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Title: Novel graphene quantum dots (GQDs)-incorporated thin film composite (TFC) membranes for forward osmosis (FO) desalination

Journal Article · · Desalination

This paper reports a novel class of thin film composite (TFC) membranes for forward osmosis (FO) desalination. The TFC membranes were fabricated via interfacial polymerization (IP) of aqueous mixture of polyethyleneimine (PEI) and graphene quantum dots (GQDs) with organic solution of trimesoyl chloride (TMC) on modified polyacrylonitrile (PAN) ultrafiltration substrates. The chemical structures and morphologies of the synthesized GQDs and the GQDs-incorporated membranes were studied by various characterization techniques. The synthesized GQDs exhibited a narrow size distribution of 1.0–4.0 nm with an average size of 2.19 nm, and the thickness were one to three graphene layers. The results showed that GQDs nanoparticles were covalently bonded to the polyamide chains. The optimized TFC membrane with 0.050 wt% GQDs loading exhibited quite hydrophilic and neutrally charged membrane surface, along with an enhanced water flux of 12.9 L m–2 h–1 and a comparable reverse salt flux of 1.41 g m–2 h–1 when DI water and 0.5 M MgCl2 were used as the feed solution and the draw solution, respectively. Also, the optimized GQDs-incorporated TFC membrane presented an especially good anti-fouling performance. Furthermore, incorporating the novel graphene nanomaterial into polymer membranes may present its great potential application in desalination, purification and wastewater treatment.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1462857
Journal Information:
Desalination, Vol. 451, Issue C; ISSN 0011-9164
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 71 works
Citation information provided by
Web of Science

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Preparation and Characterization of Thin‐Film Nanocomposite Membrane Incorporated with MoO 3 Nanoparticles with High Flux Performance for Forward Osmosis journal July 2019
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