Solid-State Synthesis of Conjugated Nanoporous Polycarbazoles

Xiang, Zhu; Chengcheng, Tian; Jin, Tian; Browning, Katie; Sacci, Robert; Veith, Gabriel; Dai, Sheng

doi:10.1021/acsmacrolett.7b00480

Solid-State Synthesis of Conjugated Nanoporous Polycarbazoles

Journal Article · Wed Sep 13 00:00:00 EDT 2017 · ACS Macro Letters

DOI:https://doi.org/10.1021/acsmacrolett.7b00480· OSTI ID:1823382

Xiang, Zhu ^[1]; Chengcheng, Tian ^[1]; Jin, Tian ^[1]; Browning, Katie ^[2]; ^[2]; ^[2]; ^[2]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

A novel solid-state synthetic approach has been developed for the generation of conjugated nanoporous polymer networks. Using mechanochemical-assisted oxidative coupling polymerization, we demonstrated a rapid and solvent-free synthesis of conjugated polycarbazoles with high porosities and promising CO₂ storage abilities. This innovative approach constitutes a new direction for the development of novel nanoporous polymer frameworks through sustainable solid-state assembly pathways, and may open up new possibilities for the rational design and synthesis of nanoporous materials for carbon capture.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1823382

Journal Information:: ACS Macro Letters, Journal Name: ACS Macro Letters Journal Issue: 10 Vol. 6; ISSN 2161-1653

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO ₂ Fixation Xu, Wei; Chen, Hao; Jie, Kecheng Angewandte Chemie, Vol. 131, Issue 15 https://doi.org/10.1002/ange.201900787	journal	March 2019
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Influence of Branching of Polythiophenes on the Microporosity Mulunda, Mikael Monga; Zhang, Zidan; Nies, Eric Macromolecular Chemistry and Physics, Vol. 219, Issue 12 https://doi.org/10.1002/macp.201800024	journal	May 2018
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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CO2 capture
adsorption
conjugated polycarbazoles
conjugated polymers
mechanochemisty
nanoporous materials
oxidative coupling polymerization
polymerization
porosity
solid-state

Solid-State Synthesis of Conjugated Nanoporous Polycarbazoles

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References (41)

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