Oxidation of tert-Butyl alcohol in a pulsed reactor
Journal Article
·
· Russian Journal of Applied Chemistry
OSTI ID:146497
- Kuznetsk Basin Polytechnic Inst. (Russian Federation)
The oxidation of tert-butyl alcohol, reduction of IK-9-4 catalyst by the alcohol, and oxidation of the catalyst by air were studied in a pulsed reactor at 573-633 K with the tert-butyl alcohol concentration varying in pulses of 0.5-0.7 vol. %. During the reduction of the catalyst by the tert-butyl alcohol stable adsorption of the alcohol was detected; upon contact with the air the alcohol gives only products of deep oxidation, while upon contact with the reaction mixture it gives methacrolein to a greater degree. It was determined that the mechanism of conversion of tert-butyl alcohol to methacrolein is a redox mechanism. 6 refs., 4 figs., 3 tabs.
- OSTI ID:
- 146497
- Journal Information:
- Russian Journal of Applied Chemistry, Journal Name: Russian Journal of Applied Chemistry Journal Issue: 2 Vol. 65; ISSN 1070-4272; ISSN RJACEO
- Country of Publication:
- United States
- Language:
- English
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