In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes

Siegel, D. A.; El Gabaly, F.; McCarty, K. F.; Bartelt, N. C.

doi:10.1103/PhysRevB.92.125421

In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes

Journal Article · Tue Sep 15 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.92.125421· OSTI ID:1426893

Siegel, D. A. ^[1]; El Gabaly, F. ^[1]; McCarty, K. F. ^[1]; Bartelt, N. C. ^[1]

Sandia National Laboratories (SNL-CA), Livermore, CA (United States). Materials Physics Dept.

The electrochemical reactions of solid oxide fuel cells occur in the region where gas-phase species, electrode, and electrolyte coincide. When the electrode is an ionic insulator and the electrolyte is an electronic insulator, this triple phase boundary is assumed to have atomic dimensions. For this study, we use photoemission electron microscopy to show that the reduced surface of the electrolyte yttria-stabilized zirconia (YSZ) has a sharp electronic metal-insulator boundary near Pt negative electrodes. The electronic conductivity of the reduced YSZ allows for oxygen reduction, allowing the reduced YSZ to behave as an extended triple phase boundary. This extended triple phase boundary can be many microns in size, depending on oxygen pressure, temperature, applied voltage, and time.

View Journal Article

Research Organization:: Sandia National Laboratories (SNL-CA), Livermore, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

DOE Contract Number:: AC04-94AL85000

OSTI ID:: 1426893

Report Number(s):: SAND2014--17609J; 537445

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Issue: 12 Vol. 92; ISSN 1098-0121; ISSN PRBMDO

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

References (27)

Measuring individual overpotentials in an operating solid-oxide electrochemical cell El Gabaly, Farid; Grass, Michael; McDaniel, Anthony H. Physical Chemistry Chemical Physics, Vol. 12, Issue 38 https://doi.org/10.1039/c003581e	journal	January 2010
Microspectroscopy at a moving reduction front in zirconia solid electrolyte Luerßen, B.; Janek, J.; Günther, S. Physical Chemistry Chemical Physics, Vol. 4, Issue 12 https://doi.org/10.1039/b109893d	journal	May 2002
Investigation of O2 reduction on Pt/YSZ by means of thin film microelectrodes: The geometry dependence of the electrode impedance Opitz, Alexander K.; Fleig, Jürgen Solid State Ionics, Vol. 181, Issue 15-16 https://doi.org/10.1016/j.ssi.2010.03.017	journal	June 2010
Measuring fundamental properties in operating solid oxide electrochemical cells by using in situ X-ray photoelectron spectroscopy Zhang, Chunjuan; Grass, Michael E.; McDaniel, Anthony H. Nature Materials, Vol. 9, Issue 11 https://doi.org/10.1038/nmat2851	journal	September 2010
Measuring oxygen reduction/evolution reactions on the nanoscale Kumar, Amit; Ciucci, Francesco; Morozovska, Anna N. Nature Chemistry, Vol. 3, Issue 9 https://doi.org/10.1038/nchem.1112	journal	August 2011
Ion and mixed conducting oxides as catalysts Gellings, P. J.; Bouwmeester, H. J. M. Catalysis Today, Vol. 12, Issue 1 https://doi.org/10.1016/0920-5861(92)80046-P	journal	February 1992
Electrochemical blackening of yttria-stabilized zirconia â€“ morphological instability of the moving reaction front Janek, J. Solid State Ionics, Vol. 116, Issue 3-4 https://doi.org/10.1016/S0167-2738(98)00415-9	journal	January 1999
Theoretical analysis of space charge layer formation at metal/ionic conductor interfaces Kasamatsu, Shusuke; Tada, Tomofumi; Watanabe, Satoshi Solid State Ionics, Vol. 183, Issue 1 https://doi.org/10.1016/j.ssi.2010.11.022	journal	February 2011
Growth mode and oxidation state analysis of individual cerium oxide islands on Ru(0001) Flege, J. I.; Kaemena, B.; Senanayake, S. D. Ultramicroscopy, Vol. 130 https://doi.org/10.1016/j.ultramic.2013.04.007	journal	July 2013
Electronic properties of ion-implanted yttria-stabilized zirconia Vohrer, U.; Wiemhofer, H.; Gopel, W. Solid State Ionics, Vol. 59, Issue 1-2 https://doi.org/10.1016/0167-2738(93)90240-4	journal	January 1993
Reducing over potential by surface mixed ionic–electronic conduction Rutman, J.; Raz, S.; Riess, I. Solid State Ionics, Vol. 177, Issue 19-25 https://doi.org/10.1016/j.ssi.2006.04.012	journal	October 2006
Reduced-Temperature Solid Oxide Fuel Cell Based on YSZ Thin-Film Electrolyte de Souza, Selmar Journal of The Electrochemical Society, Vol. 144, Issue 3 https://doi.org/10.1149/1.1837484	journal	January 1997
Microscopic and Nanoscopic Three-Phase-Boundaries of Platinum Thin-Film Electrodes on YSZ Electrolyte Ryll, Thomas; Galinski, Henning; Schlagenhauf, Lukas Advanced Functional Materials, Vol. 21, Issue 3 https://doi.org/10.1002/adfm.201001729	journal	December 2010
In situ imaging of electrode processes on solid electrolytes by photoelectron microscopy and microspectroscopy – the role of the three-phase boundary Janek, J.; Luerßen, B.; Mutoro, E. Topics in Catalysis, Vol. 44, Issue 3 https://doi.org/10.1007/s11244-006-0132-4	journal	June 2007
Blackening in yttria stabilized zirconia due to cathodic processes at solid platinum electrodes Casselton, R. E. W. Journal of Applied Electrochemistry, Vol. 4, Issue 1 https://doi.org/10.1007/BF00615903	journal	February 1974
Physical Chemistry of Ionic Materials: Ions and Electrons in Solids Maier, Joachim https://doi.org/10.1002/0470020229	book	April 2004
Model for the Electrical Conductivity of Reduced Stabilized Zirconia Levy, M. Journal of The Electrochemical Society, Vol. 135, Issue 6 https://doi.org/10.1149/1.2096057	journal	January 1988
Color-center-induced band-gap shift in yttria-stabilized zirconia PaiVerneker, V. R.; Petelin, A. N.; Crowne, F. J. Physical Review B, Vol. 40, Issue 12 https://doi.org/10.1103/PhysRevB.40.8555	journal	October 1989
Charge transfer at oxygen/zirconia interface at elevated temperatures: Part 1: Basic properties and terms Nowotny, J.; Bak, T.; Nowotny, M. K. Advances in Applied Ceramics, Vol. 104, Issue 4 https://doi.org/10.1179/174367605X20199	journal	August 2005
Decomposition of Nitric Oxide on Zirconia in a Solid-State Electrochemical Cell Gür, Turgut M. Journal of The Electrochemical Society, Vol. 126, Issue 6 https://doi.org/10.1149/1.2129175	journal	January 1979
In-situ Photoelectron Microspectroscopy and Imaging of Electrochemical Processes at the Electrodes of a Self-driven Cell Bozzini, Benedetto; Amati, Matteo; Gregoratti, Luca Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02848	journal	October 2013
Photoluminescence-spectra study of yttria-stabilized zirconia: Temperature dependence Paje, S. E.; Llopis, J. Applied Physics A Solids and Surfaces, Vol. 57, Issue 3 https://doi.org/10.1007/BF00332593	journal	September 1993
Relation between solid oxide electrolyte surface properties and electrode reaction kinetics Schouler, E. J. L. Solid State Ionics, Vol. 9-10 https://doi.org/10.1016/0167-2738(83)90115-7	journal	December 1983
Visualization of oxygen reduction sites at Pt electrodes on YSZ by means of 18O tracer incorporation: the width of the electrochemically active zone Opitz, Alexander Karl; Schintlmeister, Arno; Hutter, Herbert Physical Chemistry Chemical Physics, Vol. 12, Issue 39 https://doi.org/10.1039/c0cp00309c	journal	January 2010
In Situ X-Ray Spectromicroscopy Investigation of the Material Stability of SOFC Metal Interconnects in Operating Electrochemical Cells Bozzini, Benedetto; Tondo, Elisabetta; Prasciolu, Mauro ChemSusChem, Vol. 4, Issue 8 https://doi.org/10.1002/cssc.201100140	journal	June 2011
Experimental study of single triple-phase-boundary and platinum–yttria stabilized zirconia composite as cathodes for micro-solid oxide fuel cells Yan, Yan; Sandu, Silviu Cosmin; Conde, Janine Journal of Power Sources, Vol. 206 https://doi.org/10.1016/j.jpowsour.2012.01.113	journal	May 2012
Electrochemical promotion of catalytic reactions Imbihl, R. Progress in Surface Science, Vol. 85, Issue 5-8 https://doi.org/10.1016/j.progsurf.2010.07.001	journal	May 2010

Similar Records

The role of 8 mol % yttria stabilized zirconia in the improvement of electrochemical performance of lanthanum manganite composite electrodes

Journal Article · Mon Jun 01 00:00:00 EDT 1998 · Journal of the Electrochemical Society · OSTI ID:653348

Conditioning effects on La1-xSrxMnO3-Yttria stabilized Zirconia electrodes for thin-film solid oxide fuel cells

Technical Report · Thu Dec 05 23:00:00 EST 2002 · OSTI ID:810538

Reactive sputter deposition of yttria-stabilized zirconia

Conference · Mon May 01 00:00:00 EDT 1995 · OSTI ID:95300

Related Subjects

30 DIRECT ENERGY CONVERSION
36 MATERIALS SCIENCE

In situ characterization of the formation of a mixed conducting phase on the surface of yttria-stabilized zirconia near Pt electrodes

Citation Formats

References (27)

Similar Records

Related Subjects