A Neutrally Charged Trimethylmanganese(III) Complex: Synthesis, Characterization, and Disproportionation Chemistry

Stalzer, Madelyn M.; Telser, Joshua; Krzystek, Jurek; Motta, Alessandro; Delferro, Massimiliano; Marks, Tobin J.

doi:10.1021/acs.organomet.6b00422

A Neutrally Charged Trimethylmanganese(III) Complex: Synthesis, Characterization, and Disproportionation Chemistry

Journal Article · Tue Aug 02 04:00:00 EDT 2016 · Organometallics

DOI:https://doi.org/10.1021/acs.organomet.6b00422· OSTI ID:1387941

Stalzer, Madelyn M. ^[1]; Telser, Joshua ^[2]; Krzystek, Jurek ^[3]; Motta, Alessandro ^[4]; Delferro, Massimiliano ^[5]; Marks, Tobin J. ^[1]

Northwestern Univ., Evanston, IL (United States)
Roosevelt Univ., Chicago, IL (United States)
Florida State Univ., Tallahassee, FL (United States)
Univ. degli Studi di Roma (Italy)
Argonne National Lab. (ANL), Argonne, IL (United States)

The synthesis and properties of an unusual, neutrally charged and volatile N,N,N',N'-tetramethylethylenediamine trimethyl manganese(III) complex, (TMEDA)MnMe₃, are described, along with its facile disproportionation to the corresponding Mn(II) and Mn(IV) complexes. Characterization by single-crystal XRD, UV–vis spectroscopy, high-frequency and -field EPR (HFEPR), magnetic susceptibility, and density functional theory (DFT) computations indicate that the (TMEDA)MnMe₃ electronic structure can be described as largely square pyramidal Mn(III) centered. Finally, the paucity of manganese(III) polyalkyls and the simplicity and reactivity of this compound implicate it as a potentially useful synthetic building block.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Electrical Energy Storage (CEES)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1387941

Alternate ID(s):: OSTI ID: 1326935

Journal Information:: Organometallics, Journal Name: Organometallics Journal Issue: 16 Vol. 35; ISSN 0276-7333

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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CCDC 1481453: Experimental Crystal Structure Determination Stalzer, Madelyn M.; Krzystek, Jurek; Motta, Alessandro https://doi.org/10.5517/ccdc.csd.cc1lqktp The current record is supplemented by this dataset	dataset	January 2016
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