Pd-Metalated Conjugated Nanoporous Polycarbazoles for Additive-Free Cyanation of Aryl Halides: Boosting Catalytic Efficiency through Spatial Modulation

Ding, Shunmin; Tian, Chengcheng; Zhu, Xiang; Abney, Carter W.; Tian, Ziqi; Chen, Bo; Li, Meijun; Jiang, De-en; Zhang, Ning; Dai, Sheng

doi:10.1002/cssc.201700329

Title: Pd-Metalated Conjugated Nanoporous Polycarbazoles for Additive-Free Cyanation of Aryl Halides: Boosting Catalytic Efficiency through Spatial Modulation

Journal Article · Thu Mar 23 00:00:00 EDT 2017 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201700329· OSTI ID:1376431

Ding, Shunmin ^[1]; Tian, Chengcheng ^[2]; Zhu, Xiang ^[2];

^[3]; Tian, Ziqi ^[4]; Chen, Bo ^[5]; Li, Meijun ^[2]; Jiang, De-en ^[4]; Zhang, Ning ^[5];

^[6]

Nanchang Univ. (China). Inst. of Applied Chemistry. College of Chemistry; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Univ. of California, Riverside, CA (United States). Dept. of Chemistry
Nanchang Univ. (China). Inst. of Applied Chemistry. College of Chemistry
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States); Nanchang Univ. (China)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC); Natural Science Foundation of Jiangxi Province (China)

Contributing Organization:: Univ. of California, Riverside, CA (United States)

Grant/Contract Number:: AC05-00OR22725; 21062013; 2011ZBAB203013

OSTI ID:: 1376431

Alternate ID(s):: OSTI ID: 1399441

Journal Information:: ChemSusChem, Vol. 10, Issue 11; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 13 works

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References (26)

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Metalated Mesoporous Poly(triphenylphosphine) with Azo Functionality: Efficient Catalysts for CO ₂ Conversion Yang, Zhenzhen; Yu, Bo; Zhang, Hongye ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b02583	journal	January 2016
Use of steric encumbrance to develop conjugated nanoporous polymers for metal-free catalytic hydrogenation Tian, Chengcheng; Zhu, Xiang; Abney, Carter W. Chemical Communications, Vol. 52, Issue 80 https://doi.org/10.1039/C6CC06372A	journal	January 2016
Microporous Polycarbazole with High Specific Surface Area for Gas Storage and Separation Chen, Qi; Luo, Min; Hammershøj, Peter Journal of the American Chemical Society, Vol. 134, Issue 14 https://doi.org/10.1021/ja300438w	journal	March 2012
Pyrolysis of conjugated nanoporous polycarbazoles to mesoporous N-doped carbon nanotubes as efficient electrocatalysts for the oxygen reduction reaction Zhu, Xiang; Zhu, Yihua; Tian, Chengcheng Journal of Materials Chemistry A, Vol. 5, Issue 9 https://doi.org/10.1039/C6TA09604B	journal	January 2017
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Cited By (5)

A Porous Organic Poly(triphenylimidazole) Decorated with Palladium Nanoparticles for the Cyanation of Aryl Iodides Yu, Haiwen; Xu, Siqi; Liu, Yijiang Chemistry - An Asian Journal, Vol. 13, Issue 18 https://doi.org/10.1002/asia.201800681	journal	August 2018
Visible‐Light‐Enhanced Suzuki–Miyaura Reactions of Aryl Chlorides in Water with Pd NPs Supported on a Conjugated Nanoporous Polycarbazole Guo, Bin; Li, Hong‐Xi; Zha, Cheng‐Hao ChemSusChem, Vol. 12, Issue 7 https://doi.org/10.1002/cssc.201802918	journal	April 2019
Microporous Polycarbazole Materials: From Preparation and Properties to Applications Chen, Qi; Han, Bao-Hang Macromolecular Rapid Communications, Vol. 39, Issue 9 https://doi.org/10.1002/marc.201800040	journal	March 2018
Boronic acid-functionalized porous polycarbazoles: preparation, adsorption performance, and heterogeneous catalysts for selective oxidation Feng, Lijuan; Zhang, Shizhen; Sun, Xiaoyu Journal of Materials Science, Vol. 53, Issue 21 https://doi.org/10.1007/s10853-018-2682-9	journal	July 2018
Meso–macroporous organic polymer-supported homogeneously dispersed small Pd nanoparticles obtained by a simple ion-exchange approach for the Heck reaction Ding, Shunmin; Qu, Baihong; Li, Yuan New Journal of Chemistry, Vol. 43, Issue 37 https://doi.org/10.1039/c9nj03344k	journal	January 2019

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
cyanation
heterogeneous catalysis
palladium
polymers
porous materials

Title: Pd-Metalated Conjugated Nanoporous Polycarbazoles for Additive-Free Cyanation of Aryl Halides: Boosting Catalytic Efficiency through Spatial Modulation

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