Metal–Organic Frameworks for Separation

Zhao, Xiang; Wang, Yanxiang; Li, Dong‐Sheng; Bu, Xianhui; Feng, Pingyun

doi:10.1002/adma.201705189

Title: Metal–Organic Frameworks for Separation

Journal Article · Tue Mar 27 00:00:00 EDT 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201705189· OSTI ID:1429933

Zhao, Xiang ^[1]; Wang, Yanxiang ^[1]; Li, Dong‐Sheng ^[2]; Bu, Xianhui ^[3];

^[1]

Department of Chemistry University of California Riverside CA 92521 USA
Department of Chemistry and Biochemistry California State University Long Beach 1250 Bellflower Boulevard Long Beach CA 90840 USA
College of Materials and Chemical Engineering Hubei Provincial Collaborative Innovation Center for New Energy Microgrid Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University Yichang 443002 China

Abstract Separation is an important industrial step with critical roles in the chemical, petrochemical, pharmaceutical, and nuclear industries, as well as in many other fields. Although much progress has been made, the development of better separation technologies, especially through the discovery of high‐performance separation materials, continues to attract increasing interest due to concerns over factors such as efficiency, health and environmental impacts, and the cost of existing methods. Metal–organic frameworks (MOFs), a rapidly expanding family of crystalline porous materials, have shown great promise to address various separation challenges due to their well‐defined pore size and unprecedented tunability in both composition and pore geometry. In the past decade, extensive research is performed on applications of MOF materials, including separation and capture of many gases and vapors, and liquid‐phase separation involving both liquid mixtures and solutions. MOFs also bring new opportunities in enantioselective separation and are amenable to morphological control such as fabrication of membranes for enhanced separation outcomes. Here, some of the latest progress in the applications of MOFs for several key separation issues, with emphasis on newly synthesized MOF materials and the impact of their compositional and structural features on separation properties, are reviewed and highlighted.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: DE‐SC0010596

OSTI ID:: 1429933

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Vol. 30 Journal Issue: 37; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 622 works

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