A Chromium Hydroxide/MIL‐101(Cr) MOF Composite Catalyst and Its Use for the Selective Isomerization of Glucose to Fructose

Guo, Qiang; Ren, Limin; Kumar, Prashant; Cybulskis, Viktor J.; Mkhoyan, K. Andre; Davis, Mark E.; Tsapatsis, Michael

doi:10.1002/ange.201712818

Title: A Chromium Hydroxide/MIL‐101(Cr) MOF Composite Catalyst and Its Use for the Selective Isomerization of Glucose to Fructose

Journal Article · Fri Mar 23 00:00:00 EDT 2018 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201712818· OSTI ID:1429152

Guo, Qiang ^[1]; Ren, Limin ^[1]; Kumar, Prashant ^[1]; Cybulskis, Viktor J. ^[2]; Mkhoyan, K. Andre ^[1]; Davis, Mark E. ^[2];

^[1]

Department of Chemical Engineering and Materials Science University of Minnesota 421 Washington Ave SE Minneapolis MN 55455 USA
Chemical Engineering California Institute of Technology Pasadena CA 91125 USA

Abstract A metal–organic framework (MOF)‐based catalyst, chromium hydroxide/MIL‐101(Cr), was prepared by a one‐pot synthesis method. The combination of chromium hydroxide particles on and within Lewis acidic MIL‐101 accomplishes highly selective conversion of glucose to fructose in the presence of ethanol, matching the performance of optimized Sn‐containing Lewis acidic zeolites. Differently from zeolites, NMR spectroscopy studies with isotopically labeled molecules demonstrate that isomerization of glucose to fructose on this catalyst, proceeds predominantly via a proton transfer mechanism.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0001004

OSTI ID:: 1429152

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 130 Journal Issue: 18; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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