Polyvinylpyrrolidone (PVP)-Capped Pt Nanocubes with Superior Peroxidase-Like Activity

Ye, Haihang; Liu, Yuzi; Chhabra, Ashima; Lilla, Emily; Xia, Xiaohu

doi:10.1002/cnma.201600268

Polyvinylpyrrolidone (PVP)-Capped Pt Nanocubes with Superior Peroxidase-Like Activity

Journal Article · Wed Dec 21 04:00:00 EST 2016 · ChemNanoMat

DOI:https://doi.org/10.1002/cnma.201600268· OSTI ID:1389648

Ye, Haihang ^[1]; Liu, Yuzi ^[2]; Chhabra, Ashima ^[1]; Lilla, Emily ^[1]; Xia, Xiaohu ^[1]

Department of Chemistry, Michigan Technological University, Houghton Michigan 49931 United States
Center for Nanoscale Materials, Argonne National Laboratory, Argonne Illinois 60439 United States

Peroxidase mimics of inorganic nanoparticles are expected to circumvent the inherent issues of natural peroxidases, providing enhanced performance in important applications such as diagnosis and imaging. Despite the report of a variety of peroxidase mimics in the past decade, very limited progress has been made on improving their catalytic efficiency. The catalytic efficiencies of most previously reported mimics are only up to one order of magnitude higher than those of natural peroxidases. In this work, we demonstrate a type of highly efficient peroxidase mimic – polyvinylpyrrolidone (PVP)-capped Pt nanocubes of sub-10 nm in size. These PVP-capped Pt cubes are ~200-fold more active than the natural counterparts and exhibit a record-high specific catalytic efficiency. In addition to the superior efficiency, the new mimic shows several other promising features, including excellent stabilities, well-controlled uniformity in both size and shape, controllable sizes, and facile and scalable production.

Research Organization:: Argonne National Laboratory (ANL)

Sponsoring Organization:: USDOE Office of Science - Office of Basic Energy Sciences - Scientific User Facilities Division

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1389648

Journal Information:: ChemNanoMat, Journal Name: ChemNanoMat Journal Issue: 1 Vol. 3; ISSN 2199-692X

Publisher:: Wiley

Country of Publication:: United States

Language:: English

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