Efficient Functionalization of Polyethylene Fibers for the Uranium Extraction from Seawater through Atom Transfer Radical Polymerization

Neti, Venkata S.; Das, Sadananda; Brown, Suree; Janke, Christopher J.; Kuo, Li-Jung; Gill, Gary A.; Dai, Sheng; Mayes, Richard T.

doi:10.1021/acs.iecr.7b00482

Efficient Functionalization of Polyethylene Fibers for the Uranium Extraction from Seawater through Atom Transfer Radical Polymerization

Journal Article · Thu Sep 14 04:00:00 EDT 2017 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/acs.iecr.7b00482· OSTI ID:1398202

Neti, Venkata S. ^[1]; Das, Sadananda ^[1]; Brown, Suree ^[2]; Janke, Christopher J. ^[3]; ^[4]; Gill, Gary A. ^[4]; ^[5]; ^[1]

Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, United States
Department of Chemistry, University of Tennessee, Knoxville, Tennessee, United States
Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, United States
Marine Sciences Laboratory, Pacific Northwest National Laboratory, Sequim, Washington, United States
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, United States; Department of Chemistry, University of Tennessee, Knoxville, Tennessee, United States

Brush-on-brush structures are proposed as one method to overcome support effects in grafted polymers. Utilizing glycidyl methacrylate (GMA) grafted on polyethylene (PE) fibers using radiation-induced graft polymerization (RIGP) provides a hydrophilic surface on the hydrophobic PE. When integrated with atom transfer radical polymerization (ATRP), the grafting of acrylonitrile (AN) and hydroxyethyl acrylate (HEA) can be controlled and manipulated more easily than with RIGP. Poly(acrylonitrile)-co-poly(hydroxyethyl acrylate) chains were grown via ATRP on PE-GMA fibers to generate an adsorbent for the extraction of uranium from seawater. The prepared adsorbents in this study demonstrated promise (159.9 g- U/kg of adsorbent) in laboratory screening tests using a high uranium concentration brine and 1.24 g-U/Kg of adsorbent in the filtered natural seawater in 21-days. The modest capacity in 21- days exceeds previous efforts to generate brush-on-brush adsorbents by ATRP while manipulating the apparent surface hydrophilicity of the trunk material (PE).

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (US)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1398202

Report Number(s):: PNNL-SA-128982; AF5855000

Journal Information:: Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 38 Vol. 56; ISSN 0888-5885

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

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Photoinduced Multiple Effects to Enhance Uranium Extraction from Natural Seawater by Black Phosphorus Nanosheets Yuan, Yihui; Niu, Biye; Yu, Qiuhan Angewandte Chemie International Edition, Vol. 59, Issue 3 https://doi.org/10.1002/anie.201913644	journal	December 2019
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Polypyrrole modified Fe ⁰ -loaded graphene oxide for the enrichment of uranium( vi ) from simulated seawater Zhang, Yiming; Zhang, Hongsen; Liu, Qi Dalton Transactions, Vol. 47, Issue 37 https://doi.org/10.1039/c8dt02819b	journal	January 2018

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