Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution

Leggett, C. J.; Parker, B. F.; Teat, S. J.; Zhang, Z.; Dau, P. D.; Lukens, W. W.; Peterson, S. M.; Cardenas, A. J.  P.; Warner, M. G.; Gibson, J. K.; Arnold, J.; Rao, L.

doi:10.1039/c5sc03958d

Title: Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution

Journal Article · Thu Jan 14 00:00:00 EST 2016 · Chemical Science

DOI:https://doi.org/10.1039/c5sc03958d· OSTI ID:1377416

Leggett, C. J. ^[1]; Parker, B. F. ^[2]; Teat, S. J. ^[3]; Zhang, Z. ^[1]; Dau, P. D. ^[1]; Lukens, W. W. ^[1]; Peterson, S. M. ^[4]; Cardenas, A. J. P. ^[5]; Warner, M. G. ^[4]; Gibson, J. K. ^[1]; Arnold, J. ^[2]; Rao, L. ^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemistry
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). National Security Directorate
Fundamental and Computational Sciences Directorate; Pacific Northwest National Laboratory; Richland, USA

A “bare” V⁵⁺ complex with glutaroimide-dioxime (H₃L), a ligand for uranium recovery from seawater, was synthesized from aqueous solution as Na[V(L)₂]2H₂O and the structure determined by x-ray diffraction. It is the first non-oxo V(v) complex that has been directly synthesized in and crystallized from aqueous solution.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC02-05CH11231; AC05-76RL01830

OSTI ID:: 1377416

Alternate ID(s):: OSTI ID: 1337242

Report Number(s):: PNNL-SA-112588; CSHCBM; ark:/13030/qt2p03j1ms

Journal Information:: Chemical Science, Vol. 7, Issue 4; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 45 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
vanadium
uranium
seawater
amidoxime
XRD

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