Calcium intercalation into layered fluorinated sodium iron phosphate

Lipson, Albert L.; Kim, Soojeong; Pan, Baofei; Liao, Chen; Fister, Timothy T.; Ingram, Brian J.

doi:10.1016/j.jpowsour.2017.09.081

Calcium intercalation into layered fluorinated sodium iron phosphate

Journal Article · Mon Oct 09 00:00:00 EDT 2017 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2017.09.081· OSTI ID:1401979

Lipson, Albert L. ^[1]; Kim, Soojeong ^[1]; Pan, Baofei ^[2]; ^[1]; Fister, Timothy T. ^[1]; ^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); Nanotek Instruments, Dayton, OH (United States)

Here, the energy density and cost of battery systems could be improved by moving to alternative battery chemistries such as Ca-ion. However, in order to switch chemistries many problems need to be solved including the identification of cathode materials with high energy density, and electrolytes that can plate and strip calcium metal. Herein, the feasibility and cycling performance of Ca²⁺ intercalation into a desodiated layered Na₂FePO₄F host is described. This is the first demonstration of Ca²⁺ intercalation into a polyanionic framework, which implies that other polyanionic framework materials may be active for Ca²⁺ intercalation. Although substantial effort is still needed to identify a high energy density cathode material, this study and others demonstrate the feasibility of Ca²⁺ intercalation into multiple materials making it more probable that such a cathode material can be found.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Joint Center for Energy Storage Research (JCESR)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1401979

Alternate ID(s):: OSTI ID: 1549369

Journal Information:: Journal of Power Sources, Journal Name: Journal of Power Sources Journal Issue: C Vol. 369; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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The critical role of configurational flexibility in facilitating reversible reactive metal deposition from borohydride solutions Hahn, Nathan T.; Self, Julian; Seguin, Trevor J. Journal of Materials Chemistry A, Vol. 8, Issue 15 https://doi.org/10.1039/d0ta02502j	journal	January 2020
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Calcium intercalation into layered fluorinated sodium iron phosphate

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