Solid-Solution CrCoCuFeNi High-Entropy Alloy Thin Films Synthesized by Sputter Deposition

An, Zhinan; Jia, Haoling; Wu, Yueying; Rack, Philip D.; Patchen, Allan D.; Liu, Yuzi; Ren, Yang; Li, Nan; Liaw, Peter K.

doi:10.1080/21663831.2015.1048904

Solid-Solution CrCoCuFeNi High-Entropy Alloy Thin Films Synthesized by Sputter Deposition

Journal Article · Mon Jun 01 04:00:00 EDT 2015 · Materials Research Letters

DOI:https://doi.org/10.1080/21663831.2015.1048904· OSTI ID:1392586

An, Zhinan; Jia, Haoling; Wu, Yueying; Rack, Philip D.; Patchen, Allan D.; Liu, Yuzi; Ren, Yang; Li, Nan; Liaw, Peter K.

The concept of high configurationally entropy requires that the high-entropy alloys (HEAs) yield single-phase solid solutions. However, phase separations are quite common in bulk HEAs. A five-element alloy, CrCoCuFeNi, was deposited via radio frequency magnetron sputtering and confirmed to be a single-phase solid solution through the high-energy synchrotron X-ray diffraction, energy-dispersive spectroscopy, wavelength-dispersive spectroscopy, and transmission election microscopy. The formation of the solid-solution phase is presumed to be due to the high cooling rate of the sputter-deposition process.

Research Organization:: Argonne National Laboratory (ANL)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1392586

Journal Information:: Materials Research Letters, Journal Name: Materials Research Letters Journal Issue: 4 Vol. 3; ISSN 2166-3831

Publisher:: Taylor and Francis

Country of Publication:: United States

Language:: English

References (39)

Segregation and migration of species in the CrCoFeNi high entropy alloy Middleburgh, S. C.; King, D. M.; Lumpkin, G. R. Journal of Alloys and Compounds, Vol. 599 https://doi.org/10.1016/j.jallcom.2014.01.135	journal	June 2014
Surface-stress-induced phase transformation in metal nanowires Diao, Jiankuai; Gall, Ken; Dunn, Martin L. Nature Materials, Vol. 2, Issue 10 https://doi.org/10.1038/nmat977	journal	September 2003
Complex structure/composition relationship in thin films of AlCoCrCuFeNi high entropy alloy Dolique, V.; Thomann, A. -L.; Brault, P. Materials Chemistry and Physics, Vol. 117, Issue 1 https://doi.org/10.1016/j.matchemphys.2009.05.025	journal	September 2009
Formation and structure of V–Zr amorphous alloy thin films King, D. J. M.; Middleburgh, S. C.; Liu, A. C. Y. Acta Materialia, Vol. 83 https://doi.org/10.1016/j.actamat.2014.10.016	journal	January 2015
Microstructure characterization of AlxCo1Cr1Cu1Fe1Ni1 (x=0 and 2.5) high-entropy alloy films Wu, Z. F.; Wang, X. D.; Cao, Q. P. Journal of Alloys and Compounds, Vol. 609 https://doi.org/10.1016/j.jallcom.2014.04.094	journal	October 2014
Computer simulation of strain energy effects vs surface and interface energy effects on grain growth in thin films Carel, R.; Thompson, C. V.; Frost, H. J. Acta Materialia, Vol. 44, Issue 6 https://doi.org/10.1016/1359-6454(95)00365-7	journal	June 1996
Microstructure and electrochemical properties of high entropy alloys—a comparison with type-304 stainless steel Chen, Y. Y.; Duval, T.; Hung, U. D. Corrosion Science, Vol. 47, Issue 9 https://doi.org/10.1016/j.corsci.2004.11.008	journal	September 2005
A model for development of orientation of vapour deposits Lee, Dong Nyung Journal of Materials Science, Vol. 24, Issue 12 https://doi.org/10.1007/BF00544515	journal	December 1989
Refractory high-entropy alloys Senkov, O. N.; Wilks, G. B.; Miracle, D. B. Intermetallics, Vol. 18, Issue 9 https://doi.org/10.1016/j.intermet.2010.05.014	journal	September 2010
Electrochemical kinetics of the high entropy alloys in aqueous environments—a comparison with type 304 stainless steel Chen, Y. Y.; Hong, U. T.; Shih, H. C. Corrosion Science, Vol. 47, Issue 11 https://doi.org/10.1016/j.corsci.2004.09.026	journal	November 2005
Decomposition in multi-component AlCoCrCuFeNi high-entropy alloy Singh, S.; Wanderka, N.; Murty, B. S. Acta Materialia, Vol. 59, Issue 1 https://doi.org/10.1016/j.actamat.2010.09.023	journal	January 2011
Microstructures and Crackling Noise of AlxNbTiMoV High Entropy Alloys Chen, Shu; Yang, Xiao; Dahmen, Karin Entropy, Vol. 16, Issue 2 https://doi.org/10.3390/e16020870	journal	February 2014
Competition between surface and strain energy during grain growth in free-standing and attached Ag and Cu films on Si substrates Zhang, Jian-Min; Xu, Ke-Wei; Ji, Vincent Applied Surface Science, Vol. 187, Issue 1-2 https://doi.org/10.1016/S0169-4332(01)00782-6	journal	February 2002
Thin-film metallic glasses for substrate fatigue-property improvements Jia, Haoling; Liu, Fengxiao; An, Zhinan Thin Solid Films, Vol. 561 https://doi.org/10.1016/j.tsf.2013.12.024	journal	June 2014
Multicomponent and High Entropy Alloys Cantor, Brian Entropy, Vol. 16, Issue 9 https://doi.org/10.3390/e16094749	journal	August 2014
Thermal stability of AlCoCrCuFeNi high entropy alloy thin films studied by in-situ XRD analysis Dolique, V.; Thomann, A. -L.; Brault, P. Surface and Coatings Technology, Vol. 204, Issue 12-13 https://doi.org/10.1016/j.surfcoat.2009.12.006	journal	March 2010
Imaging of nanometer-sized precipitates in solids by electron spectroscopic imaging Hofer, F.; Warbichler, P.; Grogger, W. Ultramicroscopy, Vol. 59, Issue 1-4 https://doi.org/10.1016/0304-3991(95)00015-S	journal	July 1995
Absence of long-range chemical ordering in equimolar FeCoCrNi Lucas, M. S.; Wilks, G. B.; Mauger, L. Applied Physics Letters, Vol. 100, Issue 25 https://doi.org/10.1063/1.4730327	journal	June 2012
Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element Takeuchi, Akira; Inoue, Akihisa MATERIALS TRANSACTIONS, Vol. 46, Issue 12 https://doi.org/10.2320/matertrans.46.2817	journal	January 2005
Aluminum Alloying Effects on Lattice Types, Microstructures, and Mechanical Behavior of High-Entropy Alloys Systems Tang, Zhi; Gao, Michael C.; Diao, Haoyan JOM, Vol. 65, Issue 12 https://doi.org/10.1007/s11837-013-0776-z	journal	October 2013
Enhanced spin signals due to native oxide formation in Ni80Fe20/Ag lateral spin valves Mihajlović, Goran; Schreiber, Daniel K.; Liu, Yuzi Applied Physics Letters, Vol. 97, Issue 11 https://doi.org/10.1063/1.3484141	journal	September 2010
Solid-Solution Phase Formation Rules for Multi-component Alloys Zhang, Y.; Zhou, Y. J.; Lin, J. P. Advanced Engineering Materials, Vol. 10, Issue 6, p. 534-538 https://doi.org/10.1002/adem.200700240	journal	June 2008
Fabrication and characterizations of thin film metallic glasses: Antibacterial property and durability study for medical application Chu, Jinn P.; Liu, Tz-Yah; Li, Chia-Lin Thin Solid Films, Vol. 561 https://doi.org/10.1016/j.tsf.2013.08.111	journal	June 2014
Imperfect Oriented Attachment: Dislocation Generation in Defect-Free Nanocrystals Penn, R. Lee; Banfield, Jillian F. Science, Vol. 281, Issue 5379, p. 969-971 https://doi.org/10.1126/science.281.5379.969	journal	August 1998
Nanostructured nitride films of multi-element high-entropy alloys by reactive DC sputtering Chen, T. K.; Shun, T. T.; Yeh, J. W. Surface and Coatings Technology, Vol. 188-189 https://doi.org/10.1016/j.surfcoat.2004.08.023	journal	November 2004
Mechanical properties of metallic glass matrix composites: Effects of reinforcement character and connectivity Fu, X. L.; Li, Y.; Schuh, C. A. Scripta Materialia, Vol. 56, Issue 7 https://doi.org/10.1016/j.scriptamat.2006.12.010	journal	April 2007
A fracture-resistant high-entropy alloy for cryogenic applications Gludovatz, B.; Hohenwarter, A.; Catoor, D. Science, Vol. 345, Issue 6201 https://doi.org/10.1126/science.1254581	journal	September 2014
Embedded-atom method: Derivation and application to impurities, surfaces, and other defects in metals Daw, Murray S.; Baskes, M. I. Physical Review B, Vol. 29, Issue 12 https://doi.org/10.1103/PhysRevB.29.6443	journal	June 1984
Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes Yeh, J.-W.; Chen, S.-K.; Lin, S.-J. Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303 https://doi.org/10.1002/adem.200300567	journal	May 2004
Microstructure and properties of age-hardenable AlxCrFe1.5MnNi0.5 alloys Chen, Shin-Tsung; Tang, Wei-Yeh; Kuo, Yen-Fu Materials Science and Engineering: A, Vol. 527, Issue 21-22 https://doi.org/10.1016/j.msea.2010.05.052	journal	August 2010
Microstructure and wear behavior of AlxCo1.5CrFeNi1.5Tiy high-entropy alloys Chuang, Ming-Hao; Tsai, Ming-Hung; Wang, Woei-Ren Acta Materialia, Vol. 59, Issue 16 https://doi.org/10.1016/j.actamat.2011.06.041	journal	September 2011
Bendable bulk metallic glass: Effects of a thin, adhesive, strong, and ductile coating Chu, Jinn P.; Greene, J. E.; Jang, Jason S. C. Acta Materialia, Vol. 60, Issue 6-7 https://doi.org/10.1016/j.actamat.2012.02.037	journal	April 2012
Microstructures and properties of high-entropy alloys Zhang, Yong; Zuo, Ting Ting; Tang, Zhi Progress in Materials Science, Vol. 61 https://doi.org/10.1016/j.pmatsci.2013.10.001	journal	April 2014
Microstructure, hardness, resistivity and thermal stability of sputtered oxide films of AlCoCrCu0.5NiFe high-entropy alloy Huang, Yuan-Sheng; Chen, Ling; Lui, Hong-Wei Materials Science and Engineering: A, Vol. 457, Issue 1-2 https://doi.org/10.1016/j.msea.2006.12.001	journal	May 2007
Design and performance of the 33-BM beamline at the Advanced Photon Source Karapetrova, Evguenia; Ice, Gene; Tischler, Jonathan Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 649, Issue 1 https://doi.org/10.1016/j.nima.2010.12.159	journal	September 2011
Thickness Induced Structural Transition in Suspended fcc Metal Nanofilms Hasmy, Anwar; Medina, Ernesto Physical Review Letters, Vol. 88, Issue 9 https://doi.org/10.1103/PhysRevLett.88.096103	journal	February 2002
Fatigue behavior of Al0.5CoCrCuFeNi high entropy alloys Hemphill, M. A.; Yuan, T.; Wang, G. Y. Acta Materialia, Vol. 60, Issue 16 https://doi.org/10.1016/j.actamat.2012.06.046	journal	September 2012
Temperature Effects on Deformation and Serration Behavior of High-Entropy Alloys (HEAs) Antonaglia, J.; Xie, X.; Tang, Z. JOM, Vol. 66, Issue 10 https://doi.org/10.1007/s11837-014-1130-9	journal	September 2014
Mechanical performance of the Al x CoCrCuFeNi high-entropy alloy system with multiprincipal elements Tong, Chung-Jin; Chen, Min-Rui; Yeh, Jien-Wei Metallurgical and Materials Transactions A, Vol. 36, Issue 5 https://doi.org/10.1007/s11661-005-0218-9	journal	May 2005

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Transformations in CrFeCoNiCu High Entropy Alloy Thin Films during In-Situ Annealing in TEM Arfaoui, Mohamed; Radnóczi, György; Kovács Kis, Viktória Coatings, Vol. 10, Issue 1 https://doi.org/10.3390/coatings10010060	journal	January 2020
Microstructure, Mechanical and Corrosion Behaviors of CoCrFeNiAl0.3 High Entropy Alloy (HEA) Films Gao, Libo; Liao, Weibing; Zhang, Hongti Coatings, Vol. 7, Issue 10 https://doi.org/10.3390/coatings7100156	journal	September 2017
Structural and Mechanical Properties of AlCoCrNi High Entropy Nitride Films: Influence of Process Pressure Kim, Young Seok; Park, Hae Jin; Lim, Ki Seong Coatings, Vol. 10, Issue 1 https://doi.org/10.3390/coatings10010010	journal	December 2019
Formation of a hexagonal closed-packed phase in Al _0.5 CoCrFeNi high entropy alloy Wang, J.; Zhang, Y.; Niu, S. Z. MRS Communications, Vol. 7, Issue 4 https://doi.org/10.1557/mrc.2017.109	journal	October 2017
High-Entropy Alloy (HEA)-Coated Nanolattice Structures and Their Mechanical Properties Gao, Libo; Song, Jian; Jiao, Zengbao Advanced Engineering Materials, Vol. 20, Issue 1 https://doi.org/10.1002/adem.201700625	journal	September 2017
Microstructures and properties of high-entropy alloy films and coatings: a review Li, Wei; Liu, Ping; Liaw, Peter K. Materials Research Letters, Vol. 6, Issue 4 https://doi.org/10.1080/21663831.2018.1434248	journal	February 2018

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Solid-Solution CrCoCuFeNi High-Entropy Alloy Thin Films Synthesized by Sputter Deposition An, Zhinan; Jia, Haoling; Wu, Yueying https://doi.org/10.6084/m9.figshare.1431795.v2 The current record is supplemented by this text	text	January 2015
Solid-Solution CrCoCuFeNi High-Entropy Alloy Thin Films Synthesized by Sputter Deposition An, Zhinan; Jia, Haoling; Wu, Yueying https://doi.org/10.6084/m9.figshare.1431795 The current record is a previous version of this text	text	January 2015
Solid-Solution CrCoCuFeNi High-Entropy Alloy Thin Films Synthesized by Sputter Deposition An, Zhinan; Jia, Haoling; Wu, Yueying https://doi.org/10.6084/m9.figshare.1431795.v2 The current record is a supplement to this text	text	January 2015

Solid-Solution CrCoCuFeNi High-Entropy Alloy Thin Films Synthesized by Sputter Deposition

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