, P.B. 549 Marrakesh, Morocco
A cobalt iron oxyphosphate CoFeOPO4@C (abbreviated as CFP@C) anode was prepared via a solid-state route, and its electrochemical performance was investigated vs Li+/Li over a wide voltage range of 0.01-3.0 V at different current rates C/n (n = 20, 10, 5, 2, and 1). This anode material is able to intercalate more than six lithium ions into the structure at the C/10 current rate, delivering a specific capacity of 748.23 mAh g(-1), which is much higher than the theoretical capacity (593.7 mAh g(-1)) calculated when the insertion of a five lithium ions is considered. A reversible capacity of 200 mAhg(-1) was maintained after 30 cycles. Raman spectroscopy confirmed the incorporation of carbon layers into the CoFeOPO4@C composite. Scanning electronic microscopy revealed that CFP@C particles have an angular-flake shape with particle sizes ranging between 1 and 5 mu m. In situ X-ray absorption spectroscopy of Fe and Co at the K-edge showed that both transition metals are active during the whole discharge and charge. In operando high-energy X-ray diffraction revealed that this material undergoes a gradual evolution of the structure with lower crystallinity after the first discharge. Correlating electrochemical performance to the structural and electronic features indicated that the cycling mechanism of the CFP@C anode material exhibits a combination of intercalation and conversion processes.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- Office Cherifien des Phosphates Group (OCP)
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1467400
- Journal Information:
- Journal of Physical Chemistry. C, Vol. 122, Issue 13; ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
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