Pillared Sn‐MWW Prepared by a Solid‐State‐Exchange Method and its Use as a Lewis Acid Catalyst

Ren, Limin; Guo, Qiang; Orazov, Marat; Xu, Dandan; Politi, Dorothea; Kumar, Prashant; Alhassan, Saeed M.; Mkhoyan, K. Andre; Sidiras, Dimitrios; Davis, Mark E.; Tsapatsis, Michael

doi:10.1002/cctc.201600120

Title: Pillared Sn‐MWW Prepared by a Solid‐State‐Exchange Method and its Use as a Lewis Acid Catalyst

Journal Article · Wed Mar 23 00:00:00 EDT 2016 · ChemCatChem

DOI:https://doi.org/10.1002/cctc.201600120· OSTI ID:1401657

Ren, Limin ^[1]; Guo, Qiang ^[1]; Orazov, Marat ^[2]; Xu, Dandan ^[1]; Politi, Dorothea ^[3]; Kumar, Prashant ^[1]; Alhassan, Saeed M. ^[4]; Mkhoyan, K. Andre ^[1]; Sidiras, Dimitrios ^[3]; Davis, Mark E. ^[2];

^[1]

Department of Chemical Engineering and Materials Science University of Minnesota 421 Washington Avenue SE Minneapolis MN 55455 USA
Chemical Engineering California Institute of Technology Pasadena CA 91125 USA
Laboratory of Simulation of Industrial Processes Department of Industrial Management and Technology University of Piraeus 80 Karaoli &, Dimitriou GR-18534 Piraeus Greece
Department of Chemical Engineering The Petroleum Institute Abu Dhabi UAE

Abstract Pillared Sn‐MWW (Sn‐MWW(SP)‐SSE) was prepared through a solid‐state‐exchange (SSE) route. The pillared structure was inherited from pillared B‐MWW, and Sn was inserted in the framework by boron leaching and solid‐state‐exchange with tin tetrachloride pentahydrate. The Sn‐MWW(SP)‐SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer–Villiger oxidation, and mono‐ and disaccharide isomerizations.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0001004

OSTI ID:: 1401657

Journal Information:: ChemCatChem, Journal Name: ChemCatChem Vol. 8 Journal Issue: 7; ISSN 1867-3880

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 32 works

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