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Title: Process Design and Techno-economic Analysis for Materials to Treat Produced Waters

Journal Article · · Industrial and Engineering Chemistry Research
 [1];  [1];  [2];  [2];  [2]
  1. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
  2. Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Significant quantities of water are produced during enhanced oil recovery making these “produced water” streams attractive candidates for treatment and reuse. However, high concentrations of dissolved silica raise the propensity for fouling. In this paper, we report the design and economic analysis for a new ion exchange process using calcined hydrotalcite (HTC) to remove silica from water. This process improves upon known technologies by minimizing sludge product, reducing process fouling, and lowering energy use. Process modeling outputs included raw material requirements, energy use, and the minimum water treatment price (MWTP). Monte Carlo simulations quantified the impact of uncertainty and variability in process inputs on MWTP. These analyses showed that cost can be significantly reduced if the HTC materials are optimized. Specifically, R&D improving HTC reusability, silica binding capacity, and raw material price can reduce MWTP by 40%, 13%, and 20%, respectively. Optimizing geographic deployment further improves cost competitiveness.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
DOE Contract Number:
AC04-94AL85000; NA0003525
OSTI ID:
1429640
Report Number(s):
SAND-2017-10521J; 657393
Journal Information:
Industrial and Engineering Chemistry Research, Vol. 58, Issue 32; ISSN 0888-5885
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (19)

Increasing agricultural water use efficiency to meet future food production journal December 2000
Water scarcity: Fact or fiction? journal February 2006
Long-Term Aridity Changes in the Western United States journal November 2004
Ongoing drought-induced uplift in the western United States journal August 2014
Injection-Induced Earthquakes journal July 2013
Chemical treatment technologies for waste-water recycling—an overview journal January 2012
Estimated use of water in the United States in 2010 report January 2014
Removal of Silica from Water journal April 1940
Pretreatment and the effect of cations and anions on prevention of silica fouling journal September 2001
Silica removal using ion-exchange resins journal August 2004
Silica Nanoparticle Separation from Water by Aggregation with AlCl 3 journal July 2011
Ion exchange membranes State of their development and perspective journal October 2005
Drawbacks of applying nanofiltration and how to avoid them: A review journal October 2008
Towards zero liquid discharge in the presence of silica: Stable 98% recovery in nanofiltration and reverse osmosis journal January 2015
Removal of dissolved silica from industrial waters using inorganic ion exchangers journal June 2017
Exceptional selectivity for dissolved silicas in industrial waters using mixed oxides journal December 2017
Synthesis, Characterization, and Ion Exchange Properties of Hydrotalcite Mg6Al2(OH)16(A)x(A‘)2-x·4H2O (A, A‘ = Cl-, Br-, I-, and NO3-, 2 ≥x≥ 0) Derivatives journal September 2003
Thermal, texture and reconstruction properties of hydrotalcites substituted with Na+ or K+ ions journal February 2015
Memory effect of hydrotalcites and its impact on cyanoethylation reaction journal June 2013