Nanocrystalline iron oxide based electroactive materials in lithium ion batteries: the critical role of crystallite size, morphology, and electrode heterostructure on battery relevant electrochemistry

Bruck, Andrea M.; Cama, Christina A.; Gannett, Cara N.; Marschilok, Amy C.; Takeuchi, Esther S.; Takeuchi, Kenneth J.

doi:10.1039/C5QI00247H

Nanocrystalline iron oxide based electroactive materials in lithium ion batteries: the critical role of crystallite size, morphology, and electrode heterostructure on battery relevant electrochemistry

Journal Article · Tue Dec 08 00:00:00 EST 2015 · Inorganic Chemistry Frontiers (Online)

DOI:https://doi.org/10.1039/C5QI00247H· OSTI ID:1387419

Bruck, Andrea M. ^[1]; Cama, Christina A. ^[1]; Gannett, Cara N. ^[2]; Marschilok, Amy C. ^[1]; Takeuchi, Esther S. ^[3]; Takeuchi, Kenneth J. ^[1]

Stony Brook Univ., NY (United States)
State Univ. of New York (SUNY), Geneseo, NY (United States); Stony Brook Univ., NY (United States)
Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

The importance of crystallite size control and direct synthesis of materials with desirable properties is broadly applicable for the rational design and development of new active materials for energy storage. Recently, the use of nanoparticles and crystallite size control has redefined electrode design strategies, due in part to the large surface area/volume ratios providing more pathways for ion movement within the bulk electrode. This review is structured primarily as a case study, where reports involving a specific densely structured iron oxide, magnetite, Fe₃O₄, and its use as an electrode in LIBs are used as examples. Due to the high theoretical capacity (924 mA h g^–1), and opportunity for implementation of a low cost electrode material, magnetite was selected as the model material for this review. Notably, crystallite size, morphology, and electrode heterostructure can all play a critical role in battery relevant electrochemistry, particularly for crystallographically dense materials such as Fe₃O₄. Several examples of Fe₃O₄ based composites are described, incorporating different types of conductive materials such as carbons as part of the structure. Further, this review also provides a brief introduction to a newer iron oxide based material with a 2D layered structure, silver ferrite, where crystallite size control was synthetically achieved. By focusing on two specific iron oxide based nanoscale inorganic materials, this review highlights and distinguishes the contributions of electroactive material crystallite size, morphology and electrode heterostructure to electrochemical behavior, facilitating the future development of next generation of battery electrodes.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012673

OSTI ID:: 1387419

Journal Information:: Inorganic Chemistry Frontiers (Online), Journal Name: Inorganic Chemistry Frontiers (Online) Journal Issue: 1 Vol. 3; ISSN 2052-1553; ISSN ICFNAW

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Development of Lithium-ion Batteries from Micro-Structured to Nanostructured Materials: Its Issues and Challenges Kumar, Harish; Rajan, Sundar; Shukla, Ashok K. Science Progress, Vol. 95, Issue 3 https://doi.org/10.3184/003685012X13421145651372	journal	September 2012
Electrostatic Self-Assembly of Fe3O4 Nanoparticles on Graphene Oxides for High Capacity Lithium-Ion Battery Anodes Yoon, Taegyune; Kim, Jaegyeong; Kim, Jinku Energies, Vol. 6, Issue 9 https://doi.org/10.3390/en6094830	journal	September 2013
Modeling the Mesoscale Transport of Lithium-Magnetite Electrodes Using Insight from Discharge and Voltage Recovery Experiments Knehr, K. W.; Brady, Nicholas William; Cama, Christina A. Columbia University https://doi.org/10.7916/d83r0tcd	text	January 2015

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Self-recovery in Li-metal hybrid lithium-ion batteries via WO ₃ reduction Pathak, Rajesh; Gurung, Ashim; Elbohy, Hytham Nanoscale, Vol. 10, Issue 34 https://doi.org/10.1039/c8nr01507d	journal	January 2018
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Disentangling the role of oxygen vacancies on the surface of Fe ₃ O ₄ and γ-Fe ₂ O ₃ Jian, Wei; Wang, Shi-Ping; Zhang, Hong-Xing Inorganic Chemistry Frontiers, Vol. 6, Issue 10 https://doi.org/10.1039/c9qi00351g	journal	January 2019
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Probing enhanced lithium-ion transport kinetics in 2D holey nanoarchitectured electrodes Zhang, Xiao; Bruck, Andrea M.; Zhu, Yue Nano Futures, Vol. 2, Issue 3 https://doi.org/10.1088/2399-1984/aada90	journal	August 2018

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