Curtailing Perovskite Processing Limitations via Lamination at the Perovskite/Perovskite Interface

Dunfield, Sean P.; Moore, David T.; Klein, Talysa R.; Fabian, David M.; Christians, Jeffrey A.; Dixon, Alex G.; Dou, Benjia; Ardo, Shane; Beard, Matthew C.; Shaheen, Sean E.; Berry, Joseph J.; van Hest, Maikel F. A. M.

doi:10.1021/acsenergylett.8b00548

Curtailing Perovskite Processing Limitations via Lamination at the Perovskite/Perovskite Interface

Journal Article · Tue Apr 24 00:00:00 EDT 2018 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.8b00548· OSTI ID:1437221

^[1]; Moore, David T. ^[2]; ^[2]; Fabian, David M. ^[3]; ^[2]; Dixon, Alex G. ^[1]; ^[1]; ^[4]; ^[2]; Shaheen, Sean E. ^[5]; ^[1]; van Hest, Maikel F. A. M. ^[2]

National Renewable Energy Lab. (NREL), Golden, CO (United States); Univ. of Colorado, Boulder, CO (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States); Univ. of California, Irvine, CA (United States)
Univ. of California, Irvine, CA (United States)
Univ. of Colorado, Boulder, CO (United States)

Standard layer-by-layer solution processing methods constrain lead-halide perovskite device architectures. The layer below the perovskite must be robust to the strong organic solvents used to form the perovskite while the layer above has a limited thermal budget and must be processed in nonpolar solvents to prevent perovskite degradation. To circumvent these limitations, we developed a procedure where two transparent conductive oxide/transport material/perovskite half stacks are independently fabricated and then laminated together at the perovskite/perovskite interface. Using ultraviolet-visible absorption spectroscopy, external quantum efficiency, X-ray diffraction, and time-resolved photoluminesence spectroscopy, we show that this procedure improves photovoltaic properties of the perovskite layer. Applying this procedure, semitransparent devices employing two high-temperature oxide transport layers were fabricated, which realized an average efficiency of 9.6% (maximum: 10.6%) despite series resistance limitations from the substrate design. Overall, the developed lamination procedure curtails processing constraints, enables new device designs, and affords new opportunities for optimization.

View Accepted Manuscript (DOE)

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1437221

Report Number(s):: NREL/JA--5K00-71071

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 5 Vol. 3; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (35)

Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells Dualeh, Amalie; Tétreault, Nicolas; Moehl, Thomas Advanced Functional Materials, Vol. 24, Issue 21, p. 3250-3258 https://doi.org/10.1002/adfm.201304022	journal	February 2014
Square-Centimeter Solution-Processed Planar CH ₃ NH ₃ PbI ₃ Perovskite Solar Cells with Efficiency Exceeding 15% Yang, Mengjin; Zhou, Yuanyuan; Zeng, Yining Advanced Materials, Vol. 27, Issue 41 https://doi.org/10.1002/adma.201502586	journal	September 2015
Efficient Flexible Solar Cell based on Composition-Tailored Hybrid Perovskite Bi, Cheng; Chen, Bo; Wei, Haotong Advanced Materials, Vol. 29, Issue 30 https://doi.org/10.1002/adma.201605900	journal	June 2017
300% Enhancement of Carrier Mobility in Uniaxial-Oriented Perovskite Films Formed by Topotactic-Oriented Attachment Kim, Dong Hoe; Park, Jaehong; Li, Zhen Advanced Materials, Vol. 29, Issue 23 https://doi.org/10.1002/adma.201606831	journal	April 2017
Chemical and Electronic Structure Characterization of Lead Halide Perovskites and Stability Behavior under Different Exposures—A Photoelectron Spectroscopy Investigation Philippe, Bertrand; Park, Byung-Wook; Lindblad, Rebecka Chemistry of Materials, Vol. 27, Issue 5 https://doi.org/10.1021/acs.chemmater.5b00348	journal	February 2015
Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys Li, Zhen; Yang, Mengjin; Park, Ji-Sang Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04107	journal	December 2015
Melt Processing of Hybrid Organic–Inorganic Lead Iodide Layered Perovskites Li, Tianyang; Dunlap-Shohl, Wiley A.; Han, Qiwei Chemistry of Materials, Vol. 29, Issue 15 https://doi.org/10.1021/acs.chemmater.7b02363	journal	July 2017
Intriguing Optoelectronic Properties of Metal Halide Perovskites Manser, Joseph S.; Christians, Jeffrey A.; Kamat, Prashant V. Chemical Reviews, Vol. 116, Issue 21 https://doi.org/10.1021/acs.chemrev.6b00136	journal	June 2016
Mechanism of Pressure-Induced Phase Transitions, Amorphization, and Absorption-Edge Shift in Photovoltaic Methylammonium Lead Iodide Szafrański, Marek; Katrusiak, Andrzej The Journal of Physical Chemistry Letters, Vol. 7, Issue 17 https://doi.org/10.1021/acs.jpclett.6b01648	journal	August 2016
High-Performance Flexible Perovskite Solar Cells on Ultrathin Glass: Implications of the TCO Dou, Benjia; Miller, Elisa M.; Christians, Jeffrey A. The Journal of Physical Chemistry Letters, Vol. 8, Issue 19 https://doi.org/10.1021/acs.jpclett.7b02128	journal	September 2017
Influence of Electrode Interfaces on the Stability of Perovskite Solar Cells: Reduced Degradation Using MoO _x /Al for Hole Collection Sanehira, Erin M.; Tremolet de Villers, Bertrand J.; Schulz, Philip ACS Energy Letters, Vol. 1, Issue 1 https://doi.org/10.1021/acsenergylett.6b00013	journal	April 2016
Effect of Water Vapor, Temperature, and Rapid Annealing on Formamidinium Lead Triiodide Perovskite Crystallization Aguiar, Jeffery A.; Wozny, Sarah; Alkurd, Nooraldeen R. ACS Energy Letters, Vol. 1, Issue 1 https://doi.org/10.1021/acsenergylett.6b00042	journal	May 2016
Defect Tolerance in Methylammonium Lead Triiodide Perovskite Steirer, K. Xerxes; Schulz, Philip; Teeter, Glenn ACS Energy Letters, Vol. 1, Issue 2 https://doi.org/10.1021/acsenergylett.6b00196	journal	July 2016
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells Snaith, Henry J. The Journal of Physical Chemistry Letters, Vol. 4, Issue 21, p. 3623-3630 https://doi.org/10.1021/jz4020162	journal	October 2013
Preparation of Single-Phase Films of CH ₃ NH ₃ Pb(I _{1– x} Br _x ) ₃ with Sharp Optical Band Edges Sadhanala, Aditya; Deschler, Felix; Thomas, Tudor H. The Journal of Physical Chemistry Letters, Vol. 5, Issue 15 https://doi.org/10.1021/jz501332v	journal	July 2014
Sequential deposition as a route to high-performance perovskite-sensitized solar cells Burschka, Julian; Pellet, Norman; Moon, Soo-Jin Nature, Vol. 499, Issue 7458, p. 316-319 https://doi.org/10.1038/nature12340	journal	July 2013
Facile fabrication of large-grain CH3NH3PbI3−xBrx films for high-efficiency solar cells via CH3NH3Br-selective Ostwald ripening Yang, Mengjin; Zhang, Taiyang; Schulz, Philip Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12305	journal	August 2016
Transcending the slow bimolecular recombination in lead-halide perovskites for electroluminescence Xing, Guichuan; Wu, Bo; Wu, Xiangyang Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14558	journal	February 2017
Perovskite ink with wide processing window for scalable high-efficiency solar cells Yang, Mengjin; Li, Zhen; Reese, Matthew O. Nature Energy, Vol. 2, Issue 5 https://doi.org/10.1038/nenergy.2017.38	journal	March 2017
The emergence of perovskite solar cells Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J. Nature Photonics, Vol. 8, Issue 7, p. 506-514 https://doi.org/10.1038/nphoton.2014.134	journal	July 2014
Observation of a hot-phonon bottleneck in lead-iodide perovskites Yang, Ye; Ostrowski, David P.; France, Ryan M. Nature Photonics, Vol. 10, Issue 1 https://doi.org/10.1038/nphoton.2015.213	journal	October 2015
Tailored interfaces of unencapsulated perovskite solar cells for >1,000 hour operational stability Christians, Jeffrey A.; Schulz, Philip; Tinkham, Jonathan S. Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0067-y	journal	January 2018
Substrate-controlled band positions in CH ₃ NH ₃ PbI ₃ perovskite films Miller, Elisa M.; Zhao, Yixin; Mercado, Candy C. Phys. Chem. Chem. Phys., Vol. 16, Issue 40 https://doi.org/10.1039/C4CP03533J	journal	January 2014
Organic–inorganic hybrid lead halide perovskites for optoelectronic and electronic applications Zhao, Yixin; Zhu, Kai Chemical Society Reviews, Vol. 45, Issue 3 https://doi.org/10.1039/C4CS00458B	journal	January 2016
Review of recent progress in chemical stability of perovskite solar cells Niu, Guangda; Guo, Xudong; Wang, Liduo Journal of Materials Chemistry A, Vol. 3, Issue 17, p. 8970-8980 https://doi.org/10.1039/C4TA04994B	journal	December 2014
Perovskite solar cells: film formation and properties Song, Tze-Bin; Chen, Qi; Zhou, Huanping Journal of Materials Chemistry A, Vol. 3, Issue 17 https://doi.org/10.1039/C4TA05246C	journal	January 2015
Photo-excitation intensity dependent electron and hole injections from lead iodide perovskite to nanocrystalline TiO ₂ and spiro-OMeTAD Makuta, Satoshi; Liu, Maning; Endo, Masaru Chemical Communications, Vol. 52, Issue 4 https://doi.org/10.1039/C5CC06518F	journal	January 2016
Probing the degradation and homogeneity of embedded perovskite semiconducting layers in photovoltaic devices by Raman spectroscopy Hooper, K. E. A.; Lee, H. K. H.; Newman, M. J. Physical Chemistry Chemical Physics, Vol. 19, Issue 7 https://doi.org/10.1039/C6CP05123E	journal	January 2017
Enhanced perovskite morphology and crystallinity for high performance perovskite solar cells using a porous hole transport layer from polystyrene nanospheres Zhang, Fan; Song, Jun; Chen, Ming Physical Chemistry Chemical Physics, Vol. 18, Issue 48 https://doi.org/10.1039/C6CP06405A	journal	January 2016
Structural and chemical evolution of methylammonium lead halide perovskites during thermal processing from solution Nenon, David P.; Christians, Jeffrey A.; Wheeler, Lance M. Energy & Environmental Science, Vol. 9, Issue 6 https://doi.org/10.1039/C6EE01047D	journal	January 2016
In situ investigation of the formation and metastability of formamidinium lead tri-iodide perovskite solar cells Aguiar, Jeffery A.; Wozny, Sarah; Holesinger, Terry G. Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE01079B	journal	January 2016
A low viscosity, low boiling point, clean solvent system for the rapid crystallisation of highly specular perovskite films Noel, Nakita K.; Habisreutinger, Severin N.; Wenger, Bernard Energy & Environmental Science, Vol. 10, Issue 1 https://doi.org/10.1039/C6EE02373H	journal	January 2017
Strained hybrid perovskite thin films and their impact on the intrinsic stability of perovskite solar cells Zhao, Jingjing; Deng, Yehao; Wei, Haotong Science Advances, Vol. 3, Issue 11 https://doi.org/10.1126/sciadv.aao5616	journal	November 2017
Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells Yang, Woon Seok; Park, Byung-Wook; Jung, Eui Hyuk Science, Vol. 356, Issue 6345 https://doi.org/10.1126/science.aan2301	journal	June 2017

Cited By (3)

Laminated Perovskite Photovoltaics: Enabling Novel Layer Combinations and Device Architectures Schmager, Raphael; Roger, Julie; Schwenzer, Jonas A. Advanced Functional Materials, Vol. 30, Issue 9 https://doi.org/10.1002/adfm.201907481	journal	December 2019
PEDOT:PSS monolayers to enhance the hole extraction and stability of perovskite solar cells Hu, Lijun; Li, Meng; Yang, Ke Journal of Materials Chemistry A, Vol. 6, Issue 34 https://doi.org/10.1039/c8ta05234d	journal	January 2018
Laminated Perovskite Photovoltaics: Enabling Novel Layer Combinations and Device Architectures Schmager, Raphael; Roger, Julie; Schwenzer, Jonas A. Wiley-VCH Verlag https://doi.org/10.5445/ir/1000105051	text	January 2020

Figures / Tables (4)

Similar Records

Investigating the Effect of Lamination on FAMACs: Toward a New Phase Space of Perovskite Solar Cell Fabrication

Conference · Thu Oct 10 00:00:00 EDT 2019 · OSTI ID:1592386

Lamination of >21% Efficient Perovskite Solar Cells with Independent Process Control of Transport Layers and Interfaces

Journal Article · Thu Mar 21 20:00:00 EDT 2024 · ACS Applied Materials and Interfaces · OSTI ID:2345162

Understanding Process–Structure Relationships during Lamination of Halide Perovskite Interfaces

Journal Article · Mon Oct 14 20:00:00 EDT 2024 · ACS Applied Materials and Interfaces · OSTI ID:2475425

Related Subjects

14 SOLAR ENERGY
36 MATERIALS SCIENCE
lamination
perovskite
photovoltaics

Curtailing Perovskite Processing Limitations via Lamination at the Perovskite/Perovskite Interface

Citation Formats

References (35)

Cited By (3)

Figures / Tables (4)

Similar Records

Related Subjects