Elastocaloric cooling of additive manufactured shape memory alloys with large latent heat

Hou, Huilong; Simsek, Emrah; Stasak, Drew; Hasan, Naila Al; Qian, Suxin; Ott, Ryan; Cui, Jun; Takeuchi, Ichiro

doi:10.1088/1361-6463/aa85bf

Title: Elastocaloric cooling of additive manufactured shape memory alloys with large latent heat

Journal Article · Fri Aug 11 00:00:00 EDT 2017 · Journal of Physics. D, Applied Physics

DOI:https://doi.org/10.1088/1361-6463/aa85bf· OSTI ID:1407483

^[1]; Simsek, Emrah ^[2];

^[1]; Hasan, Naila Al ^[1]; Qian, Suxin ^[3]; Ott, Ryan ^[2]; Cui, Jun ^[4]; Takeuchi, Ichiro ^[1]

Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering
Ames Lab., Ames, IA (United States)
Xi'an Jiaotong Univ., Xi'an (China). Dept. of Refrigeration and Cryogenic Engineering
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States). Dept. of Materials Science and Engineering

The stress-induced martensitic phase transformation of shape memory alloys (SMAs) is the basis for elastocaloric cooling. In this paper, we employ additive manufacturing to fabricate TiNi SMAs, and demonstrate compressive elastocaloric cooling in the TiNi rods with transformation latent heat as large as 20 J g^-1. Adiabatic compression on as-fabricated TiNi displays cooling ΔT as high as -7.5 °C with recoverable superelastic strain up to 5%. Unlike conventional SMAs, additive manufactured TiNi SMAs exhibit linear superelasticity with narrow hysteresis in stress–strain curves under both adiabatic and isothermal conditions. Microstructurally, we find that there are Ti₂Ni precipitates typically one micron in size with a large aspect ratio enclosing the TiNi matrix. Finally, a stress transfer mechanism between reversible phase transformation in the TiNi matrix and mechanical deformation in Ti₂Ni precipitates is believed to be the origin of the unique superelasticity behavior.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States); Univ. of Maryland, College Park, MD (United States); Xi'an Jiaotong Univ., Xi'an (China)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office; USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Advanced Research Projects Agency - Energy (ARPA-E); National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: AC02-07CH11358; AR0000131; 51606140

OSTI ID:: 1407483

Report Number(s):: IS-J-9455; TRN: US1703151

Journal Information:: Journal of Physics. D, Applied Physics, Vol. 50, Issue 40; ISSN 0022-3727

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 64 works

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36 MATERIALS SCIENCE
additive manufacturing
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Title: Elastocaloric cooling of additive manufactured shape memory alloys with large latent heat

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