CO2 hydrogenation over oxide-supported PtCo catalysts: The role of the oxide support in determining the product selectivity

Kattel, Shyam; Yu, Weiting; Yang, Xiaofang; Yan, Binhang; Huang, Yanqiang; Wan, Weiming; Liu, Ping; Chen, Jingguang G.

doi:10.1002/anie.201601661

CO₂ hydrogenation over oxide-supported PtCo catalysts: The role of the oxide support in determining the product selectivity

Journal Article · Mon May 09 00:00:00 EDT 2016 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201601661· OSTI ID:1333197

Kattel, Shyam ^[1]; Yu, Weiting ^[2]; Yang, Xiaofang ^[1]; Yan, Binhang ^[1]; Huang, Yanqiang ^[3]; Wan, Weiming ^[2]; Liu, Ping ^[1]; Chen, Jingguang G. ^[4]

Brookhaven National Lab. (BNL), Upton, NY (United States)
Columbia Univ., New York, NY (United States)
Chinese Academy of Science, Dalian (China)
Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)

By simply changing the oxide support, the selectivity of a metal–oxide catalysts can be tuned. For the CO₂ hydrogenation over PtCo bimetallic catalysts supported on different reducible oxides (CeO₂, ZrO₂, and TiO₂), replacing a TiO₂ support by CeO₂ or ZrO₂ selectively strengthens the binding of C,O-bound and O-bound species at the PtCo–oxide interface, leading to a different product selectivity. Lastly, these results reveal mechanistic insights into how the catalytic performance of metal–oxide catalysts can be fine-tuned.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI ID:: 1333197

Alternate ID(s):: OSTI ID: 1401667

Report Number(s):: BNL--113193-2016-JA; KC0302010

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 28 Vol. 55; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (43)

Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia Angewandte Chemie, Vol. 125, Issue 19 https://doi.org/10.1002/ange.201210077	journal	April 2013
Metall-Substrat-Wechselwirkung: Kombination von hochauflösender Mikroskopie und Modellsystemen, um die atomare Struktur von Grenzflächen aufzuklären Willinger, Marc G.; Zhang, Wei; Bondarchuk, Oleksandr Angewandte Chemie, Vol. 126, Issue 23 https://doi.org/10.1002/ange.201400290	journal	May 2014
Molybdenum Carbide as Alternative Catalysts to Precious Metals for Highly Selective Reduction of CO ₂ to CO Porosoff, Marc D.; Yang, Xiaofang; Boscoboinik, J. Anibal Angewandte Chemie, Vol. 126, Issue 26 https://doi.org/10.1002/ange.201404109	journal	May 2014
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al ₂ O ₃ Catalysts Induced by Strong Metal-Support Interactions Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte Angewandte Chemie, Vol. 127, Issue 15 https://doi.org/10.1002/ange.201411581	journal	February 2015
Aktivierung und Elektronentransfer-induzierte Reaktion von Kohlendioxid an einer Oxid-Metall-Grenzfläche Calaza, Florencia; Stiehler, Christian; Fujimori, Yuichi Angewandte Chemie, Vol. 127, Issue 42 https://doi.org/10.1002/ange.201501420	journal	May 2015
Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy Mudiyanselage, Kumudu; Senanayake, Sanjaya D.; Feria, Leticia Angewandte Chemie International Edition, Vol. 52, Issue 19 https://doi.org/10.1002/anie.201210077	journal	April 2013
A Case of Strong Metal-Support Interactions: Combining Advanced Microscopy and Model Systems to Elucidate the Atomic Structure of Interfaces Willinger, Marc G.; Zhang, Wei; Bondarchuk, Oleksandr Angewandte Chemie International Edition, Vol. 53, Issue 23 https://doi.org/10.1002/anie.201400290	journal	May 2014
Molybdenum Carbide as Alternative Catalysts to Precious Metals for Highly Selective Reduction of CO ₂ to CO Porosoff, Marc D.; Yang, Xiaofang; Boscoboinik, J. Anibal Angewandte Chemie International Edition, Vol. 53, Issue 26 https://doi.org/10.1002/anie.201404109	journal	May 2014
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al ₂ O ₃ Catalysts Induced by Strong Metal-Support Interactions Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte Angewandte Chemie International Edition, Vol. 54, Issue 15 https://doi.org/10.1002/anie.201411581	journal	February 2015
Carbon Dioxide Activation and Reaction Induced by Electron Transfer at an Oxide-Metal Interface Calaza, Florencia; Stiehler, Christian; Fujimori, Yuichi Angewandte Chemie International Edition, Vol. 54, Issue 42 https://doi.org/10.1002/anie.201501420	journal	May 2015
Role of the Metal-Oxide Support in the Catalytic Activity of Pd Nanoparticles for Ethanol Electrooxidation in Alkaline Media Monyoncho, Evans Angwenyi; Ntais, Spyridon; Brazeau, Nicolas ChemElectroChem, Vol. 3, Issue 2 https://doi.org/10.1002/celc.201500432	journal	December 2015
CO ₂ Hydrogenation to Methanol on Supported Au Catalysts under Moderate Reaction Conditions: Support and Particle Size Effects Hartadi, Yeusy; Widmann, Daniel; Behm, R. Jürgen ChemSusChem, Vol. 8, Issue 3 https://doi.org/10.1002/cssc.201402645	journal	October 2014
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Trends in the catalytic reduction of CO2 by hydrogen over supported monometallic and bimetallic catalysts Porosoff, Marc D.; Chen, Jingguang G. Journal of Catalysis, Vol. 301 https://doi.org/10.1016/j.jcat.2013.01.022	journal	May 2013
Regenerating Pt–3d–Pt model electrocatalysts through oxidation–reduction cycles monitored at atmospheric pressure Menning, Carl A.; Chen, Jingguang G. Journal of Power Sources, Vol. 195, Issue 10 https://doi.org/10.1016/j.jpowsour.2009.11.109	journal	May 2010
Theoretical perspective of alcohol decomposition and synthesis from CO2 hydrogenation Liu, Ping; Yang, Yixiong; White, Michael G. Surface Science Reports, Vol. 68, Issue 2 https://doi.org/10.1016/j.surfrep.2013.01.001	journal	June 2013
CO Oxidation on Gold-Supported Iron Oxides: New Insights into Strong Oxide–Metal Interactions Yu, Liang; Liu, Yun; Yang, Fan The Journal of Physical Chemistry C, Vol. 119, Issue 29 https://doi.org/10.1021/acs.jpcc.5b03315	journal	July 2015
Active Sites of Au and Ag Nanoparticle Catalysts for CO ₂ Electroreduction to CO Back, Seoin; Yeom, Min Sun; Jung, Yousung ACS Catalysis, Vol. 5, Issue 9 https://doi.org/10.1021/acscatal.5b00462	journal	August 2015
Fundamental Studies of Well-Defined Surfaces of Mixed-Metal Oxides: Special Properties of MO _x /TiO ₂ (110) {M = V, Ru, Ce, or W} Stacchiola, Darío J.; Senanayake, Sanjaya D.; Liu, Ping Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr300316v	journal	December 2012
Role of Hot Electrons and Metal–Oxide Interfaces in Surface Chemistry and Catalytic Reactions Park, Jeong Young; Baker, L. Robert; Somorjai, Gabor A. Chemical Reviews, Vol. 115, Issue 8 https://doi.org/10.1021/cr400311p	journal	March 2015
Mechanism of Methanol Synthesis on Cu through CO ₂ and CO Hydrogenation Grabow, L. C.; Mavrikakis, M. ACS Catalysis, Vol. 1, Issue 4 https://doi.org/10.1021/cs200055d	journal	February 2011
Unraveling the Role of Metal–Support Interactions in Heterogeneous Catalysis: Oxygenate Selectivity in Fischer–Tropsch Synthesis Jenness, Glen R.; Schmidt, J. R. ACS Catalysis, Vol. 3, Issue 12 https://doi.org/10.1021/cs4006277	journal	November 2013
A New Type of Strong Metal–Support Interaction and the Production of H ₂ through the Transformation of Water on Pt/CeO ₂ (111) and Pt/CeO _x /TiO ₂ (110) Catalysts Bruix, Albert; Rodriguez, José A.; Ramírez, Pedro J. Journal of the American Chemical Society, Vol. 134, Issue 21 https://doi.org/10.1021/ja302070k	journal	May 2012
Evidence of Highly Active Cobalt Oxide Catalyst for the Fischer–Tropsch Synthesis and CO ₂ Hydrogenation Melaet, Gérôme; Ralston, Walter T.; Li, Cheng-Shiuan Journal of the American Chemical Society, Vol. 136, Issue 6 https://doi.org/10.1021/ja412447q	journal	January 2014
Embedding Covalency into Metal Catalysts for Efficient Electrochemical Conversion of CO ₂ Lim, Hyung-Kyu; Shin, Hyeyoung; Goddard, William A. Journal of the American Chemical Society, Vol. 136, Issue 32 https://doi.org/10.1021/ja503782w	journal	August 2014
Active and Selective Conversion of CO ₂ to CO on Ultrathin Au Nanowires Zhu, Wenlei; Zhang, Yin-Jia; Zhang, Hongyi Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja5095099	journal	November 2014
Isolated Metal Active Site Concentration and Stability Control Catalytic CO ₂ Reduction Selectivity Matsubu, John C.; Yang, Vanessa N.; Christopher, Phillip Journal of the American Chemical Society, Vol. 137, Issue 8 https://doi.org/10.1021/ja5128133	journal	February 2015
Carbon Dioxide Conversion to Methanol over Size-Selected Cu ₄ Clusters at Low Pressures Liu, Cong; Yang, Bing; Tyo, Eric Journal of the American Chemical Society, Vol. 137, Issue 27 https://doi.org/10.1021/jacs.5b03668	journal	July 2015
Low Pressure CO ₂ Hydrogenation to Methanol over Gold Nanoparticles Activated on a CeO _x /TiO ₂ Interface Yang, Xiaofang; Kattel, Shyam; Senanayake, Sanjaya D. Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b06150	journal	August 2015
Experimental and Theoretical Investigation of the Stability of Pt−3d−Pt(111) Bimetallic Surfaces under Oxygen Environment Menning, Carl A.; Hwu, Henry H.; Chen, Jingguang G. The Journal of Physical Chemistry B, Vol. 110, Issue 31 https://doi.org/10.1021/jp061697z	journal	August 2006
Comparison of O−H, C−H, and C−O Bond Scission Sequence of Methanol on Tungsten Carbide Surfaces Modified by Ni, Rh, and Au Kelly, Thomas G.; Stottlemyer, Alan L.; Ren, Hui The Journal of Physical Chemistry C, Vol. 115, Issue 14 https://doi.org/10.1021/jp112006v	journal	March 2011
Surface Chemistry of Cu in the Presence of CO ₂ and H ₂ O Deng, Xingyi; Verdaguer, Albert; Herranz, Tirma Langmuir, Vol. 24, Issue 17 https://doi.org/10.1021/la8011052	journal	September 2008
Towards the computational design of solid catalysts Nørskov, J.; Bligaard, T.; Rossmeisl, J. Nature Chemistry, Vol. 1, Issue 1, p. 37-46 https://doi.org/10.1038/nchem.121	journal	April 2009
A selective and efficient electrocatalyst for carbon dioxide reduction Lu, Qi; Rosen, Jonathan; Zhou, Yang Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4242	journal	January 2014
High-resolution X-ray luminescence extension imaging Ou, Xiangyu; Qin, Xian; Huang, Bolong Nature, Vol. 590, Issue 7846 https://doi.org/10.1038/s41586-021-03251-6	journal	February 2021
CO ₂ methanation over heterogeneous catalysts: recent progress and future prospects Aziz, M. A. A.; Jalil, A. A.; Triwahyono, S. Green Chemistry, Vol. 17, Issue 5 https://doi.org/10.1039/C5GC00119F	journal	January 2015
Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001̄) Yang, Yixiong; Evans, Jaime; Rodriguez, Jose A. Physical Chemistry Chemical Physics, Vol. 12, Issue 33 https://doi.org/10.1039/c001484b	journal	January 2010
Rationalization of the Hubbard U parameter in CeO _x from first principles: Unveiling the role of local structure in screening Lu, Deyu; Liu, Ping The Journal of Chemical Physics, Vol. 140, Issue 8 https://doi.org/10.1063/1.4865831	journal	February 2014
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2 Graciani, J.; Mudiyanselage, K.; Xu, F. Science, Vol. 345, Issue 6196 https://doi.org/10.1126/science.1253057	journal	July 2014
The critical role of water at the gold-titania interface in catalytic CO oxidation Saavedra, J.; Doan, H. A.; Pursell, C. J. Science, Vol. 345, Issue 6204 https://doi.org/10.1126/science.1256018	journal	September 2014
Finding optimal surface sites on heterogeneous catalysts by counting nearest neighbors Calle-Vallejo, F.; Tymoczko, J.; Colic, V. Science, Vol. 350, Issue 6257 https://doi.org/10.1126/science.aab3501	journal	October 2015

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