Understanding the electrochemical lithiation/delithiation process in the anode material for lithium ion batteries NiFeOPO4/C using ex-situ X-ray absorption near edge spectroscopy and in-situ synchrotron X-ray

Aziam, H.; Garhi, G.; Tamraoui, Y.; Ma, L.; Wu, T.; Xu, G. L.; Manoun, B.; Alami, J.; Amine, K.; Saadoune, I.

doi:10.1016/j.electacta.2018.07.038

Understanding the electrochemical lithiation/delithiation process in the anode material for lithium ion batteries NiFeOPO₄/C using ex-situ X-ray absorption near edge spectroscopy and in-situ synchrotron X-ray

Journal Article · Thu Jul 12 00:00:00 EDT 2018 · Electrochimica Acta

DOI:https://doi.org/10.1016/j.electacta.2018.07.038· OSTI ID:1477459

Aziam, H. ^[1]; Garhi, G. ^[2]; Tamraoui, Y. ^[3]; Ma, L. ^[4]; Wu, T. ^[4]; Xu, G. L. ^[4]; Manoun, B. ^[5]; Alami, J. ^[3]; Amine, K. ^[6]; Saadoune, I. ^[7]

Mohammed VI Polytechnic Univ., Ben Guerir (Morocco); Cadi Ayyad Univ., Marrakesh (Morocco); Argonne National Lab. (ANL), Argonne, IL (United States)
Cadi Ayyad Univ., Marrakesh (Morocco)
Mohammed VI Polytechnic Univ., Ben Guerir (Morocco)
Argonne National Lab. (ANL), Argonne, IL (United States)
Mohammed VI Polytechnic Univ., Ben Guerir (Morocco); Univ. Hassan 1er, Khouribga (Morocco)
Argonne National Lab. (ANL), Argonne, IL (United States); Stanford Univ., Stanford, CA (United States); Imam Abdulrahman Bin Faisal Univ. (IAU), Dammam (Saudi Arabia)
Mohammed VI Polytechnic Univ., Ben Guerir (Morocco); Cadi Ayyad Univ., Marrakesh (Morocco)

Here, nickel iron (III) oxyphosphate NiFeOPO₄ (NFP) was successfully synthesized using solid-state route and modified with carbon layer using sucrose as carbon source. The electrochemical performances of the composite anode material NiFeOPO₄/C (NFP/C) vs. Li⁺/Li⁰ were investigated at C/5 current rate and in a wide voltage window 0.01-3.0 V. During the first lithiation at C/5, NFP/C was able to uptake more than six lithium ions into the structure delivering a capacity of 736.63 mAh g^-1. In this study, NFP phosphate was characterized using XRD, SEM, EDS mapping, and Raman spectroscopy. The first cycle was investigated using high energy spectroscopies including: in-situ synchrotron X-Ray Diffraction and ex-situ X-ray Absorption Near Edge Spectroscopy (XANES). In-situ synchrotron XRD revealed that the crystal structure of NFP/C undergoes structural transformations leading to lower degrees of crystallinity during the first lithiation. Ex-situ XANES measurements disclosed that the redox reaction of iron and nickel during the first lithiation and delithiation is reversible.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V). Battery Materials Research (BMR) Program

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1477459

Alternate ID(s):: OSTI ID: 1495273
OSTI ID: 23121562

Journal Information:: Electrochimica Acta, Journal Name: Electrochimica Acta Journal Issue: C Vol. 283; ISSN 0013-4686

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

25 ENERGY STORAGE
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