High-Voltage Phosphate Cathodes for Rechargeable Ca-Ion Batteries

Kim, Sanghyeon; Yin, Liang; Lee, Myeong Hwan; Parajuli, Prakash; Blanc, Lauren; Fister, Timothy T.; Park, Haesun; Kwon, Bob Jin; Ingram, Brian J.; Zapol, Peter; Klie, Robert F.; Kang, Kisuk; Nazar, Linda F.; Lapidus, Saul H.; Vaughey, John T.

doi:10.1021/acsenergylett.0c01663

High-Voltage Phosphate Cathodes for Rechargeable Ca-Ion Batteries

Journal Article · Mon Sep 14 00:00:00 EDT 2020 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.0c01663· OSTI ID:1774597

^[1]; ^[1]; Lee, Myeong Hwan ^[2]; Parajuli, Prakash ^[3]; Blanc, Lauren ^[4]; ^[1]; ^[1]; ^[1]; Ingram, Brian J. ^[1]; ^[1]; ^[3]; ^[2]; ^[4]; ^[1]; ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)
Seoul National Univ. (Korea, Republic of)
Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Illinois, Chicago, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Waterloo, ON (Canada)

Calcium-ion batteries (CIBs) are under investigation as next-generation energy storage devices due to their theoretically high operating potentials and lower costs tied to the high natural abundance of calcium. However, the development of CIBs has been limited by the lack of available positive electrode materials. In this study, for the first time, we report two functional polyanionic phosphate materials as high-voltage cathodes for CIBs at room temperature. NaV₂(PO₄)₃ electrodes were found to reversibly intercalate 0.6 mol of Ca²⁺ (81 mA h g^–1) near 3.2 V (vs Ca²⁺/Ca) with stable cycling performance at a current density of 3.5 mA g^–1. The olivine framework material FePO₄ reversibly intercalates 0.2 mol of Ca²⁺ (72 mA h g^–1) near 2.9 V (vs Ca²⁺/Ca) at a current density of 7.5 mA g^–1 in the first cycle. Structural, electronic, and compositional changes are consistent with reversible Ca²⁺ intercalation into these two materials.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1774597

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 10 Vol. 5; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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calcium
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intercalation
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High-Voltage Phosphate Cathodes for Rechargeable Ca-Ion Batteries

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