Pyrolytic Carbon Nanosheets for Ultrafast and Ultrastable Sodium‐Ion Storage

Cho, Se Youn; Kang, Minjee; Choi, Jaewon; Lee, Min Eui; Yoon, Hyeon Ji; Kim, Hae Jin; Leal, Cecilia; Lee, Sungho; Jin, Hyoung‐Joon; Yun, Young Soo

doi:10.1002/smll.201703043

Title: Pyrolytic Carbon Nanosheets for Ultrafast and Ultrastable Sodium‐Ion Storage

Journal Article · Tue Apr 03 00:00:00 EDT 2018 · Small

DOI:https://doi.org/10.1002/smll.201703043· OSTI ID:1431138

Cho, Se Youn ^[1]; Kang, Minjee ^[2]; Choi, Jaewon ^[3]; Lee, Min Eui ^[1]; Yoon, Hyeon Ji ^[1]; Kim, Hae Jin ^[4]; Leal, Cecilia ^[2]; Lee, Sungho ^[5]; Jin, Hyoung‐Joon ^[1]; Yun, Young Soo ^[6]

Department of Polymer Science and Engineering Inha University Incheon 402‐751 South Korea
Department of Materials Science and Engineering University of Illinois at Urbana − Champaign Urbana IL 61801 USA
Institute of Advanced Composite Materials Korea Institute of Science and Technology (KIST) 92 Chudong‐ro, Bongdong‐eup Wanju‐gun Jeonbuk 55324 South Korea
Division of Electron Microscopic Research Korea Basic Science Institute Daejeon 34133 South Korea
Carbon Composite Materials Research Center Korea Institute of Science and Technology 92 Chudong‐ro, Bongdong‐eup Wanju‐gun Jeonbuk 55324 South Korea
Department of Chemical Engineering Kangwon National University Samcheok 245‐711 South Korea

Abstract Na‐ion cointercalation in the graphite host structure in a glyme‐based electrolyte represents a new possibility for using carbon‐based materials (CMs) as anodes for Na‐ion storage. However, local microstructures and nanoscale morphological features in CMs affect their electrochemical performances; they require intensive studies to achieve high levels of Na‐ion storage performances. Here, pyrolytic carbon nanosheets (PCNs) composed of multitudinous graphitic nanocrystals are prepared from renewable bioresources by heating. In particular, PCN‐2800 prepared by heating at 2800 °C has a distinctive sp ² carbon bonding nature, crystalline domain size of ≈44.2 Å, and high electrical conductivity of ≈320 S cm ⁻¹ , presenting significantly high rate capability at 600 C (60 A g ⁻¹ ) and stable cycling behaviors over 40 000 cycles as an anode for Na‐ion storage. The results of this study show the unusual graphitization behaviors of a char‐type carbon precursor and exceptionally high rate and cycling performances of the resulting graphitic material, PCN‐2800, even surpassing those of supercapacitors.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: DE‐AC02‐06CH11357

OSTI ID:: 1431138

Journal Information:: Small, Journal Name: Small Vol. 14 Journal Issue: 17; ISSN 1613-6810

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 21 works

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