Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands

Thangavelu, Sonia G.; Pope, Simon J.  A.; Cahill, Christopher L.

doi:10.1039/c5ce00984g

Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands

Journal Article · Mon Jul 13 00:00:00 EDT 2015 · CrystEngComm

DOI:https://doi.org/10.1039/c5ce00984g· OSTI ID:1386741

Thangavelu, Sonia G. ^[1]; Pope, Simon J. A. ^[2]; Cahill, Christopher L. ^[1]

George Washington Univ., Washington, DC (United States)
Cardiff Univ., Cardiff (United Kingdom)

In this work, seven uranyl coordination polymers [(UO₂)(BrC₈H₃O₄)(C₁₅H₁₁N₃)] (1), [(UO₂)(ClC₈H₃O₄)(C₁₅H₁₁N₃)] (2), [(UO₂)(BrC₈H₃O₄)(C₁₈H₁₂N₆)]·H₂O (3), [(UO₂)(ClC₈H₃O₄)(C₁₈H₁₂N₆)]·2H₂O (4), [(UO₂)(C₈H₃IO₄)(C₁₈H₁₂N₆)]·2C₃H₇O (5), [(UO₂)(C₉H₆O₄)(C₁₈H₁₂N₆)]·H₂O (6), and [(UO₂)(C₆H₂O₄S)(C₁₈H₁₂N₆)]·2H₂O (7) containing N-donor ligands 2,2':6',2''-terpyridine (TPY) and 2,4,6-tripyridyl s-triazine (TPTZ); and O-donor linkers thiophene 2,5-dicarboxylic acid (TDC) and X-1,4-benzene dicarboxylic acid (X-BDC, where X = Me, Cl, Br, I) were synthesized and characterized using single crystal X-ray diffraction (SC-XRD), powder X-ray diffraction (PXRD), and fluorescence spectroscopy. Each compound crystallizes as binuclear pseudo dimers containing a UO₂²⁺ pentagonal bipyramidal primary building unit. Fluorescence spectra of 1–4, and 6–7 show characteristic UO₂²⁺ emission whereas 5 is non-emissive. Red shifts within the emission of 1–4 are noted as a function of N-donor ligands TPY and TPTZ whereas emission shifts are not observed in TPTZ bearing compounds (3, 4, 6, 7) containing different O-donor linkers. Luminescent lifetimes of 1–7 were obtained and fitted with either bi-exponential or tri-exponential components.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001089

OSTI ID:: 1386741

Journal Information:: CrystEngComm, Journal Name: CrystEngComm Journal Issue: 32 Vol. 17; ISSN CRECF4; ISSN 1466-8033

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (67)

Water-Insoluble Ag-U-Organic Assemblies with Photocatalytic Activity Yu, Zhen-Tao; Liao, Zuo-Lei; Jiang, Yu-Sheng Chemistry - A European Journal, Vol. 11, Issue 9 https://doi.org/10.1002/chem.200401189	journal	April 2005
Heavy Atom Effect Driven Organic Phosphors and Their Luminescent Lanthanide Metal-Organic Frameworks Balamurugan, Ayyakkalai; Gupta, Arvind Kumar; Boomishankar, Ramamoorthy ChemPlusChem, Vol. 78, Issue 7 https://doi.org/10.1002/cplu.201300121	journal	June 2013
Synthesis, Structure and Photoluminescent Studies of Two Novel Layered Uranium Coordination Polymers Constructed from UO(OH) Polyhedra and Pyridinedicarboxylates Zheng, Yan-Zhen; Tong, Ming-Liang; Chen, Xiao-Ming European Journal of Inorganic Chemistry, Vol. 2005, Issue 20 https://doi.org/10.1002/ejic.200500399	journal	October 2005
Solid-State Luminescence and π-Stacking in Crystalline Uranyl Dipicolinates Harrowfield, Jack M.; Lugan, Noël; Shahverdizadeh, Gholam H. European Journal of Inorganic Chemistry, Vol. 2006, Issue 2 https://doi.org/10.1002/ejic.200500671	journal	January 2006
Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymers Haquin, Victor; Etienne, Mael; Daiguebonne, Carole European Journal of Inorganic Chemistry, Vol. 2013, Issue 20 https://doi.org/10.1002/ejic.201300381	journal	June 2013
Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules: Crystal Chemistry of Uranyl Carboxylate Coordination Networks Mihalcea, Ionut; Henry, Natacha; Loiseau, Thierry European Journal of Inorganic Chemistry, Vol. 2014, Issue 8 https://doi.org/10.1002/ejic.201301575	journal	February 2014
Uranium(VI) speciation by spectroscopy Meinrath, G. Journal of Radioanalytical and Nuclear Chemistry, Vol. 224, Issue 1-2 https://doi.org/10.1007/BF02034623	journal	October 1997
Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties Kerr, Andrew T.; Kumalah, Sayon A.; Holman, K. T. Journal of Inorganic and Organometallic Polymers and Materials, Vol. 24, Issue 1 https://doi.org/10.1007/s10904-013-9980-0	journal	October 2013
Characterisation of the dimer formed by hydrolysis of uranyl in aqueous solution and its role in the biexponential luminescence decay Lopez, M.; Birch, D. J. S. Chemical Physics Letters, Vol. 268, Issue 1-2 https://doi.org/10.1016/S0009-2614(97)00185-1	journal	April 1997
Developments in the photophysics and photochemistry of actinide ions and their coordination compounds Natrajan, Louise S. Coordination Chemistry Reviews, Vol. 256, Issue 15-16 https://doi.org/10.1016/j.ccr.2012.03.029	journal	August 2012
Anharmonic charge transfer vibronic states and luminescence dynamics of uranyl compounds Liu, G. K.; Vikhnin, V. S. Chemical Physics Letters, Vol. 437, Issue 1-3 https://doi.org/10.1016/j.cplett.2007.02.006	journal	March 2007
Synthesis, structure characterization and photocatalytic properties of two new uranyl naphthalene-dicarboxylate coordination polymer compounds Xia, Yin; Wang, Kai-Xue; Chen, Jie-Sheng Inorganic Chemistry Communications, Vol. 13, Issue 12 https://doi.org/10.1016/j.inoche.2010.09.008	journal	December 2010
Syntheses, structures and luminescent properties of two organic templated uranyl phosphonates Wu, Hong-Yue; Ma, Yu-Qin; Zhang, Xiuwu Inorganic Chemistry Communications, Vol. 34 https://doi.org/10.1016/j.inoche.2013.05.004	journal	August 2013
Ligand sensitized luminescence of uranyl by benzoic acid in acetonitrile medium: A new luminescent uranyl benzoate specie Kumar, Satendra; Maji, S.; Joseph, M. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 138 https://doi.org/10.1016/j.saa.2014.11.033	journal	March 2015
Hydrogen Bridges in Crystal Engineering: Interactions without Borders Desiraju, Gautam R. Accounts of Chemical Research, Vol. 35, Issue 7 https://doi.org/10.1021/ar010054t	journal	July 2002
Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds Wang, Kai-Xue; Chen, Jie-Sheng Accounts of Chemical Research, Vol. 44, Issue 7 https://doi.org/10.1021/ar200042t	journal	July 2011
Complete Series of Monohalogenated Isoreticular Metal–Organic Frameworks: Synthesis and the Importance of Activation Method Meek, Scott T.; Perry, John J.; Teich-McGoldrick, Stephanie L. Crystal Growth & Design, Vol. 11, Issue 10 https://doi.org/10.1021/cg201136k	journal	October 2011
Crystal Engineering with the Uranyl Cation III. Mixed Aliphatic Dicarboxylate/Aromatic Dipyridyl Coordination Polymers: Synthesis, Structures, and Speciation Kerr, Andrew T.; Cahill, Christopher L. Crystal Growth & Design, Vol. 11, Issue 12 https://doi.org/10.1021/cg2011869	journal	December 2011
Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel Systems Mihalcea, Ionut; Henry, Natacha; Volkringer, Christophe Crystal Growth & Design, Vol. 12, Issue 1 https://doi.org/10.1021/cg201509v	journal	December 2011
Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers Mihalcea, Ionut; Henry, Natacha; Bousquet, Till Crystal Growth & Design, Vol. 12, Issue 9 https://doi.org/10.1021/cg300853f	journal	August 2012
Ionothermal and Hydrothermal Flux Syntheses of Five New Uranyl Phosphonates Parker, T. Gannon; Cross, Justin N.; Polinski, Matthew J. Crystal Growth & Design, Vol. 14, Issue 1 https://doi.org/10.1021/cg401435w	journal	December 2013
Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent Thuéry, Pierre; Harrowfield, Jack Crystal Growth & Design, Vol. 14, Issue 3 https://doi.org/10.1021/cg4018163	journal	January 2014
Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands Yang, Weiting; Yi, Fei-Yan; Tian, Tao Crystal Growth & Design, Vol. 14, Issue 3 https://doi.org/10.1021/cg401850v	journal	January 2014
Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence Kerr, Andrew T.; Cahill, Christopher L. Crystal Growth & Design, Vol. 14, Issue 4 https://doi.org/10.1021/cg500050q	journal	March 2014
CuPYDC Metalloligands and Postsynthetic Rearrangement/Metalation as Routes to Bimetallic Uranyl Containing Hybrid Materials: Syntheses, Structures, and Fluorescence Kerr, Andrew T.; Cahill, Christopher L. Crystal Growth & Design, Vol. 14, Issue 8 https://doi.org/10.1021/cg5007132	journal	July 2014
Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye Li, Hao-Hong; Zeng, Xian-Hua; Wu, Hong-Yan Crystal Growth & Design, Vol. 15, Issue 1 https://doi.org/10.1021/cg501252x	journal	December 2014
Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures Andrews, Michael B.; Cahill, Christopher L. Chemical Reviews, Vol. 113, Issue 2 https://doi.org/10.1021/cr300202a	journal	August 2012
Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products Knope, Karah E.; Soderholm, L. Chemical Reviews, Vol. 113, Issue 2 https://doi.org/10.1021/cr300212f	journal	October 2012
Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO ₂ (C ₆ H ₈ O ₄ )(H ₂ O) ₂ and Three-Dimensional UO ₂ (C ₆ H ₈ O ₄ ) Borkowski, Lauren A.; Cahill, Christopher L. Inorganic Chemistry, Vol. 42, Issue 22 https://doi.org/10.1021/ic030196e	journal	November 2003
Exploring Lanthanide Luminescence in Metal-Organic Frameworks: Synthesis, Structure, and Guest-Sensitized Luminescence of a Mixed Europium/Terbium-Adipate Framework and a Terbium-Adipate Framework de Lill, Daniel T.; de Bettencourt-Dias, Ana; Cahill, Christopher L. Inorganic Chemistry, Vol. 46, Issue 10 https://doi.org/10.1021/ic062019u	journal	May 2007
Hydrothermal Synthesis of Uranyl Squarates and Squarate-Oxalates: Hydrolysis Trends and in Situ Oxalate Formation Rowland, Clare E.; Cahill, Christopher L. Inorganic Chemistry, Vol. 49, Issue 14 https://doi.org/10.1021/ic100887c	journal	July 2010
Uranyl Sensitization of Samarium(III) Luminescence in a Two-Dimensional Coordination Polymer Knope, Karah E.; de Lill, Daniel T.; Rowland, Clare E. Inorganic Chemistry, Vol. 51, Issue 1 https://doi.org/10.1021/ic201450e	journal	December 2011
Increased Antenna Effect of the Lanthanide Complexes by Control of a Number of Terdentate N-Donor Pyridine Ligands Yip, Yuk-Wang; Wen, Hongli; Wong, Wing-Tak Inorganic Chemistry, Vol. 51, Issue 13 https://doi.org/10.1021/ic300916e	journal	June 2012
Environmental Speciation of Actinides Maher, Kate; Bargar, John R.; Brown, Gordon E. Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic301686d	journal	June 2012
Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers Thangavelu, Sonia G.; Andrews, Michael B.; Pope, Simon J. A. Inorganic Chemistry, Vol. 52, Issue 4 https://doi.org/10.1021/ic3024698	journal	January 2013
Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies Yang, Weiting; Tian, Tao; Wu, Hong-Yue Inorganic Chemistry, Vol. 52, Issue 5 https://doi.org/10.1021/ic302847g	journal	February 2013
Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds Liao, Zuo-Lei; Li, Guo-Dong; Bi, Ming-Hui Inorganic Chemistry, Vol. 47, Issue 11 https://doi.org/10.1021/ic800109y	journal	June 2008
Structural Variation within Homometallic Uranium(VI) Carboxyphosphonates: In Situ Ligand Synthesis, Directed Assembly, Metal−Ligand Coordination and Hydrogen Bonding Knope, Karah E.; Cahill, Christopher L. Inorganic Chemistry, Vol. 47, Issue 17 https://doi.org/10.1021/ic800683m	journal	September 2008
Quenching of the uranyl fluorescence by aromatic molecules Matsushima, Ryoka; Sakuraba, Shukichi Journal of the American Chemical Society, Vol. 93, Issue 26 https://doi.org/10.1021/ja00755a004	journal	December 1971
Mechanism of quenching of the uranyl fluorescence by organic compounds Matsushima, Ryoka Journal of the American Chemical Society, Vol. 94, Issue 17 https://doi.org/10.1021/ja00772a012	journal	August 1972
Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host−Guest Interactions Devic, Thomas; Horcajada, Patricia; Serre, Christian Journal of the American Chemical Society, Vol. 132, Issue 3 https://doi.org/10.1021/ja9092715	journal	January 2010
Quenching of IR Luminescence of Erbium, Neodymium, and Ytterbium β-Diketonate Complexes by Ligand C−H and C−D Bonds Tan, Rendy H. C.; Motevalli, Majid; Abrahams, Isaac The Journal of Physical Chemistry B, Vol. 110, Issue 48 https://doi.org/10.1021/jp0654462	journal	December 2006
Electronic Structure and Bonding in Actinyl Ions and their Analogs Denning, Robert G. The Journal of Physical Chemistry A, Vol. 111, Issue 20 https://doi.org/10.1021/jp071061n	journal	May 2007
Deactivation processes of the lowest excited state of [UO ₂ (H ₂ O) ₅ ] ²⁺ in aqueous solution Formosinho, Sebastião J.; Burrows, Hugh D.; da Graça Miguel, Maria Photochem. Photobiol. Sci., Vol. 2, Issue 5 https://doi.org/10.1039/B300346A	journal	January 2003
Syntheses, structures and fluorescent properties of two novel coordination polymers in the U–Cu–H ₃ pdc system Frisch, Mark; Cahill, Christopher L. Dalton Trans., Issue 8 https://doi.org/10.1039/B500127G	journal	January 2005
Lanthanide luminescence for functional materials and bio-sciences Eliseeva, Svetlana V.; Bünzli, Jean-Claude G. Chem. Soc. Rev., Vol. 39, Issue 1 https://doi.org/10.1039/B905604C	journal	January 2010
Synthesis and crystal structures of lanthanide 4-benzyloxy benzoates: Influence of electron-withdrawing and electron-donating groups on luminescent properties Sivakumar, Sarika; Reddy, M. L. P.; Cowley, Alan H. Dalton Trans., Vol. 39, Issue 3 https://doi.org/10.1039/B917256D	journal	January 2010
Non-radiative deactivation of the excited states of europium, terbium and ytterbium complexes by proximate energy-matched OH, NH and CH oscillators: an improved luminescence method for establishing solution hydration states Beeby, Andrew; Clarkson, Ian M.; Dickins, Rachel S. Journal of the Chemical Society, Perkin Transactions 2, Issue 3 https://doi.org/10.1039/a808692c	journal	January 1999
A critical account on π–π stacking in metal complexes with aromatic nitrogen-containing ligands † Janiak, Christoph Journal of the Chemical Society, Dalton Transactions, Issue 21 https://doi.org/10.1039/b003010o	journal	January 2000
Taking advantage of luminescent lanthanide ions Bünzli, Jean-Claude G.; Piguet, Claude Chemical Society Reviews, Vol. 34, Issue 12 https://doi.org/10.1039/b406082m	journal	January 2005
Synthesis, structure and fluorescent studies of novel uranium coordination polymers in the pyridinedicarboxylic acid system Frisch, Mark; Cahill, Christopher L. Dalton Transactions, Issue 39 https://doi.org/10.1039/b608187h	journal	January 2006
Probing the local coordination environment and nuclearity of uranyl(vi) complexes in non-aqueous media by emission spectroscopy Redmond, Michael P.; Cornet, Stephanie M.; Woodall, Sean D. Dalton Transactions, Vol. 40, Issue 15 https://doi.org/10.1039/c0dt01464h	journal	January 2011
Combining coordination and supramolecular chemistry for the formation of uranyl-organic hybrid materials Deifel, Nicholas P.; Cahill, Christopher L. Chemical Communications, Vol. 47, Issue 21 https://doi.org/10.1039/c1cc11116g	journal	January 2011
Rethinking the term “pi-stacking” Martinez, Chelsea R.; Iverson, Brent L. Chemical Science, Vol. 3, Issue 7 https://doi.org/10.1039/c2sc20045g	journal	January 2012
An exploration of homo- and heterometallic UO22+ hybrid materials containing chelidamic acid: synthesis, structure, and luminescence studies Cantos, Paula M.; Pope, Simon J. A.; Cahill, Christopher L. CrystEngComm, Vol. 15, Issue 44 https://doi.org/10.1039/c3ce41655k	journal	January 2013
Chiral one- to three-dimensional uranyl–organic assemblies from (1R,3S)-(+)-camphoric acid Thuéry, Pierre; Harrowfield, Jack CrystEngComm, Vol. 16, Issue 14 https://doi.org/10.1039/c3ce42613k	journal	January 2014
The photochemistry of the uranyl ion Burrows, H. D.; Kemp, T. J. Chemical Society Reviews, Vol. 3, Issue 2 https://doi.org/10.1039/cs9740300139	journal	January 1974
Photochemistry and exciplex of the uranyl ion in aqueous solution Marcantonatos, Minas D. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 76, Issue 0 https://doi.org/10.1039/f19807601093	journal	January 1980
Photophysics of the excited uranyl ion in aqueous solutions. Part 1.—Reversible crossing Formosinho, Sebastião J.; Miguel, Maria da Graça M.; Burrows, Hugh D. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 80, Issue 7 https://doi.org/10.1039/f19848001717	journal	January 1984
The second emission of the uranyl ion in aqueous solution Marcantonatos, Minas D.; Pawlowska, Magdalena M. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 85, Issue 8 https://doi.org/10.1039/f19898502481	journal	January 1989
Completion and refinement of crystal structures with SIR 92 Altomare, A.; Cascarano, G.; Giacovazzo, C. Journal of Applied Crystallography, Vol. 26, Issue 3 https://doi.org/10.1107/S0021889892010331	journal	June 1993
WinGX suite for small-molecule single-crystal crystallography Farrugia, Louis J. Journal of Applied Crystallography, Vol. 32, Issue 4 https://doi.org/10.1107/S0021889899006020	journal	August 1999
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Structure validation in chemical crystallography Spek, Anthony L. Acta Crystallographica Section D Biological Crystallography, Vol. 65, Issue 2, p. 148-155 https://doi.org/10.1107/S090744490804362X	journal	January 2009
Time-Resolved Laser-Induced Fluorescence as a Unique Tool for Low-Level Uranium Speciation Moulin, Christophe; Laszak, Ivan; Moulin, Valérie Applied Spectroscopy, Vol. 52, Issue 4 https://doi.org/10.1366/0003702981944076	journal	April 1998
Study of uranyl(VI) malonate complexation by time resolved laser-induced fluorescence spectroscopy (TRLFS) Brachmann, A.; Geipel, Gerhard; Bernhard, G. Radiochimica Acta, Vol. 90, Issue 3 https://doi.org/10.1524/ract.2002.90.3_2002.147	journal	January 2002
First 5f-element complexes with the tetradentate BTBP ligand. Synthesis and crystal structure of uranyl(VI) compounds with CyMe4BTBP Berthet, Jean-Claude; Thuéry, P.; Foreman, M. R. S. Radiochimica Acta, Vol. 96, Issue 4-5 https://doi.org/10.1524/ract.2008.1478	journal	January 2008

Cited By (8)

Syntheses, crystal structures, adsorption properties and visible photocatalytic activities of highly stable Pb-based coordination polymers constructed by 2-(2-carboxyphenyl)imidazo(4,5- f )-(1,10)phenanthroline and bridging linkers Li, Zhi-Min; Qiao, Yu; Liu, Chun-Bo Dalton Transactions, Vol. 47, Issue 23 https://doi.org/10.1039/c8dt00997j	journal	January 2018
Monomeric thorium chalcogenolates with bipyridine and terpyridine ligands Ringgold, Marissa; Wu, Wen; Stuber, Matthew Dalton Transactions, Vol. 47, Issue 41 https://doi.org/10.1039/c8dt02543f	journal	January 2018
The structural evolution and tunable photoluminescence of f-element bearing coordination polymers of the 2,4,6-tri-α-pyridyl-1,3,5-triazine ligand Yue, Zenghui; Lu, Huangjie; Li, Zijian CrystEngComm, Vol. 21, Issue 34 https://doi.org/10.1039/c9ce00867e	journal	January 2019
Synthesis and crystal structures of two new uranyl coordination compounds obtained in aqueous solutions of 1-butyl-2,3-dimethylimidazolium chloride Wang, Fangyuan; Mei, Lei; Shi, Weiqun Journal of Coordination Chemistry, Vol. 71, Issue 15 https://doi.org/10.1080/00958972.2018.1479034	journal	May 2018
Crystal structure of a hydroxo-bridged dimeric uranyl complex with a 2,2′:6′,2″-terpyridine ligand Lyczko, K.; Steczek, L. Journal of Structural Chemistry, Vol. 58, Issue 1 https://doi.org/10.1134/s0022476617010152	journal	January 2017
Crystal structure of a hydroxo-bridged dimeric uranyl complex with a 2,2':6',2-terpyridine ligand Lyczko, K.; Stecze, L. Журнал структурной химии, Issue 1 https://doi.org/10.15372/jsc20170115	journal	January 2017
Synthesis and crystal structures of two new uranyl coordination compounds obtained in aqueous solutions of 1-butyl-2,3-dimethylimidazolium chloride Wang, Fangyuan; Mei, Lei; Shi, Weiqun Taylor & Francis https://doi.org/10.6084/m9.figshare.6339524	text	January 2018
Synthesis and crystal structures of two new uranyl coordination compounds obtained in aqueous solutions of 1-butyl-2,3-dimethylimidazolium chloride Wang, Fangyuan; Mei, Lei; Shi, Weiqun Taylor & Francis https://doi.org/10.6084/m9.figshare.6339524.v1	text	January 2018

Similar Records

Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers

Journal Article · Fri May 29 00:00:00 EDT 2015 · Crystal Growth and Design · OSTI ID:1370892

Synthesis and characterization of rhodium complexes containing 2,4,6-tris(2-pyridyl)-1,3,5-triazine and its metal-promoted hydrolytic products: Potential uses of the new complexes in electrocatalytic reduction of carbon dioxide

Journal Article · Sun Nov 01 23:00:00 EST 1998 · Inorganic Chemistry · OSTI ID:316203

Three Pb{sup II} coordination polymers based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid: Syntheses, crystal structures, and fluorescent properties

Journal Article · Thu Aug 15 00:00:00 EDT 2013 · Journal of Solid State Chemistry · OSTI ID:22274054

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
materials and chemistry by design
nuclear (including radiation effects)
synthesis (novel materials)
synthesis (self-assembly)

CCDC 1400915: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Pope, Simon J. A.; Cahill, Christopher L. https://doi.org/10.5517/cc1j0rt3 The current record is supplemented by this dataset	dataset	January 2015
CCDC 1400916: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Pope, Simon J. A.; Cahill, Christopher L. https://doi.org/10.5517/cc1j0rv4 The current record is supplemented by this dataset	dataset	January 2015
CCDC 1400917: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Pope, Simon J. A.; Cahill, Christopher L. https://doi.org/10.5517/cc1j0rw5 The current record is supplemented by this dataset	dataset	January 2015
CCDC 1400918: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Pope, Simon J. A.; Cahill, Christopher L. https://doi.org/10.5517/cc1j0rx6 The current record is supplemented by this dataset	dataset	January 2015
CCDC 1400919: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Pope, Simon J. A.; Cahill, Christopher L. https://doi.org/10.5517/cc1j0ry7 The current record is supplemented by this dataset	dataset	January 2015
CCDC 1400920: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Pope, Simon J. A.; Cahill, Christopher L. https://doi.org/10.5517/cc1j0rz8 The current record is supplemented by this dataset	dataset	January 2015
CCDC 1400921: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Pope, Simon J. A.; Cahill, Christopher L. https://doi.org/10.5517/cc1j0s0b The current record is supplemented by this dataset	dataset	January 2015

Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands

Citation Formats

References (67)

Cited By (8)

Linked Research (7)

Similar Records

Related Subjects