Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Stable solvent for solution-based electrical doping of semiconducting polymer films and its application to organic solar cells

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/c8ee00811f· OSTI ID:1476171

A solution-based method to electrically p-dope organic semiconductors enabling the fabrication of organic solar cells with simplified geometry is implemented with acetonitrile as an alternative to nitromethane.

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1476171
Alternate ID(s):
OSTI ID: 1441224
Journal Information:
Energy & Environmental Science, Journal Name: Energy & Environmental Science Journal Issue: 8 Vol. 11; ISSN EESNBY; ISSN 1754-5692
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

References (37)

Effects of Thermal Annealing Upon the Morphology of Polymer-Fullerene Blends journal August 2010
n-Doping of Organic Electronic Materials using Air-Stable Organometallics journal November 2011
Direct-Write Optical Patterning of P3HT Films Beyond the Diffraction Limit journal October 2016
Controlling Molecular Doping in Organic Semiconductors journal September 2017
High-Efficiency Polymer Solar Cells Enabled by Environment-Friendly Single-Solvent Processing journal January 2016
On-Fabrication Solid-State N-Doping of Graphene by an Electron-Transporting Metal Oxide Layer for Efficient Inverted Organic Solar Cells journal April 2016
Highly Efficient Organic Devices Based on Electrically Doped Transport Layers journal July 2007
Green-solvent-processable organic solar cells journal November 2016
Decamethylcobaltocene as an efficient n-dopant in organic electronic materials and devices journal October 2008
P-type doping of organic wide band gap materials by transition metal oxides: A case-study on Molybdenum trioxide journal August 2009
The chemical and structural origin of efficient p-type doping in P3HT journal May 2013
Investigation of p-dopant diffusion in polymer films and bulk heterojunctions: Stable spatially-confined doping for all-solution processed solar cells journal August 2015
The effect of thermal annealing on dopant site choice in conjugated polymers journal June 2016
Molecular Electrical Doping of Organic Semiconductors: Fundamental Mechanisms and Emerging Dopant Design Rules journal February 2016
Quantitative Dedoping of Conductive Polymers journal January 2017
Mixing Behavior in Small Molecule:Fullerene Organic Photovoltaics journal March 2017
Doped Organic Transistors journal October 2016
Optical Dedoping Mechanism for P3HT:F4TCNQ Mixtures journal October 2016
Measurement of Small Molecular Dopant F4TCNQ and C 60 F 36 Diffusion in Organic Bilayer Architectures journal December 2015
Design of Organic Semiconductors from Molecular Electrostatics journal February 2011
A Molybdenum Dithiolene Complex as p -Dopant for Hole-Transport Materials: A Multitechnique Experimental and Theoretical Investigation journal January 2010
Highly Efficient Organic Devices Based on Electrically Doped Transport Layers journal April 2007
Solution-based electrical doping of semiconducting polymer films over a limited depth journal December 2016
Universal energy level tailoring of self-organized hole extraction layers in organic solar cells and organic–inorganic hybrid perovskite solar cells journal January 2016
Simultaneous cross-linking and p-doping of a polymeric semiconductor film by immersion into a phosphomolybdic acid solution for use in organic solar cells journal January 2016
Organic photovoltaics journal January 2009
Direct correlation between work function of indium-tin-oxide electrodes and solar cell performance influenced by ultraviolet irradiation and air exposure journal January 2012
From lab to fab: how must the polymer solar cell materials design change? – an industrial perspective journal January 2014
Controlled p doping of the hole-transport molecular material N,N′-diphenyl-N,N′-bis(1-naphthyl)-1,1′-biphenyl-4,4′-diamine with tetrafluorotetracyanoquinodimethane journal July 2003
Solution doping of organic semiconductors using air-stable n-dopants journal February 2012
Effect of leakage current and shunt resistance on the light intensity dependence of organic solar cells journal February 2015
Optical spectroscopy of field-induced charge in self-organized high mobility poly(3-hexylthiophene) journal March 2001
Effect of interchain interactions on the absorption and emission of poly(3-hexylthiophene) journal February 2003
Hole doping by molecular oxygen in organic semiconductors: Band-structure calculations journal June 2007
Optical measurement of doping efficiency in poly(3-hexylthiophene) solutions and thin films journal February 2015
Nika : software for two-dimensional data reduction journal March 2012
Organic Photovoltaics audiovisual January 2015

Cited By (3)

Introducing a Nonvolatile N‐Type Dopant Drastically Improves Electron Transport in Polymer and Small‐Molecule Organic Transistors journal June 2019
Energetic disorder in perovskite/polymer solar cells and its relationship with the interfacial carrier losses
  • Yaghoobi Nia, Narges; Méndez, Maria; di Carlo, Aldo
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2152 https://doi.org/10.1098/rsta.2018.0315
journal July 2019
Molecular Doping for Hole Transporting Materials in Hybrid Perovskite Solar Cells journal December 2019

Figures / Tables (6)


Similar Records

Solution-based electrical doping of semiconducting polymer films over a limited depth
Journal Article · Sun Dec 04 19:00:00 EST 2016 · Nature Materials · OSTI ID:1579840

Solution-based electrical doping of organic photovoltaics with non-fullerene acceptors facilitated by solvent vapor pre-treatment
Journal Article · Sun Dec 31 19:00:00 EST 2023 · AIP Advances · OSTI ID:2578473