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Title: Complexation-assisted reduction: complexes of glutaroimide-dioxime with tetravalent actinides (Np( iv ) and Th( iv ))

Abstract

Glutaroimide-dioxime forms strong complexes with Np( iv ) and Th( iv ) in aqueous solution and in crystals. The formation of Np( iv ) complexes from initial Np( v ) is interpreted by a complexation-assisted reduction mechanism.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [1]
  1. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
  2. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Chemistry
  3. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1441041
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Journal Article: Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 24; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Zhang, Zhicheng, Parker, Bernard F., Lohrey, Trevor D., Teat, Simon J., Arnold, John, and Rao, Linfeng. Complexation-assisted reduction: complexes of glutaroimide-dioxime with tetravalent actinides (Np( iv ) and Th( iv )). United Kingdom: N. p., 2018. Web. doi:10.1039/C8DT01191E.
Zhang, Zhicheng, Parker, Bernard F., Lohrey, Trevor D., Teat, Simon J., Arnold, John, & Rao, Linfeng. Complexation-assisted reduction: complexes of glutaroimide-dioxime with tetravalent actinides (Np( iv ) and Th( iv )). United Kingdom. doi:10.1039/C8DT01191E.
Zhang, Zhicheng, Parker, Bernard F., Lohrey, Trevor D., Teat, Simon J., Arnold, John, and Rao, Linfeng. Mon . "Complexation-assisted reduction: complexes of glutaroimide-dioxime with tetravalent actinides (Np( iv ) and Th( iv ))". United Kingdom. doi:10.1039/C8DT01191E.
@article{osti_1441041,
title = {Complexation-assisted reduction: complexes of glutaroimide-dioxime with tetravalent actinides (Np( iv ) and Th( iv ))},
author = {Zhang, Zhicheng and Parker, Bernard F. and Lohrey, Trevor D. and Teat, Simon J. and Arnold, John and Rao, Linfeng},
abstractNote = {Glutaroimide-dioxime forms strong complexes with Np( iv ) and Th( iv ) in aqueous solution and in crystals. The formation of Np( iv ) complexes from initial Np( v ) is interpreted by a complexation-assisted reduction mechanism.},
doi = {10.1039/C8DT01191E},
journal = {Dalton Transactions},
number = 24,
volume = 47,
place = {United Kingdom},
year = {Mon Jan 01 00:00:00 EST 2018},
month = {Mon Jan 01 00:00:00 EST 2018}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on May 22, 2019
Publisher's Accepted Manuscript

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Works referenced in this record:

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Crystal structure refinement with SHELXL
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  • Sheldrick, George M.
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