Importance of interlayer H bonding structure to the stability of layered minerals

Conroy, Michele; Soltis, Jennifer A.; Wittman, Rick S.; Smith, Frances N.; Chatterjee, Sayandev; Zhang, Xin; Ilton, Eugene S.; Buck, Edgar C.

doi:10.1038/S41598-017-13452-7

Title: Importance of interlayer H bonding structure to the stability of layered minerals

Journal Article · Mon Oct 16 00:00:00 EDT 2017 · Scientific Reports

DOI:https://doi.org/10.1038/S41598-017-13452-7· OSTI ID:1430728

Conroy, Michele ^[1]; Soltis, Jennifer A. ^[2]; Wittman, Rick S. ^[3]; Smith, Frances N. ^[1]; Chatterjee, Sayandev ^[1]; Zhang, Xin ^[2]; Ilton, Eugene S. ^[2]; Buck, Edgar C. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Energy and Environment Directorate
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical and Computational Sciences Directorate
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). National Security Directorate

The exact atomic structures of layered minerals have been difficult to characterize because the layers often possess out-of-plane hydrogen atoms that cannot be detected by many analytical techniques. However, the ordering of these bonds are thought to play a fundamental role in the structural stability and solubility of layered minerals. We report a new strategy of using the intense radiation field of a focused electron beam to probe the effect of differences in hydrogen bonding networks on mineral solubility while simultaneously imaging the dissolution behavior in real time via liquid cell electron microscopy. We show the loss in hydrogens from interlayers of boehmite (?-AlOOH) resulted in 2D nanosheets exfoliating from the bulk that subsequently and rapidly dissolved. However gibbsite (?-Al(OH)3), with its higher concentration of OH terminating groups, was more accommodating to the deprotonation and stable under the beam.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5); USDOE Office of Science (SC), Biological and Environmental Research (BER); PNNL Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1430728

Alternate ID(s):: OSTI ID: 1512401

Report Number(s):: PNNL-SA-126728; PII: 13452

Journal Information:: Scientific Reports, Vol. 7; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 36 works

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Title: Importance of interlayer H bonding structure to the stability of layered minerals

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