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Beyond native block copolymer morphologies

Journal Article · · Molecular Systems Design & Engineering
DOI:https://doi.org/10.1039/c7me00069c· OSTI ID:1399668

Block copolymers self-assemble into a range of canonical morphologies. Here, we review a broad range of techniques for inducing these materials to form structures beyond the ‘native’ morphologies seen in the bulk equilibrium phase diagram. Methods that exploit intrinsic encoding (molecular design) and external enforcement (directed assembly) are compared.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
SC0012704
OSTI ID:
1399668
Report Number(s):
BNL--114375-2017-JA; KC0403020
Journal Information:
Molecular Systems Design & Engineering, Journal Name: Molecular Systems Design & Engineering Journal Issue: 5 Vol. 2; ISSN 2058-9689; ISSN MSDEBG
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

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A Kriging-Based Approach to Autonomous Experimentation with Applications to X-Ray Scattering journal August 2019
Advances in Kriging-Based Autonomous X-Ray Scattering Experiments journal January 2020
Nanoscale Block Copolymer Self‐Assembly and Microscale Polymer Film Dewetting: Progress in Understanding the Role of Interfacial Energies in the Formation of Hierarchical Nanostructures journal December 2019
Photothermally Directed Assembly of Block Copolymers journal December 2019
Non‐Native Block Copolymer Thin Film Nanostructures Derived from Iterative Self‐Assembly Processes journal December 2019
Directing Block Copolymer Self-Assembly on Patterned Substrates journal October 2018
Sticky ends in a self-assembling ABA triblock copolymer: the role of ureas in stimuli-responsive hydrogels journal January 2019
Hybrid line–dot nanopatterns from directed self-assembly of diblock copolymers by trenches journal January 2019
The influence of confinement on the structure of colloidal systems with competing interactions journal January 2020
Origins of low-symmetry phases in asymmetric diblock copolymer melts journal January 2018
Mesoscopic theory for systems with competing interactions near a confining wall journal December 2019

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