Engineering efficient bifunctional electrocatalysts for rechargeable zinc–air batteries by confining Fe–Co–Ni nanoalloys in nitrogen-doped carbon nanotube@nanosheet frameworks

Tang, Xiannong; Cao, Rui; Li, Longbin; Huang, Bingyu; Zhai, Weijuan; Yuan, Kai; Chen, Yiwang

doi:10.1039/d0ta09580j

Engineering efficient bifunctional electrocatalysts for rechargeable zinc–air batteries by confining Fe–Co–Ni nanoalloys in nitrogen-doped carbon nanotube@nanosheet frameworks

Journal Article · Wed Nov 18 00:00:00 UTC 2020 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/d0ta09580j· OSTI ID:1767949

^[1]; Cao, Rui ^[2]; Li, Longbin ^[1]; Huang, Bingyu ^[1]; Zhai, Weijuan ^[1]; ^[1]; ^[3]

Nanchang Univ. (China)
SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
Nanchang Univ. (China); Jiangxi Normal Univ., Nanchang (China)

Developing precious-metal-free bifunctional oxygen reduction and evolution reaction (ORR/OER) electrocatalysts is of great significance for several key energy conversion and storage systems, yet remains a formidable challenge. In this work, we systematically designed Fe–Co–Ni trimetallic nanoalloys encapsulated in nitrogen-doped carbon nanotube@nanosheet frameworks (FeCoNi-NC) for application as effective bifunctional ORR/OER electrocatalysts. The rational structural design of FeCoNi-NC provides hierarchical porosity coupled with greatly increased effective electrochemical specific area for exposing abundant active sites and enhanced mass-transfer capability toward the ORR/OER. Experimental observations and theoretical calculations confirmed that Fe–Co–Ni nanoalloys interacting with pyridinic nitrogen-rich carbon synergistically optimized the adsorption/desorption free energies of oxygen intermediates, thus significantly enhancing the intrinsic ORR/OER activity. Consequently, FeCoNi-NC exhibits remarkable bifunctionality for the ORR (half-wave potential of 0.89 V) and OER (1.54 V at 10 mA cm^–2) with ΔE = 0.65 V, and even outperforms Pt/C–RuO₂ benchmarks. Moreover, the corresponding zinc–air battery shows large power density (315.2 mW cm^–2), high capacity (803.78 mA h g^–1 at 100 mA cm^–2) and excellent cycling durability (over 100 hours at 50 mA cm^–2), further testifying its practical applications. This work demonstrates an effective pathway to highly active non-precious-metal bifunctional catalysts toward sustainable energy technologies.

View Accepted Manuscript (DOE)

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: China Postdoctoral Science Foundation; National Natural Science Foundation of China (NNSFC); National Postdoctoral Program for Innovative Talents; Natural Science Foundation of Jiangxi Province; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1767949

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 48 Vol. 8; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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