Elastocaloric cooling of additive manufactured shape memory alloys with large latent heat

Hou, Huilong; Simsek, Emrah; Stasak, Drew; Hasan, Naila Al; Qian, Suxin; Ott, Ryan; Cui, Jun; Takeuchi, Ichiro

doi:10.1088/1361-6463/aa85bf

Elastocaloric cooling of additive manufactured shape memory alloys with large latent heat

Journal Article · Fri Aug 11 00:00:00 EDT 2017 · Journal of Physics. D, Applied Physics

DOI:https://doi.org/10.1088/1361-6463/aa85bf· OSTI ID:1407483

^[1]; Simsek, Emrah ^[2]; ^[1]; Hasan, Naila Al ^[1]; Qian, Suxin ^[3]; Ott, Ryan ^[2]; Cui, Jun ^[4]; Takeuchi, Ichiro ^[1]

Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering
Ames Lab., Ames, IA (United States)
Xi'an Jiaotong Univ., Xi'an (China). Dept. of Refrigeration and Cryogenic Engineering
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering

The stress-induced martensitic phase transformation of shape memory alloys (SMAs) is the basis for elastocaloric cooling. In this paper, we employ additive manufacturing to fabricate TiNi SMAs, and demonstrate compressive elastocaloric cooling in the TiNi rods with transformation latent heat as large as 20 J g^-1. Adiabatic compression on as-fabricated TiNi displays cooling ΔT as high as -7.5 °C with recoverable superelastic strain up to 5%. Unlike conventional SMAs, additive manufactured TiNi SMAs exhibit linear superelasticity with narrow hysteresis in stress–strain curves under both adiabatic and isothermal conditions. Microstructurally, we find that there are Ti₂Ni precipitates typically one micron in size with a large aspect ratio enclosing the TiNi matrix. Finally, a stress transfer mechanism between reversible phase transformation in the TiNi matrix and mechanical deformation in Ti₂Ni precipitates is believed to be the origin of the unique superelasticity behavior.

View Accepted Manuscript (DOE)

Research Organization:: Ames Lab., Ames, IA (United States); Univ. of Maryland, College Park, MD (United States); Xi'an Jiaotong Univ., Xi'an (China)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Advanced Manufacturing Office (EE-5A); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-07CH11358; AR0000131

OSTI ID:: 1407483

Alternate ID(s):: OSTI ID: 22665126

Report Number(s):: IS-J--9455

Journal Information:: Journal of Physics. D, Applied Physics, Journal Name: Journal of Physics. D, Applied Physics Journal Issue: 40 Vol. 50; ISSN 0022-3727

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

References (62)

The Elastocaloric Effect: A Way to Cool Efficiently Tušek, Jaka; Engelbrecht, Kurt; Millán-Solsona, Rubén Advanced Energy Materials, Vol. 5, Issue 13 https://doi.org/10.1002/aenm.201500361	journal	May 2015
Fabrication of porous NiTi shape memory alloy structures using laser engineered net shaping Krishna, B. Vamsi; Bose, Susmita; Bandyopadhyay, Amit Journal of Biomedical Materials Research Part B: Applied Biomaterials, Vol. 89B, Issue 2 https://doi.org/10.1002/jbm.b.31238	journal	May 2009
Experimental studies on selective laser melting of metallic parts Meier, H.; Haberland, Ch. Materialwissenschaft und Werkstofftechnik, Vol. 39, Issue 9 https://doi.org/10.1002/mawe.200800327	journal	September 2008
Application of Laser Engineered Net Shaping (LENS) to manufacture porous and functionally graded structures for load bearing implants Bandyopadhyay, Amit; Krishna, B. V.; Xue, Weichang Journal of Materials Science: Materials in Medicine, Vol. 20, Issue S1 https://doi.org/10.1007/s10856-008-3478-2	journal	June 2008
In Situ Synthesis and Characterization of Shape Memory Alloy Nitinol by Laser Direct Deposition Halani, Pratik R.; Shin, Yung C. Metallurgical and Materials Transactions A, Vol. 43, Issue 2 https://doi.org/10.1007/s11661-011-0890-x	journal	September 2011
Microstructure of Ti-48.2 at. Pct Ni shape memory thin films Ishida, A.; Ogawa, K.; Sato, M. Metallurgical and Materials Transactions A, Vol. 28, Issue 10 https://doi.org/10.1007/s11661-997-0155-x	journal	October 1997
Local Evolution of the Elastocaloric Effect in TiNi-Based Films Ossmer, H.; Chluba, C.; Gueltig, M. Shape Memory and Superelasticity, Vol. 1, Issue 2 https://doi.org/10.1007/s40830-015-0014-3	journal	May 2015
Thermal Stabilization of NiTiCuV Shape Memory Alloys: Observations During Elastocaloric Training Schmidt, Marvin; Ullrich, Johannes; Wieczorek, André Shape Memory and Superelasticity, Vol. 1, Issue 2 https://doi.org/10.1007/s40830-015-0021-4	journal	June 2015
Ultra-Low Fatigue Quaternary TiNi-Based Films for Elastocaloric Cooling Chluba, C.; Ossmer, H.; Zamponi, C. Shape Memory and Superelasticity, Vol. 2, Issue 1 https://doi.org/10.1007/s40830-016-0054-3	journal	February 2016
Properties of Cu-Based Shape-Memory Alloys Prepared by Selective Laser Melting Gustmann, T.; dos Santos, J. M.; Gargarella, P. Shape Memory and Superelasticity, Vol. 3, Issue 1 https://doi.org/10.1007/s40830-016-0088-6	journal	December 2016
Stress dependence of the hysteresis in single crystal NiTi alloys Hamilton, R. F.; Sehitoglu, H.; Chumlyakov, Y. Acta Materialia, Vol. 52, Issue 11 https://doi.org/10.1016/j.actamat.2004.03.038	journal	June 2004
Influence of Ni on martensitic phase transformations in NiTi shape memory alloys Frenzel, J.; George, E. P.; Dlouhy, A. Acta Materialia, Vol. 58, Issue 9 https://doi.org/10.1016/j.actamat.2010.02.019	journal	May 2010
Size effects in shape memory alloy microwires Chen, Ying; Schuh, Christopher A. Acta Materialia, Vol. 59, Issue 2 https://doi.org/10.1016/j.actamat.2010.09.057	journal	January 2011
Evolution of temperature profiles in TiNi films for elastocaloric cooling Ossmer, H.; Lambrecht, F.; Gültig, M. Acta Materialia, Vol. 81 https://doi.org/10.1016/j.actamat.2014.08.006	journal	December 2014
On the effect of alloy composition on martensite start temperatures and latent heats in Ni–Ti-based shape memory alloys Frenzel, J.; Wieczorek, A.; Opahle, I. Acta Materialia, Vol. 90 https://doi.org/10.1016/j.actamat.2015.02.029	journal	May 2015
Elastocaloric effect in Ni 50 Fe 19 Ga 27 Co 4 single crystals Xiao, Fei; Jin, Mingjiang; Liu, Jian Acta Materialia, Vol. 96 https://doi.org/10.1016/j.actamat.2015.05.054	journal	September 2015
Elastocaloric cooling potential of NiTi, Ni2FeGa, and CoNiAl Pataky, Garrett J.; Ertekin, Elif; Sehitoglu, Huseyin Acta Materialia, Vol. 96 https://doi.org/10.1016/j.actamat.2015.06.011	journal	September 2015
Review of alternative cooling technologies Steven Brown, J.; Domanski, Piotr A. Applied Thermal Engineering, Vol. 64, Issue 1-2 https://doi.org/10.1016/j.applthermaleng.2013.12.014	journal	March 2014
Dynamic operation of an active magnetic regenerator (AMR): Numerical optimization of a packed-bed AMR Tušek, Jaka; Kitanovski, Andrej; Prebil, Ivan International Journal of Refrigeration, Vol. 34, Issue 6 https://doi.org/10.1016/j.ijrefrig.2011.04.007	journal	September 2011
Scientific test setup for investigation of shape memory alloy based elastocaloric cooling processes Schmidt, Marvin; Schütze, Andreas; Seelecke, Stefan International Journal of Refrigeration, Vol. 54 https://doi.org/10.1016/j.ijrefrig.2015.03.001	journal	June 2015
Thermodynamics cycle analysis and numerical modeling of thermoelastic cooling systems Qian, Suxin; Ling, Jiazhen; Hwang, Yunho International Journal of Refrigeration, Vol. 56 https://doi.org/10.1016/j.ijrefrig.2015.04.001	journal	August 2015
Performance enhancement of a compressive thermoelastic cooling system using multi-objective optimization and novel designs Qian, Suxin; Alabdulkarem, Abdullah; Ling, Jiazhen International Journal of Refrigeration, Vol. 57 https://doi.org/10.1016/j.ijrefrig.2015.04.012	journal	September 2015
Not-in-kind cooling technologies: A quantitative comparison of refrigerants and system performance Qian, Suxin; Nasuta, Dennis; Rhoads, Adam International Journal of Refrigeration, Vol. 62 https://doi.org/10.1016/j.ijrefrig.2015.10.019	journal	February 2016
Load transfer in phase transforming matrix–nanowire composite revealing the significant load carrying capacity of the nanowires Yu, Cun; Liu, Zhenyang; Liu, Yinong Materials & Design, Vol. 89 https://doi.org/10.1016/j.matdes.2015.10.029	journal	January 2016
Phase transformation characteristics and mechanical characterization of nitinol synthesized by laser direct deposition Halani, Pratik R.; Kaya, Irfan; Shin, Yung C. Materials Science and Engineering: A, Vol. 559 https://doi.org/10.1016/j.msea.2012.09.031	journal	January 2013
Local strain matching between Nb nanowires and a phase transforming NiTi matrix in an in-situ composite Liu, Zhenyang; Liu, Yinong; Jiang, Daqiang Materials Science and Engineering: A, Vol. 610 https://doi.org/10.1016/j.msea.2014.05.041	journal	July 2014
Anisotropic microstructure and superelasticity of additive manufactured NiTi alloy bulk builds using laser directed energy deposition Bimber, Beth A.; Hamilton, Reginald F.; Keist, Jayme Materials Science and Engineering: A, Vol. 674 https://doi.org/10.1016/j.msea.2016.07.059	journal	September 2016
Physical metallurgy of Ti–Ni-based shape memory alloys Otsuka, K.; Ren, X. Progress in Materials Science, Vol. 50, Issue 5 https://doi.org/10.1016/j.pmatsci.2004.10.001	journal	July 2005
Manufacturing and processing of NiTi implants: A review Elahinia, Mohammad H.; Hashemi, Mahdi; Tabesh, Majid Progress in Materials Science, Vol. 57, Issue 5 https://doi.org/10.1016/j.pmatsci.2011.11.001	journal	June 2012
Fabrication of NiTi through additive manufacturing: A review Elahinia, Mohammad; Shayesteh Moghaddam, Narges; Taheri Andani, Mohsen Progress in Materials Science, Vol. 83 https://doi.org/10.1016/j.pmatsci.2016.08.001	journal	October 2016
A review of regenerative heat exchange methods for various cooling technologies Qian, Suxin; Yu, Jianlin; Yan, Gang Renewable and Sustainable Energy Reviews, Vol. 69 https://doi.org/10.1016/j.rser.2016.11.180	journal	March 2017
Spatial characterization of the thermal-induced phase transformation throughout as-deposited additive manufactured NiTi bulk builds Hamilton, Reginald F.; Palmer, Todd A.; Bimber, Beth A. Scripta Materialia, Vol. 101 https://doi.org/10.1016/j.scriptamat.2015.01.018	journal	May 2015
Giant elastocaloric effect in directionally solidified Ni–Mn–In magnetic shape memory alloy Huang, Y. J.; Hu, Q. D.; Bruno, N. M. Scripta Materialia, Vol. 105 https://doi.org/10.1016/j.scriptamat.2015.04.024	journal	August 2015
Large elastocaloric effect at small transformation strain in Ni45Mn44Sn11 metamagnetic shape memory alloys Sun, Wen; Liu, Jian; Lu, Binfeng Scripta Materialia, Vol. 114 https://doi.org/10.1016/j.scriptamat.2015.11.021	journal	March 2016
NiTi thin films prepared by biased target ion beam deposition co-sputtering from elemental Ni and Ti targets Hou, Huilong; Hamilton, Reginald F.; Horn, Mark W. Thin Solid Films, Vol. 570 https://doi.org/10.1016/j.tsf.2014.09.004	journal	November 2014
A regenerative elastocaloric heat pump Tušek, Jaka; Engelbrecht, Kurt; Eriksen, Dan Nature Energy, Vol. 1, Issue 10 https://doi.org/10.1038/nenergy.2016.134	journal	September 2016
Caloric materials near ferroic phase transitions Moya, X.; Kar-Narayan, S.; Mathur, N. D. Nature Materials, Vol. 13, Issue 5 https://doi.org/10.1038/nmat3951	journal	April 2014
Origin of high strength, low modulus superelasticity in nanowire-shape memory alloy composites Zhang, Xudong; Zong, Hongxiang; Cui, Lishan Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep46360	journal	April 2017
Phase-stress partition and stress-induced martensitic transformation in NbTi/NiTi nanocomposite Hao, S. J.; Jiang, D. Q.; Cui, L. S. Applied Physics Letters, Vol. 99, Issue 8 https://doi.org/10.1063/1.3629768	journal	August 2011
Demonstration of high efficiency elastocaloric cooling with large ΔT using NiTi wires Cui, Jun; Wu, Yiming; Muehlbauer, Jan Applied Physics Letters, Vol. 101, Issue 7 https://doi.org/10.1063/1.4746257	journal	August 2012
High cyclic stability of the elastocaloric effect in sputtered TiNiCu shape memory films Bechtold, C.; Chluba, C.; Lima de Miranda, R. Applied Physics Letters, Vol. 101, Issue 9 https://doi.org/10.1063/1.4748307	journal	August 2012
Elastocaloric and magnetocaloric effects in Ni-Mn-Sn(Cu) shape-memory alloy Castillo-Villa, Pedro O.; Mañosa, Lluís; Planes, Antoni Journal of Applied Physics, Vol. 113, Issue 5 https://doi.org/10.1063/1.4790140	journal	February 2013
Significant elastocaloric effect in a Fe-31.2Pd (at. %) single crystal Xiao, Fei; Fukuda, Takashi; Kakeshita, Tomoyuki Applied Physics Letters, Vol. 102, Issue 16 https://doi.org/10.1063/1.4803168	journal	April 2013
Large temperature span and giant refrigerant capacity in elastocaloric Cu-Zn-Al shape memory alloys Mañosa, Lluís; Jarque-Farnos, Segio; Vives, Eduard Applied Physics Letters, Vol. 103, Issue 21 https://doi.org/10.1063/1.4832339	journal	November 2013
Large entropy change associated with the elastocaloric effect in polycrystalline Ni-Mn-Sb-Co magnetic shape memory alloys Millán-Solsona, Rubén; Stern-Taulats, Enric; Vives, Eduard Applied Physics Letters, Vol. 105, Issue 24 https://doi.org/10.1063/1.4904419	journal	December 2014
Elastocaloric effect of Ni-Ti wire for application in a cooling device Tušek, J.; Engelbrecht, K.; Mikkelsen, L. P. Journal of Applied Physics, Vol. 117, Issue 12 https://doi.org/10.1063/1.4913878	journal	March 2015
Large and reversible elastocaloric effect in dual-phase Ni ₅₄ Fe ₁₉ Ga ₂₇ superelastic alloys Xu, Yang; Lu, Binfeng; Sun, Wen Applied Physics Letters, Vol. 106, Issue 20 https://doi.org/10.1063/1.4921531	journal	May 2015
Stress transfer during different deformation stages in a nano-precipitate-strengthened Ni-Ti shape memory alloy Dong, Y. H.; Cong, D. Y.; Nie, Z. H. Applied Physics Letters, Vol. 107, Issue 20 https://doi.org/10.1063/1.4935691	journal	November 2015
Elastocaloric cooling processes: The influence of material strain and strain rate on efficiency and temperature span Schmidt, Marvin; Schütze, Andreas; Seelecke, Stefan APL Materials, Vol. 4, Issue 6 https://doi.org/10.1063/1.4953433	journal	June 2016
Giant elastocaloric effect covering wide temperature range in columnar-grained Cu _71.5 Al _17.5 Mn ₁₁ shape memory alloy Xu, Sheng; Huang, Hai-You; Xie, Jianxin APL Materials, Vol. 4, Issue 10 https://doi.org/10.1063/1.4964621	journal	October 2016
Strengthening of Ti-Ni shape-memory films by coherent subnanometric plate precipitates Kajiwara, S. Philosophical Magazine Letters, Vol. 74, Issue 3 https://doi.org/10.1080/095008396180281	journal	September 1996
Design of a hydraulically driven compressive elastocaloric cooling system Qian, Suxin; Geng, Yunlong; Wang, Yi Science and Technology for the Built Environment, Vol. 22, Issue 5 https://doi.org/10.1080/23744731.2016.1171630	journal	March 2016
Thermomechanical characterization of Ni-rich NiTi fabricated by selective laser melting Saedi, Soheil; Turabi, Ali Sadi; Andani, Mohsen Taheri Smart Materials and Structures, Vol. 25, Issue 3 https://doi.org/10.1088/0964-1726/25/3/035005	journal	February 2016
Energy-efficient miniature-scale heat pumping based on shape memory alloys Ossmer, Hinnerk; Wendler, Frank; Gueltig, Marcel Smart Materials and Structures, Vol. 25, Issue 8 https://doi.org/10.1088/0964-1726/25/8/085037	journal	July 2016
Elastocaloric effect in CuAlZn and CuAlMn shape memory alloys under compression Qian, Suxin; Geng, Yunlong; Wang, Yi Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2074 https://doi.org/10.1098/rsta.2015.0309	journal	August 2016
Elastocaloric Effect Associated with the Martensitic Transition in Shape-Memory Alloys Bonnot, Erell; Romero, Ricardo; Mañosa, Lluís Physical Review Letters, Vol. 100, Issue 12 https://doi.org/10.1103/PhysRevLett.100.125901	journal	March 2008
Tips and Tricks for Characterizing Shape Memory Alloy Wire: part 2-Fundamental Isothermal Responses Churchill, C. B.; Shaw, J. A.; Iadicola, M. A. Experimental Techniques, Vol. 33, Issue 1 https://doi.org/10.1111/j.1747-1567.2008.00460.x	journal	January 2009
A Transforming Metal Nanocomposite with Large Elastic Strain, Low Modulus, and High Strength Hao, Shijie; Cui, Lishan; Jiang, Daqiang Science, Vol. 339, Issue 6124, p. 1191-1194 https://doi.org/10.1126/science.1228602	journal	March 2013
Solid state refrigeration: Cooling and refrigeration using crystalline phase changes in metal alloys Quarini, J.; Prince, A. Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science, Vol. 218, Issue 10 https://doi.org/10.1243/0954406042369062	journal	October 2004
ASTM F2004-16: Standard Test Method for Transformation Temperature of Nickel-Titanium Alloys by Thermal Analysis No authors listed ASTM International https://doi.org/10.1520/F2004-16	standard	October 2017
Laser additive manufacturing of bulk and porous shape-memory NiTi alloys: From processes to potential biomedical applications Dadbakhsh, Sasan; Speirs, Mathew; Van Humbeeck, Jan MRS Bulletin, Vol. 41, Issue 10 https://doi.org/10.1557/mrs.2016.209	journal	October 2016
Sputter-Deposited Shape-Memory Alloy Thin Films: Properties and Applications Ishida, Akira; Martynov, Valery MRS Bulletin, Vol. 27, Issue 2 https://doi.org/10.1557/mrs2002.46	journal	February 2002

Cited By (7)

A Short Review on the Microstructure, Transformation Behavior and Functional Properties of NiTi Shape Memory Alloys Fabricated by Selective Laser Melting Wang, Xiebin; Kustov, Sergey; Van Humbeeck, Jan Materials, Vol. 11, Issue 9 https://doi.org/10.3390/ma11091683	journal	September 2018
The influence of texture on the reversible elastocaloric effect of a polycrystalline Ni ₅₀ Mn ₃₂ In ₁₆ Cr ₂ alloy Hernández-Navarro, Fernando; Camarillo-Garcia, Juan-Pablo; Aguilar-Ortiz, Christian-Omar Applied Physics Letters, Vol. 112, Issue 16 https://doi.org/10.1063/1.5018732	journal	April 2018
Characterization and modeling of elastocaloric effects of shape memory poly(cyclooctene) Hong, Seok Bin; An, Yongsan; Yu, Woong-Ryeol Applied Physics Letters, Vol. 114, Issue 1 https://doi.org/10.1063/1.5082357	journal	January 2019
Solid-state thermal energy storage using reversible martensitic transformations Sharar, Darin J.; Donovan, Brian F.; Warzoha, Ronald J. Applied Physics Letters, Vol. 114, Issue 14 https://doi.org/10.1063/1.5087135	journal	April 2019
Ultra-high fatigue life of NiTi cylinders for compression-based elastocaloric cooling Chen, Junyu; Zhang, Kuo; Kan, Qianhua Applied Physics Letters, Vol. 115, Issue 9 https://doi.org/10.1063/1.5115793	journal	August 2019
Accurate prediction of work and coefficient of performance of elastocaloric materials with phase transformation kinetics Qian, Suxin; Yuan, Lifen; Hou, Huilong Science and Technology for the Built Environment, Vol. 24, Issue 6 https://doi.org/10.1080/23744731.2018.1457411	journal	February 2018
Solid-State Thermal Energy Storage Using Reversible Martensitic Transformations Sharar, Darin J.; Donovan, Brian F.; Warzoha, Ronald J. arXiv https://doi.org/10.48550/arxiv.1901.06990	text	January 2019

Similar Records

Tuning the temperature range of superelastic Ni-Ti alloys for elastocaloric cooling via thermal processing

Journal Article · Thu Apr 27 20:00:00 EDT 2023 · JPhys Energy · OSTI ID:1971947

Large room-temperature elastocaloric effect in a bulk polycrystalline Ni-Ti-Cu-Co alloy with low isothermal stress hysteresis

Journal Article · Mon Nov 30 19:00:00 EST 2020 · Applied Materials Today · OSTI ID:1797912

Related Subjects

36 MATERIALS SCIENCE
additive manufacturing
elastocaloric cooling
latent heat
linear superelasticity
shape memory alloys
three-dimensional (3D) printing

Elastocaloric cooling of additive manufactured shape memory alloys with large latent heat

Citation Formats

References (62)

Cited By (7)

Similar Records

Related Subjects