CO 2 Hydrogenation over Oxide‐Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity

Kattel, Shyam; Yu, Weiting; Yang, Xiaofang; Yan, Binhang; Huang, Yanqiang; Wan, Weiming; Liu, Ping; Chen, Jingguang G.

doi:10.1002/ange.201601661

CO ₂ Hydrogenation over Oxide‐Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity

Journal Article · Mon May 09 00:00:00 EDT 2016 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201601661· OSTI ID:1400968

Kattel, Shyam ^[1]; Yu, Weiting ^[2]; Yang, Xiaofang ^[1]; Yan, Binhang ^[1]; Huang, Yanqiang ^[3]; Wan, Weiming ^[2]; Liu, Ping ^[1]; Chen, Jingguang G. ^[4]

Chemistry Department Brookhaven National Laboratory 2 Center St. Upton NY 11973 USA
Department of Chemical Engineering Columbia University 1500 W. 120th St. New York NY 10027 USA
Dalian Institute of Chemical Physics Chinese Academy of Science Dalian 116023 China
Chemistry Department Brookhaven National Laboratory 2 Center St. Upton NY 11973 USA, Department of Chemical Engineering Columbia University 1500 W. 120th St. New York NY 10027 USA

Abstract

By simply changing the oxide support, the selectivity of a metal–oxide catalysts can be tuned. For the CO ₂ hydrogenation over PtCo bimetallic catalysts supported on different reducible oxides (CeO ₂ , ZrO ₂ , and TiO ₂ ), replacing a TiO ₂ support by CeO ₂ or ZrO ₂ selectively strengthens the binding of C,O‐bound and O‐bound species at the PtCo–oxide interface, leading to a different product selectivity. These results reveal mechanistic insights into how the catalytic performance of metal–oxide catalysts can be fine‐tuned.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1400968

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 28 Vol. 128; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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CO₂ hydrogenation over oxide-supported PtCo catalysts: The role of the oxide support in determining the product selectivity

Journal Article · Mon May 09 00:00:00 EDT 2016 · Angewandte Chemie (International Edition) · OSTI ID:1333197

CO 2 Hydrogenation over Oxide‐Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity

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CO ₂ Hydrogenation over Oxide‐Supported PtCo Catalysts: The Role of the Oxide Support in Determining the Product Selectivity