Synthesis of NaTi 2 ( PO 4 ) 3 by the Inorganic–Organic Steric Entrapment Method and Its Thermal Expansion Behavior

Ribero, Daniel; Seymour, Kevin C.; Kriven, Waltraud M.; White, ed., M. A.

doi:10.1111/jace.14420

Title: Synthesis of NaTi ₂ ( PO ₄ ) ₃ by the Inorganic–Organic Steric Entrapment Method and Its Thermal Expansion Behavior

Journal Article · Tue Aug 02 00:00:00 EDT 2016 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.14420· OSTI ID:1400576

Ribero, Daniel ^[1]; Seymour, Kevin C. ^[1]; Kriven, Waltraud M. ^[1]; White, ed., M. A.

Department of Materials Science and Engineering University of Illinois at Urbana‐Champaign 1304 W. Green St Urbana Illinois

Crystalline pure NaTi ₂ ( PO ₄ ) ₃ ( NTP ) powder was synthesized at 700°C using a simple and low energy, hybrid inorganic–organic, steric entrapment method. Sodium nitrite (Na NO ₂ ) and ammonium phosphate dibasic (( NH ₄ ) ₂ HPO ₄ ) dissolved in water, whereas titanium ( IV ) isopropoxide (Ti[ OCH ( CH ₃ ) ₂ ] ₄ ) hydrolyzed in water. Ethylene glycol ( HOCH ₂ CH ₂ OH ) was used as a polymeric entrapper and hydrolysis of the Ti source was hindered by its dissolution in isopropyl alcohol. The resulting NTP powder was characterized by thermogravimetric analysis/differential thermal analysis, X‐ray diffractometry, scanning electron microscopy, specific surface area by Brunauer–Emmett–Teller nitrogen absorption, and particle size analysis. Furthermore, C, H, N were measured by the classical Pregl‐Dumas method. The thermal expansion behavior in all { hkl } pole directions was also determined by in situ high‐temperature X‐ray diffraction using synchrotron radiation and was found to be in agreement with other published studies.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1400576

Journal Information:: Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Vol. 99 Journal Issue: 11; ISSN 0002-7820

Publisher:: Wiley-BlackwellCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 13 works

Citation information provided by
Web of Science

References (49)

Fast Na+-ion transport in skeleton structures Goodenough, J. B.; Hong, H. Y-P.; Kafalas, J. A. Materials Research Bulletin, Vol. 11, Issue 2 https://doi.org/10.1016/0025-5408(76)90077-5	journal	February 1976
Synthesis of a new NASICON-type blue luminescent material Masui, Toshiyuki; Koyabu, Kazuhiko; Tamura, Shinji Journal of Alloys and Compounds, Vol. 418, Issue 1-2 https://doi.org/10.1016/j.jallcom.2005.08.097	journal	July 2006
Negative thermal expansion: a review Miller, W.; Smith, C. W.; Mackenzie, D. S. Journal of Materials Science, Vol. 44, Issue 20 https://doi.org/10.1007/s10853-009-3692-4	journal	July 2009
Synthesis and Thermal Expansion of β-Eucryptite Powders Produced by the Inorganic-Organic Steric Entrapment Method Seymour, Kevin C.; Kriven, Waltraud M. Journal of the American Ceramic Society, Vol. 97, Issue 10 https://doi.org/10.1111/jace.13102	journal	July 2014
[CTP]: A new structural family of near-zero expansion ceramics Roy, Rustum; Agrawal, D. K.; Alamo, J. Materials Research Bulletin, Vol. 19, Issue 4 https://doi.org/10.1016/0025-5408(84)90108-9	journal	April 1984
Investigation of porous counter electrode for the CO2 sensing properties of NASICON based gas sensor Dang, Heng-Yao; Guo, Xing-Min Solid State Ionics, Vol. 201, Issue 1 https://doi.org/10.1016/j.ssi.2011.08.011	journal	October 2011
Synthesis and characterization of sodium-titanium phosphates, Na4(TiO)(PO4)2, Na(TiO)PO4, and NaTi2(PO4)3 Bamberger, Carlos E.; Begun, George M.; Cavin, O. B. Journal of Solid State Chemistry, Vol. 73, Issue 2 https://doi.org/10.1016/0022-4596(88)90115-6	journal	April 1988
Polymerized Organic-Inorganic Synthesis of Mixed Oxides Gülgün, Mehmet A.; Nguyen, My H.; Kriven, Waltraud M. Journal of the American Ceramic Society, Vol. 82, Issue 3 https://doi.org/10.1111/j.1151-2916.1999.tb01800.x	journal	March 1999
Thermal Expansion of HfO ₂ and ZrO ₂ : Thermal Expansion Haggerty, Ryan P.; Sarin, Pankaj; Apostolov, Zlatomir D. Journal of the American Ceramic Society, Vol. 97, Issue 7 https://doi.org/10.1111/jace.12975	journal	May 2014
A wide-ranging review on Nasicon type materials Anantharamulu, N.; Koteswara Rao, K.; Rambabu, G. Journal of Materials Science, Vol. 46, Issue 9 https://doi.org/10.1007/s10853-011-5302-5	journal	February 2011
Origin of the negative thermal expansion in and Pryde, Alexandra K. A.; Hammonds, Kenton D.; Dove, Martin T. Journal of Physics: Condensed Matter, Vol. 8, Issue 50 https://doi.org/10.1088/0953-8984/8/50/023	journal	December 1996
Comparison of the structural behaviour of the low thermal expansion NZP phases MTi2(PO4)3 (M = Li, Na, K) Woodcock, D. A.; Lightfoot, P. Journal of Materials Chemistry, Vol. 9, Issue 11 https://doi.org/10.1039/a904193a	journal	January 1999
The nasicon-type titanium phosphates Ati2(PO4)3 (A=Li, Na) as electrode materials Delmas, C.; Nadiri, A.; Soubeyroux, J. L. Solid State Ionics, Vol. 28-30 https://doi.org/10.1016/S0167-2738(88)80075-4	journal	September 1988
Characterization of active sites on AgHf2(PO4)3 in butan-2-ol conversion Brik, Youness; Kacimi, Mohamed; Bozon-Verduraz, François Microporous and Mesoporous Materials, Vol. 43, Issue 1 https://doi.org/10.1016/S1387-1811(00)00353-X	journal	March 2001
Ion-exchange properties of NASICON-type phosphates with the frameworks [Ti2(PO4)3] and [Ti1.7Al0.3(PO4)3] Hirose, Naohiro; Kuwano, Jun Journal of Materials Chemistry, Vol. 4, Issue 1 https://doi.org/10.1039/jm9940400009	journal	January 1994
Towards High Power High Energy Aqueous Sodium-Ion Batteries: The NaTi ₂ (PO ₄ ) ₃ /Na _0.44 MnO ₂ System Li, Zheng; Young, David; Xiang, Kai Advanced Energy Materials, Vol. 3, Issue 3 https://doi.org/10.1002/aenm.201200598	journal	October 2012
Chemistry and properties of solids with the [NZP] skeleton Alamo, J. Solid State Ionics, Vol. 63-65 https://doi.org/10.1016/0167-2738(93)90158-Y	journal	September 1993
Thermal Expansion of the Orthorhombic Phase in the Ln ₂ TiO ₅ System Seymour, Kevin C.; Hughes, Robert W.; Kriven, Waltraud M. Journal of the American Ceramic Society, Vol. 98, Issue 12 https://doi.org/10.1111/jace.13821	journal	August 2015
Very Low Thermal Expansion Coefficient Materials Roy, R.; Agrawal, D. K.; McKinstry, H. A. Annual Review of Materials Science, Vol. 19, Issue 1 https://doi.org/10.1146/annurev.ms.19.080189.000423	journal	August 1989
Negative Thermal Expansion in the Siliceous Zeolites Chabazite and ITQ-4: A Neutron Powder Diffraction Study Woodcock, David A.; Lightfoot, Philip; Villaescusa, Luis A. Chemistry of Materials, Vol. 11, Issue 9 https://doi.org/10.1021/cm991047q	journal	September 1999
Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW2O8 Mary, T. A.; Evans, J. S. O.; Vogt, T. Science, Vol. 272, Issue 5258 https://doi.org/10.1126/science.272.5258.90	journal	April 1996
Low thermal expansion materials: a comparison of the structural behaviour of La0.33Ti2(PO4)3, Sr0.5Ti2(PO4)3 and NaTi2(PO4)3 Lightfoot, Philip; Woodcock, David A.; Jorgensen, James D. International Journal of Inorganic Materials, Vol. 1, Issue 1 https://doi.org/10.1016/S1463-0176(99)00008-3	journal	April 1999
Thermal Expansion Behavior of NaZr2(PO4)3Type Compounds Oota, Toshitaka; Yamai, Iwao Journal of the American Ceramic Society, Vol. 69, Issue 1 https://doi.org/10.1111/j.1151-2916.1986.tb04682.x	journal	January 1986
Synthesis of sodium titanium phosphate at ultra-low temperature Sun, Fuhong; Wang, Rui; Jiang, Heng Research on Chemical Intermediates, Vol. 39, Issue 4 https://doi.org/10.1007/s11164-012-0720-9	journal	July 2012
Quadrupole lamp furnace for high temperature (up to 2050K) synchrotron powder x-ray diffraction studies in air in reflection geometry Sarin, P.; Yoon, W.; Jurkschat, K. Review of Scientific Instruments, Vol. 77, Issue 9 https://doi.org/10.1063/1.2349600	journal	September 2006
Mechanism of low thermal expansion in the cation-ordered Nasicon structure Woodcock, David A.; Lightfoot, Philip; Woodcock, David A. Chemical Communications, Issue 1 https://doi.org/10.1039/a706928f	journal	January 1998
Thermal expansion behaviour of M′Ti2P3O12 (M′=Li, Na, K, Cs) and M″Ti4P6O24 (M″=Mg, Ca, Sr, Ba) compounds Huang, C. -Y.; Agrawal, D. K.; McKinstry, H. A. Journal of Materials Science, Vol. 30, Issue 13 https://doi.org/10.1007/BF00349902	journal	July 1995
Exceptional Negative Thermal Expansion in AlPO ₄ -17 Attfield, Martin P.; Sleight, Arthur W. Chemistry of Materials, Vol. 10, Issue 7 https://doi.org/10.1021/cm9801587	journal	July 1998
The Crystal Structure of NaM2IV(PO4)3; MeIV = Ge, Ti, Zr. Hagman, Lars-Ove; Kierkegaard, Peder; Karvonen, Pertti Acta Chemica Scandinavica, Vol. 22 https://doi.org/10.3891/acta.chem.scand.22-1822	journal	January 1968
Synthesis of LiFePO ₄ powder by the organic–inorganic steric entrapment method Ribero, Daniel; Kriven, Waltraud M. Journal of Materials Research, Vol. 30, Issue 14 https://doi.org/10.1557/jmr.2015.181	journal	July 2015
Effect of microstructure on the conductivity of a NASICON-type lithium ion conductor Johnson, Paul; Sammes, Nigel; Imanishi, Nobuyuki Solid State Ionics, Vol. 192, Issue 1 https://doi.org/10.1016/j.ssi.2010.01.005	journal	June 2011
Electrochemical Properties of NaTi2(PO4)3 Anode for Rechargeable Aqueous Sodium-Ion Batteries Park, Sun Il; Gocheva, Irina; Okada, Shigeto Journal of The Electrochemical Society, Vol. 158, Issue 10 https://doi.org/10.1149/1.3611434	journal	January 2011
Pulsed Laser Deposition of NASICON Thin Films for the Fabrication of Ion Selective Membranes Izquierdo, R. Journal of The Electrochemical Society, Vol. 144, Issue 12 https://doi.org/10.1149/1.1838147	journal	January 1997
A rapid synthesis of sodium titanium phosphate, NaTi2(PO4)3 by using microwave energy Güler, Halil; Kurtuluş, Figen Materials Chemistry and Physics, Vol. 99, Issue 2-3 https://doi.org/10.1016/j.matchemphys.2005.11.011	journal	October 2006
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
A study on lithium/air secondary batteries—Stability of the NASICON-type lithium ion conducting solid electrolyte in alkaline aqueous solutions Shimonishi, Yuta; Zhang, Tao; Imanishi, Nobuyuki Journal of Power Sources, Vol. 196, Issue 11 https://doi.org/10.1016/j.jpowsour.2011.02.023	journal	June 2011
Hydrothermal synthesis of MTi2(PO4)3 (M=Li,Na,K) Yue, Yong; Pang, Wenqin Materials Research Bulletin, Vol. 25, Issue 7 https://doi.org/10.1016/0025-5408(90)90060-F	journal	July 1990
NASICON-type Li1+2xZr2−xCax(PO4)3 with high ionic conductivity at room temperature Xie, Hui; Li, Yutao; Goodenough, John B. RSC Advances, Vol. 1, Issue 9 https://doi.org/10.1039/c1ra00383f	journal	January 2011
Sodium zirconium phosphate (NZP) as a host structure for nuclear waste immobilization: A review Scheetz, B. E.; Agrawal, D. K.; Breval, E. Waste Management, Vol. 14, Issue 6 https://doi.org/10.1016/0956-053X(94)90133-3	journal	January 1994
Low temperature preparation of NaTi<SUB align=right>2(PO<SUB align=right>4)<SUB align=right>3 by sol-gel method Velchuri, Radha; Kumar, B. Vijaya; Devi, V. Rama International Journal of Nanotechnology, Vol. 7, Issue 9/10/11/12 https://doi.org/10.1504/IJNT.2010.034712	journal	January 2010
Preparation and measurement of standard organic gases using a diffusion method and a NASICON-based CO2 sensor combined with a combustion catalyst Kida, Tetsuya; Seo, Min-Hyun; Kishi, Shotaro Analytical Methods, Vol. 3, Issue 8 https://doi.org/10.1039/c1ay05223c	journal	January 2011
Thermal expansion of NaTi2(PO4)3 studied by rietveld method from X-ray diffraction data Rodrigo, J. L.; Carrasco, P.; Alamo, J. Materials Research Bulletin, Vol. 24, Issue 5 https://doi.org/10.1016/0025-5408(89)90109-8	journal	May 1989
CTEAS : a graphical-user-interface-based program to determine thermal expansion from high-temperature X-ray diffraction Jones, Z. A.; Sarin, P.; Haggerty, R. P. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813002938	journal	March 2013
Strong negative thermal expansion in siliceous faujasite Attfield, Martin P. Chemical Communications, Issue 5 https://doi.org/10.1039/a707141h	journal	January 1998
Strong negative thermal expansion in the siliceous zeolites ITQ-1, ITQ-3 and SSZ-23 Woodcock, David A.; Lightfoot, Philip; Wright, Paul A. Journal of Materials Chemistry, Vol. 9, Issue 2 https://doi.org/10.1039/a808059c	journal	January 1999
A nasicon-type phase as intercalation electrode: NaTi2(PO4)3 Delmas, C.; Cherkaoui, F.; Nadiri, A. Materials Research Bulletin, Vol. 22, Issue 5 https://doi.org/10.1016/0025-5408(87)90112-7	journal	May 1987
NZP: A new family of low-thermal expansion materials Agrawal, D. K.; Huang, C. -Y.; McKinstry, H. A. International Journal of Thermophysics, Vol. 12, Issue 4 https://doi.org/10.1007/BF00534225	journal	July 1991
Microwave Synthesized NaTi ₂ (PO ₄ ) ₃ as an Aqueous Sodium-Ion Negative Electrode Wu, Wei; Mohamed, Alex; Whitacre, J. F. Journal of The Electrochemical Society, Vol. 160, Issue 3 https://doi.org/10.1149/2.054303jes	journal	January 2013
Negative Thermal Expansion and Phase Transitions in the ZrV2-xPxO7 Series Korthuis, V.; Khosrovani, N.; Sleight, A. W. Chemistry of Materials, Vol. 7, Issue 2 https://doi.org/10.1021/cm00050a028	journal	February 1995

Similar Records

Defect mechanisms in BaTiO ₃ ‐Bi M O ₃ ceramics

Journal Article · Mon Jan 08 00:00:00 EST 2018 · Journal of the American Ceramic Society · OSTI ID:1400576

Kumar, Nitish; Patterson, Eric A.; Frömling, Till; +8 more

Atmospheric CH ₄ oxidation by Arctic permafrost and mineral cryosols as a function of water saturation and temperature

Journal Article · Fri Jul 29 00:00:00 EDT 2016 · Geobiology · OSTI ID:1400576

Stackhouse, B.; Lau, M. C. Y.; Vishnivetskaya, T.; +5 more

Dense nanocrystalline UO _{2+
x} fuel pellets synthesized by high pressure spark plasma sintering

Journal Article · Wed Nov 01 00:00:00 EDT 2017 · Journal of the American Ceramic Society · OSTI ID:1400576

Yao, Tiankai; Scott, Spencer M.; Xin, Guoqing; +2 more

Title: Synthesis of NaTi 2 ( PO 4 ) 3 by the Inorganic–Organic Steric Entrapment Method and Its Thermal Expansion Behavior

Citation Formats

References (49)

Similar Records

Related Subjects

Title: Synthesis of NaTi ₂ ( PO ₄ ) ₃ by the Inorganic–Organic Steric Entrapment Method and Its Thermal Expansion Behavior