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Non-native three-dimensional block copolymer morphologies

Journal Article · · Nature Communications
DOI:https://doi.org/10.1038/ncomms13988· OSTI ID:1347375

Self-assembly is a powerful paradigm, wherein molecules spontaneously form ordered phases exhibiting well-defined nanoscale periodicity and shapes. However, the inherent energy-minimization aspect of self-assembly yields a very limited set of morphologies, such as lamellae or hexagonally packed cylinders. Here, we show how soft self-assembling materials—block copolymer thin films—can be manipulated to form a diverse library of previously unreported morphologies. In this iterative assembly process, each polymer layer acts as both a structural component of the final morphology and a template for directing the order of subsequent layers. Specifically, block copolymer films are immobilized on surfaces, and template successive layers through subtle surface topography. As a result, this strategy generates an enormous variety of three-dimensional morphologies that are absent in the native block copolymer phase diagram.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI ID:
1347375
Alternate ID(s):
OSTI ID: 1786306
Report Number(s):
BNL--113659-2017-JA; KC0403020
Journal Information:
Nature Communications, Journal Name: Nature Communications Vol. 7; ISSN 2041-1723
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

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Cited By (14)

Thin Film Analysis by Nanomechanical Infrared Spectroscopy journal April 2019
Smart Nanostructured Materials based on Self‐Assembly of Block Copolymers journal June 2019
Understanding Film Thickness‐Dependent Block Copolymer Self‐Assembly by Controlled Polymer Dewetting on Prepatterned Surfaces journal November 2019
Non‐Native Block Copolymer Thin Film Nanostructures Derived from Iterative Self‐Assembly Processes journal December 2019
Directing Block Copolymer Self-Assembly on Patterned Substrates journal October 2018
Metal Oxide Heterostructure Array via Spatially Controlled–Growth within Block Copolymer Templates journal October 2019
Review of Recent Advances in Applications of Vapor-Phase Material Infiltration Based on Atomic Layer Deposition journal September 2018
Emergent symmetries in block copolymer epitaxy journal July 2019
Fit-for-purpose block polymer membranes molecularly engineered for water treatment journal April 2018
Three-dimensional electroactive ZnO nanomesh directly derived from hierarchically self-assembled block copolymer thin films journal January 2019
Fusion and clustering of spherical micelles by extruding through a cylindrical channel journal January 2019
Automated solvent vapor annealing with nanometer scale control of film swelling for block copolymer thin films journal January 2019
The chemical physics of sequential infiltration synthesis—A thermodynamic and kinetic perspective journal November 2019
Modification of block copolymer lithography masks by O 2 /Ar plasma treatment: insights from lift-off experiments, nanopore etching and free membranes journal March 2019

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