Atomically Thin Mesoporous Co3O4 Layers Strongly Coupled with N-rGO Nanosheets as High-Performance Bifunctional Catalysts for 1D Knittable Zinc-Air Batteries [Atomically Thin Mesoporous Co3O4/N-rGO Nanosheets as the Bifunctional Catalysts for One-Dimensional Knittable Zinc-Air Batteries]

Li, Yingbo; Zhong, Cheng; Liu, Jie; Zeng, Xiaoqiao; Qu, Shengxiang; Han, Xiaopeng; Deng, Yida; Hu, Wenbin; Lu, Jun

doi:10.1002/adma.201703657

Title: Atomically Thin Mesoporous Co₃O₄ Layers Strongly Coupled with N-rGO Nanosheets as High-Performance Bifunctional Catalysts for 1D Knittable Zinc-Air Batteries [Atomically Thin Mesoporous Co₃O₄/N-rGO Nanosheets as the Bifunctional Catalysts for One-Dimensional Knittable Zinc-Air Batteries]

Journal Article · Wed Dec 06 00:00:00 EST 2017 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201703657· OSTI ID:1466320

Li, Yingbo ^[1]; Zhong, Cheng ^[1]; Liu, Jie ^[1]; Zeng, Xiaoqiao ^[2]; Qu, Shengxiang ^[1]; Han, Xiaopeng ^[1]; Deng, Yida ^[1]; Hu, Wenbin ^[1];

^[2]

Tianjin Univ., Tianjin (China)
Argonne National Lab. (ANL), Lemont, IL (United States)

Abstract Under development for next‐generation wearable electronics are flexible, knittable, and wearable energy‐storage devices with high energy density that can be integrated into textiles. Herein, knittable fiber‐shaped zinc–air batteries with high volumetric energy density (36.1 mWh cm ⁻³ ) are fabricated via a facile and continuous method with low‐cost materials. Furthermore, a high‐yield method is developed to prepare the key component of the fiber‐shaped zinc–air battery, i.e., a bifunctional catalyst composed of atomically thin layer‐by‐layer mesoporous Co ₃ O ₄ /nitrogen‐doped reduced graphene oxide (N‐rGO) nanosheets. Benefiting from the high surface area, mesoporous structure, and strong synergetic effect between the Co ₃ O ₄ and N‐rGO nanosheets, the bifunctional catalyst exhibits high activity and superior durability for oxygen reduction and evolution reactions. Compared to a fiber‐shaped zinc–air battery using state‐of‐the‐art Pt/C + RuO ₂ catalysts, the battery based on these Co ₃ O ₄ /N‐rGO nanosheets demonstrates enhanced and stable electrochemical performance, even under severe deformation. Such batteries, for the first time, can be successfully knitted into clothes without short circuits under external forces and can power various electronic devices and even charge a cellphone.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE

Grant/Contract Number:: AC02-06CH11357; DE‐AC02‐06CH11357

OSTI ID:: 1466320

Alternate ID(s):: OSTI ID: 1412569

Journal Information:: Advanced Materials, Vol. 30, Issue 4; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 276 works

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References (66)

Co@Co ₃ O ₄ @PPD Core@bishell Nanoparticle-Based Composite as an Efficient Electrocatalyst for Oxygen Reduction Reaction Wang, Zhijuan; Li, Bing; Ge, Xiaoming Small, Vol. 12, Issue 19 https://doi.org/10.1002/smll.201503694	journal	March 2016
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation Gorlin, Yelena; Jaramillo, Thomas F. Journal of the American Chemical Society, Vol. 132, Issue 39, p. 13612-13614 https://doi.org/10.1021/ja104587v	journal	October 2010
A flexible solid-state electrolyte for wide-scale integration of rechargeable zinc–air batteries Fu, Jing; Zhang, Jing; Song, Xueping Energy & Environmental Science, Vol. 9, Issue 2 https://doi.org/10.1039/C5EE03404C	journal	January 2016
Two dimensional nanomaterials for flexible supercapacitors Peng, Xu; Peng, Lele; Wu, Changzheng Chemical Society Reviews, Vol. 43, Issue 10 https://doi.org/10.1039/c3cs60407a	journal	January 2014
Metal (Ni, Co)-Metal Oxides/Graphene Nanocomposites as Multifunctional Electrocatalysts Liu, Xien; Liu, Wen; Ko, Minseong Advanced Functional Materials, Vol. 25, Issue 36 https://doi.org/10.1002/adfm.201502217	journal	August 2015
Flexible, Stretchable, and Rechargeable Fiber-Shaped Zinc-Air Battery Based on Cross-Stacked Carbon Nanotube Sheets Xu, Yifan; Zhang, Ye; Guo, Ziyang Angewandte Chemie International Edition, Vol. 54, Issue 51 https://doi.org/10.1002/anie.201508848	journal	October 2015
Elastomeric and Dynamic MnO ₂ /CNT Core-Shell Structure Coiled Yarn Supercapacitor Choi, Changsoon; Sim, Hyeon Jun; Spinks, Geoffrey M. Advanced Energy Materials, Vol. 6, Issue 5 https://doi.org/10.1002/aenm.201502119	journal	January 2016
Oxygen Reduction Electrocatalyst Based on Strongly Coupled Cobalt Oxide Nanocrystals and Carbon Nanotubes Liang, Yongye; Wang, Hailiang; Diao, Peng Journal of the American Chemical Society, Vol. 134, Issue 38 https://doi.org/10.1021/ja305623m	journal	September 2012
Fabrication of flexible and freestanding zinc chalcogenide single layers Sun, Yongfu; Sun, Zhihu; Gao, Shan Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2066	journal	January 2012
Wearable energy-dense and power-dense supercapacitor yarns enabled by scalable graphene–metallic textile composite electrodes Liu, Libin; Yu, You; Yan, Casey Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8260	journal	June 2015
An All-Solid-State Fiber-Shaped Aluminum-Air Battery with Flexibility, Stretchability, and High Electrochemical Performance Xu, Yifan; Zhao, Yang; Ren, Jing Angewandte Chemie International Edition, Vol. 55, Issue 28 https://doi.org/10.1002/anie.201601804	journal	May 2016
Nanocarbon Electrocatalysts for Oxygen Reduction in Alkaline Media for Advanced Energy Conversion and Storage Li, Qing; Cao, Ruiguo; Cho, Jaephil Advanced Energy Materials, Vol. 4, Issue 6 https://doi.org/10.1002/aenm.201301415	journal	January 2014
Controlled Functionalization of Carbonaceous Fibers for Asymmetric Solid-State Micro-Supercapacitors with High Volumetric Energy Density Yu, Dingshan; Goh, Kunli; Zhang, Qiang Advanced Materials, Vol. 26, Issue 39 https://doi.org/10.1002/adma.201403061	journal	September 2014
Atomically-thin non-layered cobalt oxide porous sheets for highly efficient oxygen-evolving electrocatalysts Sun, Yongfu; Gao, Shan; Lei, Fengcai Chemical Science, Vol. 5, Issue 10 https://doi.org/10.1039/C4SC00565A	journal	January 2014
Cobalt oxide-coated N- and B-doped graphene hollow spheres as bifunctional electrocatalysts for oxygen reduction and oxygen evolution reactions Jiang, Zhongqing; Jiang, Zhong-Jie; Maiyalagan, Thandavarayan Journal of Materials Chemistry A, Vol. 4, Issue 16 https://doi.org/10.1039/C6TA01349J	journal	January 2016
Pomegranate-Inspired Design of Highly Active and Durable Bifunctional Electrocatalysts for Rechargeable Metal-Air Batteries Li, Ge; Wang, Xiaolei; Fu, Jing Angewandte Chemie International Edition, Vol. 55, Issue 16 https://doi.org/10.1002/anie.201600750	journal	March 2016
N,P-Codoped Carbon Networks as Efficient Metal-free Bifunctional Catalysts for Oxygen Reduction and Hydrogen Evolution Reactions Zhang, Jintao; Qu, Liangti; Shi, Gaoquan Angewandte Chemie International Edition, Vol. 55, Issue 6 https://doi.org/10.1002/anie.201510495	journal	December 2015
Metallic Cobalt Nanoparticles Encapsulated in Nitrogen-Enriched Graphene Shells: Its Bifunctional Electrocatalysis and Application in Zinc-Air Batteries Zeng, Min; Liu, Yiling; Zhao, Feipeng Advanced Functional Materials, Vol. 26, Issue 24 https://doi.org/10.1002/adfm.201600636	journal	April 2016
Advanced zinc-air batteries based on high-performance hybrid electrocatalysts Li, Yanguang; Gong, Ming; Liang, Yongye Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2812	journal	May 2013
Elastic and Wearable Wire-Shaped Lithium-Ion Battery with High Electrochemical Performance Ren, Jing; Zhang, Ye; Bai, Wenyu Angewandte Chemie International Edition, Vol. 53, Issue 30 https://doi.org/10.1002/anie.201402388	journal	June 2014
All-Solid-State Cable-Type Flexible Zinc-Air Battery Park, Joohyuk; Park, Minjoon; Nam, Gyutae Advanced Materials, Vol. 27, Issue 8 https://doi.org/10.1002/adma.201404639	journal	December 2014
Covalent Hybrid of Spinel Manganese–Cobalt Oxide and Graphene as Advanced Oxygen Reduction Electrocatalysts Liang, Yongye; Wang, Hailiang; Zhou, Jigang Journal of the American Chemical Society, Vol. 134, Issue 7 https://doi.org/10.1021/ja210924t	journal	February 2012
Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes Wang, Zhong-Li; Xu, Dan; Xu, Ji-Jing Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60248F	journal	January 2014
In Situ Coupling of Strung Co ₄ N and Intertwined N–C Fibers toward Free-Standing Bifunctional Cathode for Robust, Efficient, and Flexible Zn–Air Batteries Meng, Fanlu; Zhong, Haixia; Bao, Di Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b05046	journal	August 2016
Phosphorus-Doped Graphitic Carbon Nitrides Grown In Situ on Carbon-Fiber Paper: Flexible and Reversible Oxygen Electrodes Ma, Tian Yi; Ran, Jingrun; Dai, Sheng Angewandte Chemie International Edition, Vol. 54, Issue 15 https://doi.org/10.1002/anie.201411125	journal	December 2014
Fabricating Continuous Supercapacitor Fibers with High Performances by Integrating All Building Materials and Steps into One Process Wang, Bingjie; Fang, Xin; Sun, Hao Advanced Materials, Vol. 27, Issue 47 https://doi.org/10.1002/adma.201503441	journal	October 2015
Scalable Fabrication of Nanoporous Carbon Fiber Films as Bifunctional Catalytic Electrodes for Flexible Zn-Air Batteries Liu, Qin; Wang, Yaobing; Dai, Liming Advanced Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adma.201506112	journal	February 2016
Flexible Supercapacitor Made of Carbon Nanotube Yarn with Internal Pores Choi, Changsoon; Lee, Jae Ah; Choi, A. Young Advanced Materials, Vol. 26, Issue 13 https://doi.org/10.1002/adma.201304736	journal	December 2013
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction Shao, Minhua; Chang, Qiaowan; Dodelet, Jean-Pol Chemical Reviews, Vol. 116, Issue 6 https://doi.org/10.1021/acs.chemrev.5b00462	journal	February 2016
3D Ordered Mesoporous Bifunctional Oxygen Catalyst for Electrically Rechargeable Zinc-Air Batteries Park, Moon Gyu; Lee, Dong Un; Seo, Min Ho Small, Vol. 12, Issue 20 https://doi.org/10.1002/smll.201600051	journal	April 2016
Advanced Extremely Durable 3D Bifunctional Air Electrodes for Rechargeable Zinc-Air Batteries Lee, Dong Un; Choi, Ja-Yeon; Feng, Kun Advanced Energy Materials, Vol. 4, Issue 6 https://doi.org/10.1002/aenm.201301389	journal	December 2013
Recent advances in free-standing two-dimensional crystals with atomic thickness: design, assembly and transfer strategies Zhang, Xiaodong; Xie, Yi Chemical Society Reviews, Vol. 42, Issue 21 https://doi.org/10.1039/c3cs60138b	journal	January 2013
Laminated Cross-Linked Nanocellulose/Graphene Oxide Electrolyte for Flexible Rechargeable Zinc-Air Batteries Zhang, Jing; Fu, Jing; Song, Xueping Advanced Energy Materials, Vol. 6, Issue 14 https://doi.org/10.1002/aenm.201600476	journal	May 2016
Carbon Nanotubes and Graphene for Flexible Electrochemical Energy Storage: from Materials to Devices Wen, Lei; Li, Feng; Cheng, Hui-Ming Advanced Materials, Vol. 28, Issue 22 https://doi.org/10.1002/adma.201504225	journal	January 2016
Surface-Tuned Co ₃ O ₄ Nanoparticles Dispersed on Nitrogen-Doped Graphene as an Efficient Cathode Electrocatalyst for Mechanical Rechargeable Zinc–Air Battery Application Singh, Santosh K.; Dhavale, Vishal M.; Kurungot, Sreekumar ACS Applied Materials & Interfaces, Vol. 7, Issue 38 https://doi.org/10.1021/acsami.5b04865	journal	September 2015
Recent advances in zinc–air batteries Li, Yanguang; Dai, Hongjie Chem. Soc. Rev., Vol. 43, Issue 15 https://doi.org/10.1039/C4CS00015C	journal	January 2014
Metallic Co ₄ N Porous Nanowire Arrays Activated by Surface Oxidation as Electrocatalysts for the Oxygen Evolution Reaction Chen, Pengzuo; Xu, Kun; Fang, Zhiwei Angewandte Chemie International Edition, Vol. 54, Issue 49 https://doi.org/10.1002/anie.201506480	journal	October 2015
Highly Active and Durable Nanocrystal-Decorated Bifunctional Electrocatalyst for Rechargeable Zinc-Air Batteries Lee, Dong Un; Park, Moon Gyu; Park, Hey Woong ChemSusChem, Vol. 8, Issue 18 https://doi.org/10.1002/cssc.201500609	journal	August 2015
Nitrogen-doped cobalt phosphate@nanocarbon hybrids for efficient electrocatalytic oxygen reduction Zhou, Tianhua; Du, Yonghua; Yin, Shengming Energy & Environmental Science, Vol. 9, Issue 8 https://doi.org/10.1039/C6EE01297C	journal	January 2016
Controlling the Active Sites of Sulfur-Doped Carbon Nanotube-Graphene Nanolobes for Highly Efficient Oxygen Evolution and Reduction Catalysis El-Sawy, Abdelhamid M.; Mosa, Islam M.; Su, Dong Advanced Energy Materials, Vol. 6, Issue 5 https://doi.org/10.1002/aenm.201501966	journal	December 2015
Co₃O₄ nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction Liang, Yongye; Li, Yanguang; Wang, Hailiang Nature Materials, Vol. 10, Issue 10, p. 780-786 https://doi.org/10.1038/nmat3087	journal	August 2011
Atomically-thick two-dimensional crystals: electronic structure regulation and energy device construction Sun, Yongfu; Gao, Shan; Xie, Yi Chem. Soc. Rev., Vol. 43, Issue 2 https://doi.org/10.1039/C3CS60231A	journal	January 2014
Morphologically controlled Co3O4 nanodisks as practical bi-functional catalyst for rechargeable zinc–air battery applications Lee, Dong Un; Scott, Jordan; Park, Hey Woong Electrochemistry Communications, Vol. 43 https://doi.org/10.1016/j.elecom.2014.03.020	journal	June 2014
A fiber-shaped aqueous lithium ion battery with high power density Zhang, Ye; Wang, Yuhang; Wang, Lie Journal of Materials Chemistry A, Vol. 4, Issue 23 https://doi.org/10.1039/C6TA03477B	journal	January 2016
Advances and challenges for flexible energy storage and conversion devices and systems Li, Lin; Wu, Zhong; Yuan, Shuang Energy & Environmental Science, Vol. 7, Issue 7 https://doi.org/10.1039/c4ee00318g	journal	January 2014
Advances in Wearable Fiber-Shaped Lithium-Ion Batteries Zhang, Ye; Zhao, Yang; Ren, Jing Advanced Materials, Vol. 28, Issue 22 https://doi.org/10.1002/adma.201503891	journal	December 2015
Room-Temperature Intercalation-Deintercalation Strategy Towards VO ₂ (B) Single Layers with Atomic Thickness Liu, Liang; Yao, Tao; Tan, Xiaogang Small, Vol. 8, Issue 24 https://doi.org/10.1002/smll.201201552	journal	August 2012
A Fiber Supercapacitor with High Energy Density Based on Hollow Graphene/Conducting Polymer Fiber Electrode Qu, Guoxing; Cheng, Jianli; Li, Xiaodong Advanced Materials, Vol. 28, Issue 19 https://doi.org/10.1002/adma.201600689	journal	March 2016
Metallic anodes for next generation secondary batteries Kim, Hansu; Jeong, Goojin; Kim, Young-Ugk Chemical Society Reviews, Vol. 42, Issue 23 https://doi.org/10.1039/c3cs60177c	journal	January 2013
Ordered mesoporous Co3O4 spinels as stable, bifunctional, noble metal-free oxygen electrocatalysts Sa, Young Jin; Kwon, Kyungjung; Cheon, Jae Yeong Journal of Materials Chemistry A, Vol. 1, Issue 34 https://doi.org/10.1039/c3ta11917c	journal	January 2013
Flexible Rechargeable Zinc-Air Batteries through Morphological Emulation of Human Hair Array Fu, Jing; Hassan, Fathy Mohamed; Li, Jingde Advanced Materials, Vol. 28, Issue 30 https://doi.org/10.1002/adma.201600762	journal	May 2016
Electrically Rechargeable Zinc-Air Batteries: Progress, Challenges, and Perspectives Fu, Jing; Cano, Zachary Paul; Park, Moon Gyu Advanced Materials, Vol. 29, Issue 7 https://doi.org/10.1002/adma.201604685	journal	November 2016
Co ₃ O ₄ nanoparticles decorated carbon nanofiber mat as binder-free air-cathode for high performance rechargeable zinc-air batteries Li, Bing; Ge, Xiaoming; Goh, F. W. Thomas Nanoscale, Vol. 7, Issue 5 https://doi.org/10.1039/C4NR05988C	journal	January 2015
Two-Dimensional Materials for Beyond-Lithium-Ion Batteries Peng, Lele; Zhu, Yue; Chen, Dahong Advanced Energy Materials, Vol. 6, Issue 11 https://doi.org/10.1002/aenm.201600025	journal	March 2016
Mn _x O _y /NC and Co _x O _y /NC Nanoparticles Embedded in a Nitrogen-Doped Carbon Matrix for High-Performance Bifunctional Oxygen Electrodes Masa, Justus; Xia, Wei; Sinev, Ilya Angewandte Chemie International Edition, Vol. 53, Issue 32 https://doi.org/10.1002/anie.201402710	journal	June 2014
Flexible High-Energy Polymer-Electrolyte-Based Rechargeable Zinc-Air Batteries Fu, Jing; Lee, Dong Un; Hassan, Fathy Mohamed Advanced Materials, Vol. 27, Issue 37 https://doi.org/10.1002/adma.201502853	journal	August 2015
Energy harvesting and storage in 1D devices Sun, Hao; Zhang, Ye; Zhang, Jing Nature Reviews Materials, Vol. 2, Issue 6 https://doi.org/10.1038/natrevmats.2017.23	journal	April 2017
Low Overpotential in Vacancy-Rich Ultrathin CoSe ₂ Nanosheets for Water Oxidation Liu, Youwen; Cheng, Hao; Lyu, Mengjie Journal of the American Chemical Society, Vol. 136, Issue 44 https://doi.org/10.1021/ja5085157	journal	October 2014
Co/CoO nanoparticles immobilized on Co–N-doped carbon as trifunctional electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions Zhang, Xian; Liu, Rongrong; Zang, Yipeng Chemical Communications, Vol. 52, Issue 35 https://doi.org/10.1039/C6CC02513G	journal	January 2016
Elastic and Wearable Wire-Shaped Lithium-Ion Battery with High Electrochemical Performance Ren, Jing; Zhang, Ye; Bai, Wenyu Angewandte Chemie, Vol. 126, Issue 30 https://doi.org/10.1002/ange.201402388	journal	June 2014
Phosphorus-Doped Graphitic Carbon Nitrides Grown In Situ on Carbon-Fiber Paper: Flexible and Reversible Oxygen Electrodes Ma, Tian Yi; Ran, Jingrun; Dai, Sheng Angewandte Chemie, Vol. 127, Issue 15 https://doi.org/10.1002/ange.201411125	journal	December 2014
Flexible, Stretchable, and Rechargeable Fiber-Shaped Zinc-Air Battery Based on Cross-Stacked Carbon Nanotube Sheets Xu, Yifan; Zhang, Ye; Guo, Ziyang Angewandte Chemie, Vol. 127, Issue 51 https://doi.org/10.1002/ange.201508848	journal	October 2015
N,P-Codoped Carbon Networks as Efficient Metal-free Bifunctional Catalysts for Oxygen Reduction and Hydrogen Evolution Reactions Zhang, Jintao; Qu, Liangti; Shi, Gaoquan Angewandte Chemie, Vol. 128, Issue 6 https://doi.org/10.1002/ange.201510495	journal	December 2015
An All-Solid-State Fiber-Shaped Aluminum-Air Battery with Flexibility, Stretchability, and High Electrochemical Performance Xu, Yifan; Zhao, Yang; Ren, Jing Angewandte Chemie, Vol. 128, Issue 28 https://doi.org/10.1002/ange.201601804	journal	May 2016
Metallic Co ₄ N Porous Nanowire Arrays Activated by Surface Oxidation as Electrocatalysts for the Oxygen Evolution Reaction Chen, Pengzuo; Xu, Kun; Fang, Zhiwei Angewandte Chemie, Vol. 127, Issue 49 https://doi.org/10.1002/ange.201506480	journal	October 2015
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In Situ Fabrication of Heterostructure on Nickel Foam with Tuned Composition for Enhancing Water‐Splitting Performance Zheng, Xuerong; Zhang, Yiqi; Liu, Hui Small, Vol. 14, Issue 50 https://doi.org/10.1002/smll.201803666	journal	October 2018
Nonsiliceous Mesoporous Materials: Design and Applications in Energy Conversion and Storage Wang, Yongfei; Guo, Hong; Luo, Xudong Small, Vol. 15, Issue 32 https://doi.org/10.1002/smll.201805277	journal	March 2019
General and Scalable Fabrication of Core–Shell Metal Sulfides@C Anchored on 3D N‐Doped Foam toward Flexible Sodium Ion Batteries Ma, Xiangdong; Xiong, Xunhui; Zou, Pinjuan Small, Vol. 15, Issue 45 https://doi.org/10.1002/smll.201903259	journal	September 2019
Surface and Interface Engineering: Molybdenum Carbide–Based Nanomaterials for Electrochemical Energy Conversion Ge, Riyue; Huo, Juanjuan; Sun, Mingjie Small https://doi.org/10.1002/smll.201903380	journal	September 2019
Oxygen Vacancy–Rich In‐Doped CoO/CoP Heterostructure as an Effective Air Cathode for Rechargeable Zn–Air Batteries Jin, Wei; Chen, Jianping; Liu, Bing Small, Vol. 15, Issue 46 https://doi.org/10.1002/smll.201904210	journal	September 2019
Designing Advanced Catalysts for Energy Conversion Based on Urea Oxidation Reaction Zhu, Bingjun; Liang, Zibin; Zou, Ruqiang Small, Vol. 16, Issue 7 https://doi.org/10.1002/smll.201906133	journal	January 2020
Self-templated nitrogen-doped mesoporous carbon decorated with double transition-metal active sites for enhanced oxygen electrode catalysis Qiao, Meng-Fei; Wang, Ying; Li, Lei Rare Metals, Vol. 39, Issue 7 https://doi.org/10.1007/s12598-019-01345-9	journal	December 2019
Energy autonomous electronic skin García Núñez, Carlos; Manjakkal, Libu; Dahiya, Ravinder npj Flexible Electronics, Vol. 3, Issue 1 https://doi.org/10.1038/s41528-018-0045-x	journal	January 2019
Electrochemical energy storage devices for wearable technology: a rationale for materials selection and cell design Sumboja, Afriyanti; Liu, Jiawei; Zheng, Wesley Guangyuan Chemical Society Reviews, Vol. 47, Issue 15 https://doi.org/10.1039/c8cs00237a	journal	January 2018
N,S-Atom-coordinated Co ₉ S ₈ trinary dopants within a porous graphene framework as efficient catalysts for oxygen reduction/evolution reactions Li, Yi; Zhou, Yazhou; Wen, Hejing Dalton Transactions, Vol. 47, Issue 42 https://doi.org/10.1039/c8dt02324g	journal	January 2018
Highly active bifunctional oxygen electrocatalysts derived from nickel– or cobalt–phytic acid xerogel for zinc–air batteries Wang, Shuai; Nam, Gyutae; Li, Ping Nanoscale, Vol. 10, Issue 33 https://doi.org/10.1039/c8nr04733b	journal	January 2018
Robust N-doped carbon aerogels strongly coupled with iron–cobalt particles as efficient bifunctional catalysts for rechargeable Zn–air batteries Fu, Gengtao; Liu, Yu; Chen, Yifan Nanoscale, Vol. 10, Issue 42 https://doi.org/10.1039/c8nr05812a	journal	January 2018
Controllable synthesis of nickel sulfide nanocatalysts and their phase-dependent performance for overall water splitting Zheng, Xuerong; Han, Xiaopeng; Zhang, Yiqi Nanoscale, Vol. 11, Issue 12 https://doi.org/10.1039/c8nr09902b	journal	January 2019
Methacrylated gelatin-embedded fabrication of 3D graphene-supported Co ₃ O ₄ nanoparticles for water splitting Zhuang, Minghao; Liu, Zhenjing; Ding, Yao Nanoscale, Vol. 11, Issue 14 https://doi.org/10.1039/c8nr10369k	journal	January 2019
Bifunctional electrocatalysts of MOF-derived Co–N/C on bamboo-like MnO nanowires for high-performance liquid- and solid-state Zn–air batteries Chen, Ya-Nan; Guo, Yibo; Cui, Huijuan Journal of Materials Chemistry A, Vol. 6, Issue 20 https://doi.org/10.1039/c8ta01859f	journal	January 2018
Subnanometer iron clusters confined in a porous carbon matrix for highly efficient zinc–air batteries Wu, Xin; Dong, Juncai; Qiu, Mei Nanoscale Horizons, Vol. 5, Issue 2 https://doi.org/10.1039/c9nh00510b	journal	January 2020
Co ₃ O ₄ nanosheets on zeolite-templated carbon as an efficient oxygen electrocatalyst for a zinc–air battery Bera, Raj Kumar; Park, Hongjun; Ryoo, Ryong Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/c9ta01482a	journal	January 2019
Nanostructured Co-based bifunctional electrocatalysts for energy conversion and storage: current status and perspectives Li, Shasha; Hao, Xiaogang; Abudula, Abuliti Journal of Materials Chemistry A, Vol. 7, Issue 32 https://doi.org/10.1039/c9ta04949e	journal	January 2019
Long-battery-life flexible zinc–air battery with near-neutral polymer electrolyte and nanoporous integrated air electrode Li, Yuan; Fan, Xiayue; Liu, Xiaorui Journal of Materials Chemistry A, Vol. 7, Issue 44 https://doi.org/10.1039/c9ta09137h	journal	January 2019
Enhanced performance of multi-dimensional CoS nanoflake/NiO nanosheet architecture with synergetic effect for asymmetric supercapacitor Yang, Yanqin; Li, Songzhan; Liu, Feng Nanotechnology, Vol. 29, Issue 45 https://doi.org/10.1088/1361-6528/aadd63	journal	September 2018
Review—Energy Autonomous Wearable Sensors for Smart Healthcare: A Review Dahiya, Abhishek Singh; Thireau, Jerome; Boudaden, Jamila Journal of The Electrochemical Society, Vol. 167, Issue 3 https://doi.org/10.1149/2.0162003jes	journal	January 2020
BCNO Nanosheet Supported Co ₃ O ₄ Nanoparticles as an Enhanced Electrocatalyst for Oxygen Evolution Reaction Ji, Xuefeng; Li, Yingxin; Jia, Xiaobo Journal of The Electrochemical Society, Vol. 166, Issue 6 https://doi.org/10.1149/2.0581906jes	journal	January 2019
Controlled Synthesis of Porous Co ₃ O ₄ Nanostructures for Efficient Electrochemical Sensing of Glucose Luo, Jiankang; Wu, Jun; Liu, Zheng Journal of Nanomaterials, Vol. 2019 https://doi.org/10.1155/2019/8346251	journal	September 2019
Investigation of the Environmental Stability of Poly(vinyl alcohol)–KOH Polymer Electrolytes for Flexible Zinc–Air Batteries Fan, Xiayue; Liu, Jie; Ding, Jia Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00678	journal	October 2019
Effective Oxygen Reduction Reaction Performance of FeCo Alloys In Situ Anchored on Nitrogen-Doped Carbon by the Microwave-Assistant Carbon Bath Method and Subsequent Plasma Etching Liu, Mincong; Yu, Feng; Ma, Cunhua Nanomaterials, Vol. 9, Issue 9 https://doi.org/10.3390/nano9091284	journal	September 2019
2D Nitrogen‐Doped Carbon Nanotubes/Graphene Hybrid as Bifunctional Oxygen Electrocatalyst for Long‐Life Rechargeable Zn–Air Batteries Xu, Yangyang; Deng, Peilin; Chen, Guangda Advanced Functional Materials, Vol. 30, Issue 6 https://doi.org/10.1002/adfm.201906081	journal	November 2019
A Confinement Strategy for Stabilizing ZIF-Derived Bifunctional Catalysts as a Benchmark Cathode of Flexible All-Solid-State Zinc-Air Batteries Zhu, Lin; Zheng, Dezhou; Wang, Zifan Advanced Materials, Vol. 30, Issue 45 https://doi.org/10.1002/adma.201805268	journal	September 2018
Identifying the Activation of Bimetallic Sites in NiCo ₂ S ₄ @g‐C ₃ N ₄ ‐CNT Hybrid Electrocatalysts for Synergistic Oxygen Reduction and Evolution Han, Xiaopeng; Zhang, Wei; Ma, Xiaoya Advanced Materials, Vol. 31, Issue 18 https://doi.org/10.1002/adma.201808281	journal	February 2019
Flexible 1D Batteries: Recent Progress and Prospects Zhu, Yun‐Hai; Yang, Xiao‐Yang; Liu, Tong Advanced Materials https://doi.org/10.1002/adma.201901961	journal	July 2019
Ultrafine Pt Nanoparticle-Decorated Pyrite-Type CoS ₂ Nanosheet Arrays Coated on Carbon Cloth as a Bifunctional Electrode for Overall Water Splitting Han, Xiaopeng; Wu, Xiaoyu; Deng, Yida Advanced Energy Materials, Vol. 8, Issue 24 https://doi.org/10.1002/aenm.201800935	journal	July 2018
Fe/Co Double Hydroxide/Oxide Nanoparticles on N-Doped CNTs as Highly Efficient Electrocatalyst for Rechargeable Liquid and Quasi-Solid-State Zinc-Air Batteries Wu, Mingjie; Wei, Qiliang; Zhang, Gaixia Advanced Energy Materials, Vol. 8, Issue 30 https://doi.org/10.1002/aenm.201801836	journal	September 2018
Electrode Materials for Rechargeable Zinc-Ion and Zinc-Air Batteries: Current Status and Future Perspectives Yang, Dan; Tan, Huiteng; Rui, Xianhong Electrochemical Energy Reviews, Vol. 2, Issue 3 https://doi.org/10.1007/s41918-019-00035-5	journal	May 2019
Monolithic heteronanomat paper air cathodes toward origami-foldable/rechargeable Zn–air batteries Lee, Donggue; Lee, Hansol; Gwon, Ohhun Journal of Materials Chemistry A, Vol. 7, Issue 42 https://doi.org/10.1039/c9ta07681f	journal	January 2019

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