Complexation-assisted reduction: complexes of glutaroimide-dioxime with tetravalent actinides (Np( iv ) and Th( iv ))

Zhang, Zhicheng; Parker, Bernard F.; Lohrey, Trevor D.; Teat, Simon J.; Arnold, John; Rao, Linfeng

doi:10.1039/C8DT01191E

Title: Complexation-assisted reduction: complexes of glutaroimide-dioxime with tetravalent actinides (Np( iv ) and Th( iv ))

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Dalton Transactions

DOI:https://doi.org/10.1039/C8DT01191E· OSTI ID:1441041

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Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA, Department of Chemistry
Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, USA

Glutaroimide-dioxime forms strong complexes with Np( iv ) and Th( iv ) in aqueous solution and in crystals. The formation of Np( iv ) complexes from initial Np( v ) is interpreted by a complexation-assisted reduction mechanism.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1441041

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Vol. 47 Journal Issue: 24; ISSN 1477-9226

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 15 works

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