Synchrotron‐Based X‐ray Absorption Fine Structures, X‐ray Diffraction, and X‐ray Microscopy Techniques Applied in the Study of Lithium Secondary Batteries

Li, Weihan; Li, Minsi; Hu, Yongfeng; Lu, Jun; Lushington, Andrew; Li, Ruying; Wu, Tianpin; Sham, Tsun‐Kong; Sun, Xueliang

doi:10.1002/smtd.201700341

Title: Synchrotron‐Based X‐ray Absorption Fine Structures, X‐ray Diffraction, and X‐ray Microscopy Techniques Applied in the Study of Lithium Secondary Batteries

Journal Article · Wed Apr 18 00:00:00 EDT 2018 · Small Methods

DOI:https://doi.org/10.1002/smtd.201700341· OSTI ID:1433551

Li, Weihan ^[1]; Li, Minsi ^[1]; Hu, Yongfeng ^[2]; Lu, Jun ^[3]; Lushington, Andrew ^[4]; Li, Ruying ^[4]; Wu, Tianpin ^[5]; Sham, Tsun‐Kong ^[6]; Sun, Xueliang ^[4]

Department of Mechanical and Materials Engineering University of Western Ontario London Ontario N6A 5B9 Canada, Department of Chemistry University of Western Ontario London Ontario N6A 5B7 Canada
Canadian Light Source 44 Innovation Boulevard Saskatoon Saskatchewan S7N 2V3 Canada
Chemical Science and Engineering Division Argonne National Laboratory 9700 South, Cass Avenue Lemont IL 60439 USA
Department of Mechanical and Materials Engineering University of Western Ontario London Ontario N6A 5B9 Canada
X‐ray Science Division Argonne National Laboratory 9700 South, Cass Avenue Lemont IL 60439 USA
Department of Chemistry University of Western Ontario London Ontario N6A 5B7 Canada

Abstract Owing to the recent advance of third‐generation synchrotron radiation (SR) sources, SR‐based X‐ray techniques have been widely applied to study lithium‐ion batteries, lithium–sulfur batteries, and lithium–oxygen batteries to solve material challenges. SR‐based techniques provide high chemical and physical sensitivity and a comprehensive picture of material structure and reaction mechanisms. An in‐depth understanding of batteries is imperative for the development of future energy storage devices with enhanced electrochemical performance to meet societies' growing need for devices with high energy density. Here, recent progress in the application of SR techniques for lithium secondary batteries with a focus on several techniques, including X‐ray absorption fine structure, synchrotron X‐ray diffraction, and synchrotron X‐ray microscopy techniques is reviewed. The working principle for all characterization techniques is introduced to provide context for how the technique is used in the field of energy storage. Through discussing the utilization of SR techniques in different directions of batteries, including electrodes, electrolytes, and interfaces, the practical application strategies of techniques in batteries are clarified. By summarizing and discussing the application of SR techniques in batteries, the aim is to highlight the crucial role of SR characterization in the development of advanced energy materials.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: DE‐AC02‐06CH11357

OSTI ID:: 1433551

Journal Information:: Small Methods, Journal Name: Small Methods Vol. 2 Journal Issue: 8; ISSN 2366-9608

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 42 works

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