A Tunable 3D Nanostructured Conductive Gel Framework Electrode for High-Performance Lithium Ion Batteries

Shi, Ye; Zhang, Jun; Bruck, Andrea M.; Zhang, Yiman; Li, Jing; Stach, Eric A.; Takeuchi, Kenneth J.; Marschilok, Amy C.; Takeuchi, Esther S.; Yu, Guihua

doi:10.1002/adma.201603922

A Tunable 3D Nanostructured Conductive Gel Framework Electrode for High-Performance Lithium Ion Batteries

Journal Article · Wed Mar 22 00:00:00 EDT 2017 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201603922· OSTI ID:1388500

Shi, Ye ^[1]; Zhang, Jun ^[1]; Bruck, Andrea M. ^[2]; Zhang, Yiman ^[2]; Li, Jing ^[3]; Stach, Eric A. ^[3]; Takeuchi, Kenneth J. ^[4]; Marschilok, Amy C. ^[4]; Takeuchi, Esther S. ^[5]; Yu, Guihua ^[1]

Univ. of Texas, Austin, TX (United States). Materials Science and Engineering Program, and Dept. of Mechanical Engineering
Stony Brook Univ., NY (United States). Dept. of Chemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials
Stony Brook Univ., NY (United States). Dept. of Chemistry, and Dept. of Materials Science and Engineering
Stony Brook Univ., NY (United States). Dept. of Chemistry, and Dept. of Materials Science and Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate

This study develops a tunable 3D nanostructured conductive gel framework as both binder and conductive framework for lithium ion batteries. A 3D nanostructured gel framework with continuous electron pathways can provide hierarchical pores for ion transport and form uniform coatings on each active particle against aggregation. The hybrid gel electrodes based on a polypyrrole gel framework and Fe₃O₄ nanoparticles as a model system in this study demonstrate the best rate performance, the highest achieved mass ratio of active materials, and the highest achieved specific capacities when considering total electrode mass, compared to current literature. Finally, this 3D nanostructured gel-based framework represents a powerful platform for various electrochemically active materials to enable the next-generation high-energy batteries.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012673

OSTI ID:: 1388500

Alternate ID(s):: OSTI ID: 1401897
OSTI ID: 1462424

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 22 Vol. 29; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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