Structural and chemical evolution in layered oxide cathodes of lithium-ion batteries revealed by synchrotron techniques

Qian, (钱冠男), Guannan; Wang, (汪君洋), Junyang; Li, (李泓), Hong; Ma, (马紫峰), Zi-Feng; Pianetta, Piero; Li, (李林森), Linsen; Yu, (禹习谦), Xiqian; Liu, (刘宜晋), Yijin

doi:10.1093/nsr/nwab146

Title: Structural and chemical evolution in layered oxide cathodes of lithium-ion batteries revealed by synchrotron techniques

Journal Article · Tue Aug 17 00:00:00 EDT 2021 · National Science Review

DOI:https://doi.org/10.1093/nsr/nwab146· OSTI ID:1844006

Qian, (钱冠男), Guannan;

; Li, (李泓), Hong; Ma, (马紫峰), Zi-Feng; Pianetta, Piero;

; Yu, (禹习谦), Xiqian; Liu, (刘宜晋), Yijin

Abstract Rechargeable battery technologies have revolutionized electronics, transportation and grid energy storage. Many materials are being researched for battery applications, with layered transition metal oxides (LTMO) the dominating cathode candidate with remarkable electrochemical performance. Yet, daunting challenges persist in the quest for further battery developments targeting lower cost, longer lifespan, improved energy density and enhanced safety. This is, in part, because of the intrinsic complexity of real-world batteries, featuring sophisticated interplay among microstructural, compositional and chemical heterogeneities, which has motivated tremendous research efforts using state-of-the-art analytical techniques. In this research field, synchrotron techniques have been identified as a suite of effective methods for advanced battery characterization in a non-destructive manner with sensitivities to the lattice, electronic and morphological structures. This article provides a holistic overview of cutting-edge developments in synchrotron-based research on LTMO battery cathode materials. We discuss the complexity and evolution of LTMO’s material properties upon battery operation and review recent synchrotron-based research works that address the frontier challenges and provide novel insights in this field. Finally, we formulate a perspective on future directions of synchrotron-based battery research, involving next-generation X-ray facilities and advanced computational developments.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1844006

Alternate ID(s):: OSTI ID: 1842367

Journal Information:: National Science Review, Journal Name: National Science Review Vol. 9 Journal Issue: 2; ISSN 2095-5138

Publisher:: Oxford University PressCopyright Statement

Country of Publication:: China

Language:: English

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