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Title: Size dependent behavior of Fe3O4 crystals during electrochemical (de)lithiation: an in situ X-ray diffraction, ex situ X-ray absorption spectroscopy, transmission electron microscopy and theoretical investigation

Journal Article · · Physical Chemistry Chemical Physics. PCCP
DOI:https://doi.org/10.1039/c7cp03312e· OSTI ID:1402423
 [1];  [1];  [1];  [2];  [3];  [3];  [1];  [4];  [2]; ORCiD logo [5];  [2]; ORCiD logo [2]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States)
  2. Stony Brook Univ., Stony Brook, NY (United States)
  3. Columbia Univ., New York, NY (United States)
  4. American Physical Society, Ridge, NY (United States)
  5. Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States)
+ Show Author Affiliations

Crystal and atomic structural changes of Fe3O4upon electrochemical (de)lithiation were determined.

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
Grant/Contract Number:
SC0012704
OSTI ID:
1402423
Alternate ID(s):
OSTI ID: 1425178
Report Number(s):
BNL-114433-2017-JA; BNL-114491-2017-JAAM; PPCPFQ; TRN: US1703237
Journal Information:
Physical Chemistry Chemical Physics. PCCP, Vol. 19, Issue 31; ISSN 1463-9076
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 39 works
Citation information provided by
Web of Science

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Cited By (7)

The Systematic Refinement for the Phase Change and Conversion Reactions Arising from the Lithiation of Magnetite Nanocrystals journal November 2019
Scalable Synthesis of an Artificial Polydopamine Solid‐Electrolyte‐Interface‐Assisted 3D rGO/Fe 3 O 4 @PDA Hydrogel for a Highly Stable Anode with Enhanced Lithium‐Ion‐Storage Properties journal January 2019
In Situ Probing Multiple-Scale Structures of Energy Materials for Li-Ion Batteries journal May 2019
Synthesis and structural characterization of iron-cementite nanoparticles encapsulated in carbon matrix journal January 2020
Multi-electron transfer enabled by topotactic reaction in magnetite journal April 2019
Probing enhanced lithium-ion transport kinetics in 2D holey nanoarchitectured electrodes journal August 2018
Application of Operando X-ray Diffractometry in Various Aspects of the Investigations of Lithium/Sodium-Ion Batteries journal November 2018

Figures / Tables (30)

Figure 1(p. 6)figure Figure 1
Figure 2(p. 6)figure Figure 2
Figure 3(p. 6)figure Figure 3
Figure 4(p. 7)figure Figure 4
Figure 5(p. 8)figure Figure 5
Figure 6(p. 8)figure Figure 6
Figure 7(p. 9)figure Figure 7
Figure 8(p. 9)figure Figure 8
Figure 9(p. 10)figure Figure 9
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Figure 11(p. 12)figure Figure 11
Table 1(p. 12)table Table 1
Table 2(p. 12)table Table 2
Figure 12(p. 13)figure Figure 12
Figure 13(p. 13)figure Figure 13
Figure S1(p. 18)figure Figure S1
Figure S2(p. 19)figure Figure S2
Figure S3(p. 20)figure Figure S3
Figure S4(p. 21)figure Figure S4
Figure S5(p. 22)figure Figure S5
Figure S6(p. 22)figure Figure S6
Table S7(p. 23)table Table S7
Table S8(p. 24)table Table S8
Table S9(p. 25)table Table S9
Table S10(p. 26)table Table S10
Table S11(p. 26)table Table S11
Table S12(p. 27)table Table S12
Figure S13(p. 28)figure Figure S13
Figure S14(p. 28)figure Figure S14
Figure S15(p. 29)figure Figure S15

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