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Title: Operando Spectromicroscopy of Sulfur Species in Lithium-Sulfur Batteries

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/2.0091801jes· OSTI ID:1407716
ORCiD logo [1]; ORCiD logo [2];  [1];  [3]; ORCiD logo [1]
  1. SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource
  2. SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource; Stanford Univ., CA (United States). Dept. of Materials Science and Engineering
  3. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Joint Center for Energy Storage Research

Abstract not provided.

Research Organization:
SLAC National Accelerator Lab., Menlo Park, CA (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1407716
Alternate ID(s):
OSTI ID: 1472266
Report Number(s):
SAND2018-9772J
Journal Information:
Journal of the Electrochemical Society, Vol. 165, Issue 1; ISSN 0013-4651
Publisher:
The Electrochemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 17 works
Citation information provided by
Web of Science

References (49)

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In Situ Raman Spectroscopy of Sulfur Speciation in Lithium–Sulfur Batteries journal January 2015
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Recent progress and remaining challenges in sulfur-based lithium secondary batteries – a review journal January 2013
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Shuttle phenomenon – The irreversible oxidation mechanism of sulfur active material in Li–S battery journal August 2013
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Stabilizing lithium–sulphur cathodes using polysulphide reservoirs journal May 2011
Ab Initio Structure Search and in Situ 7 Li NMR Studies of Discharge Products in the Li–S Battery System journal November 2014
Best Practices for Operando Battery Experiments: Influences of X-ray Experiment Design on Observed Electrochemical Reactivity journal May 2015
Understanding the degradation mechanism of rechargeable lithium/sulfur cells: a comprehensive study of the sulfur–graphene oxide cathode after discharge–charge cycling journal January 2014
Operando Characterization of Intermediates Produced in a Lithium-Sulfur Battery journal January 2015
Analytical Detection of Polysulfides in the Presence of Adsorption Additives by Operando X-ray Absorption Spectroscopy journal August 2015
Towards Stable Lithium-Sulfur Batteries with a Low Self-Discharge Rate: Ion Diffusion Modulation and Anode Protection journal June 2015
Rechargeable Lithium–Sulfur Batteries journal July 2014
Understanding the Charging Mechanism of Lithium-Sulfur Batteries Using Spatially Resolved Operando X-Ray Absorption Spectroscopy journal January 2016
Solvate Ionic Liquid Electrolyte for Li–S Batteries journal January 2013
Polysulfide dissolution control: the common ion effect journal January 2013
Suppression of degradation for lithium iron phosphate cylindrical batteries by nano silicon surface modification journal January 2017
X-ray Absorption Spectroscopy Characterization of a Li/S Cell journal January 2016
Emerging In Situ and Operando Nanoscale X-Ray Imaging Techniques for Energy Storage Materials journal February 2015
Polysulfide Shuttle Study in the Li/S Battery System journal January 2004
A Lithium/Dissolved Sulfur Battery with an Organic Electrolyte journal January 1979
In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries journal March 2012
Status and prospects in sulfur–carbon composites as cathode materials for rechargeable lithium–sulfur batteries journal October 2015
New Approaches for High Energy Density Lithium–Sulfur Battery Cathodes journal June 2012
Three-Dimensional Growth of Li 2 S in Lithium–Sulfur Batteries Promoted by a Redox Mediator journal December 2015
Balancing surface adsorption and diffusion of lithium-polysulfides on nonconductive oxides for lithium–sulfur battery design journal April 2016
Recent Advances in Electrolytes for Lithium-Sulfur Batteries journal April 2015
Sulfur Speciation in Li–S Batteries Determined by Operando X-ray Absorption Spectroscopy journal September 2013
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Identification of lithium–sulfur battery discharge products through 6Li and 33S solid-state MAS and 7Li solution NMR spectroscopy journal January 2015
Lithium Sulfur Battery: Oxidation/Reduction Mechanisms of Polysulfides in THF Solutions journal January 1988
Exploring 3D microstructural evolution in Li-Sulfur battery electrodes using in-situ X-ray tomography journal October 2016
X-ray Absorption Spectra of Dissolved Polysulfides in Lithium–Sulfur Batteries from First-Principles journal April 2014
Direct observation of lithium polysulfides in lithium–sulfur batteries using operando X-ray diffraction journal May 2017
In operando scanning electron microscopy and ultraviolet–visible spectroscopy studies of lithium/sulfur cells using all solid-state polymer electrolyte journal July 2016
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Characterization of Polysulfide Radicals Present in an Ether-Based Electrolyte of a Lithium-Sulfur Battery During Initial Discharge Using In Situ X-Ray Absorption Spectroscopy Experiments and First-Principles Calculations journal June 2015
Li–O2 and Li–S batteries with high energy storage journal January 2012
Ionic Conduction in Lithium Ion Battery Composite Electrode Governs Cross-sectional Reaction Distribution journal May 2016
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New insight into the working mechanism of lithium–sulfur batteries: in situ and operando X-ray diffraction characterization journal January 2013
In situ monitoring the viscosity change of an electrolyte in a Li–S battery journal January 2017
The Li–S battery: an investigation of redox shuttle and self-discharge behaviour with LiNO 3 -containing electrolytes journal January 2016
High Energy Density Lithium-Sulfur Batteries: Challenges of Thick Sulfur Cathodes journal March 2015

Cited By (5)

The Absence and Importance of Operando Techniques for Metal‐Free Catalysts journal November 2018
A Lithium-Sulfur Cell Based on Reversible Lithium Deposition from a Li 2 S Cathode Host onto a Hostless-Anode Substrate journal July 2018
Deciphering the Reaction Mechanism of Lithium–Sulfur Batteries by In Situ/Operando Synchrotron‐Based Characterization Techniques journal March 2019
Polysulfide Speciation in the Bulk Electrolyte of a Lithium Sulfur Battery journal January 2018
Rate Constants of Electrochemical Reactions in a Lithium-Sulfur Cell Determined by Operando X-ray Absorption Spectroscopy journal January 2018