In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth

Van Vleet, Mary J.; Weng, Tingting; Li, Xinyi; Schmidt, J. R.

doi:10.1021/acs.chemrev.7b00582

In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth

Journal Article · Wed Mar 07 00:00:00 EST 2018 · Chemical Reviews

DOI:https://doi.org/10.1021/acs.chemrev.7b00582· OSTI ID:1433911

Van Vleet, Mary J. ^[1]; Weng, Tingting ^[2]; Li, Xinyi ^[2]; ^[2]

Univ. of Wisconsin, Madison, WI (United States). Theoretical Chemistry Inst. and Dept. of Chemistry; University of Wisconsin-Madison Department of Chemistry
Univ. of Wisconsin, Madison, WI (United States). Theoretical Chemistry Inst. and Dept. of Chemistry

The vast chemical and structural diversity of metal–organic frameworks (MOFs) opens up the exciting possibility of “crystal engineering” MOFs tailored for particular catalytic or separation applications. Yet the process of reaction discovery, optimization, and scale-up of MOF synthesis remains extremely challenging, presenting significant obstacles to the synthetic realization of many otherwise promising MOF structures. Recently, significant new insights into the fundamental processes governing MOF nucleation and growth, as well as the relationship between reaction parameters and synthetic outcome, have been derived using powerful in situ, time-resolved and/or mechanistic studies of MOF crystallization. This Review provides a summary and associated critical analysis of the results of these and other related “direct” studies of MOF nucleation and growth, with a particular emphasis on the recent advances in instrument technologies that have enabled such studies and on the major hypotheses, theories, and models that have been used to explain MOF formation. We conclude with a summary of the major insights that have been gained from the work summarized in this Review, outlining our own perspective on potential fruitful new directions for investigation.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0014059

OSTI ID:: 1433911

Journal Information:: Chemical Reviews, Journal Name: Chemical Reviews Journal Issue: 7 Vol. 118; ISSN 0009-2665

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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