Long cycle life microporous spherical carbon anodes for sodium-ion batteries derived from furfuryl alcohol

Zhou, Dehua; Peer, Maryam; Yang, Zhenzhen; Pol, Vilas G.; Key, Fulya Dogan; Jorne, Jacob; Foley, Henry C.; Johnson, Christopher S.

doi:10.1039/C6TA00242K

Long cycle life microporous spherical carbon anodes for sodium-ion batteries derived from furfuryl alcohol

Journal Article · Mon Apr 11 00:00:00 EDT 2016 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C6TA00242K· OSTI ID:1399267

Zhou, Dehua ^[1]; Peer, Maryam ^[2]; Yang, Zhenzhen ^[3]; Pol, Vilas G. ^[4]; Key, Fulya Dogan ^[3]; Jorne, Jacob ^[5]; Foley, Henry C. ^[2]; Johnson, Christopher S. ^[3]

Argonne National Lab. (ANL), Lemont, IL (United States); Univ. of Rochester, Rochester, NY (United States)
The Pennsylvania State Univ., University Park, PA (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Purdue Univ., West Lafayette, IN (United States)
Univ. of Rochester, Rochester, NY (United States)

Spherical micron-sized carbon powders were synthesized from feedstock furfuryl alcohol and tested as anodes in sodium ion batteries (SIBs). A long cycle life of 1000 cycles is achievable with this carbon at C rate (3–4 mg cm^–2 loading and i = 200 mA g^–1) yielding a steady capacity of ca. 115 mA h g^–1. Furthermore, the results from solid-state 23Na MAS NMR analyses of cycled electrodes indicate no correlation in voltage profiles with sodium site nature (graphene or nanopores), which is a new observation in SIB carbon anodes.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1399267

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 17 Vol. 4; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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SIB
battery
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sodium ion

Long cycle life microporous spherical carbon anodes for sodium-ion batteries derived from furfuryl alcohol

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