Thermally activated delayed fluorescence of a Zr-based metal–organic framework

Mieno, H.; Kabe, R.; Allendorf, M. D.; Adachi, C.

doi:10.1039/C7CC08595H

Title: Thermally activated delayed fluorescence of a Zr-based metal–organic framework

Journal Article · Fri Dec 22 00:00:00 EST 2017 · ChemComm

DOI:https://doi.org/10.1039/C7CC08595H· OSTI ID:1421615

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Kyushu Univ. (Japan). Center for Organic Photonics and Electronics Research (OPERA)
Kyushu Univ. (Japan). Center for Organic Photonics and Electronics Research (OPERA); Kyushu Univ. (Japan). Japan Science and Technology Agency (JST), ERATO, Adachi Molecular Exciton Engineering Project
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Kyushu Univ. (Japan). Center for Organic Photonics and Electronics Research (OPERA); Kyushu Univ. (Japan). Japan Science and Technology Agency (JST), ERATO, Adachi Molecular Exciton Engineering Project; Kyushu Univ. (Japan). International Inst. for Carbon Neutral Energy Research (WPI-I2CNER)

Here, the first metal–organic framework exhibiting thermally activated delayed fluorescence (TADF) was developed. The zirconium-based framework (UiO-68-dpa) uses a newly designed linker composed of a terphenyl backbone, an electron-accepting carboxyl group, and an electron-donating diphenylamine and exhibits green TADF emission with a photoluminescence quantum yield of 30% and high thermal stability.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1421615

Report Number(s):: SAND-2017-12341J; CHCOFS; 658757

Journal Information:: ChemComm, Vol. 54, Issue 6; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 23 works

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Cited By (2)

Advanced Photoresponsive Materials Using the Metal–Organic Framework Approach Haldar, Ritesh; Heinke, Lars; Wöll, Christof Advanced Materials, Vol. 32, Issue 20 https://doi.org/10.1002/adma.201905227	journal	November 2019
Advanced Photoresponsive Materials Using the Metal–Organic Framework Approach Haldar, Ritesh; Heinke, Lars; Wöll, Christof Wiley https://doi.org/10.5445/ir/1000100622	text	January 2020

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