Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers

Thangavelu, Sonia G.; Butcher, Ray J.; Cahill, Christopher L.

doi:10.1021/acs.cgd.5b00549

Title: Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers

Journal Article · Fri May 29 00:00:00 EDT 2015 · Crystal Growth and Design

DOI:https://doi.org/10.1021/acs.cgd.5b00549· OSTI ID:1370892

Thangavelu, Sonia G. ^[1]; Butcher, Ray J. ^[2]; Cahill, Christopher L. ^[1]

The George Washington Univ., Washington D.C. (United States)
Howard Univ., Washington D.C. (United States)

Thiophene 2,5-dicarboxylic acid (TDC) was reacted with uranyl acetate dihydrate and one (or none) of six N-donor chelating ligands (2,2'-bipyridine (BPY), 4,4'-dimethyl-2,2'-bipyridine (4-MeBPY), 5,5'-dimethyl-2,2'-bipyridine (5-MeBPY), 6,6'-dimethyl-2,2'-bipyridine (6-MeBPY), 4,4',6,6'-tetramethyl-2,2'-bipyridine (4,6-MeBPY), and tetrakis(2-pyridyl)pyrazine (TPPZ) to result in the crystallization of seven uranyl coordination polymers, which were characterized by their crystal structures and luminescence properties. The seven coordination polymers, Na₂[(UO₂)₂(C₆H₂O₄S)₃]·₄H₂O (1), [(UO₂)₄(C₆H₂O₄S)₅(C₁₀H₈N₂)₂]·C₁₀H₁₀N₂·3H₂O (2), [(UO₂)(C₆H₂O₄S)(C₁₂H₁₂N₃)] (3), [(UO₂)(C₆H₂O₄S)(C₁₂H₁₂N₃)]·H₂O (4), [(UO₂)₂(C₆H₂O₄S)₃]·(C₁₂H₁₄N₂)·5H₂O (5), [(UO₂)₃(CH₃CO₂)(C₆H₂O₄S)₄](C₁₄H₁₇N₂)₃·(C₁₄H₁₆N₂)·H₂O (6), and [(UO₂)₂(C₆H₂O₄S)₃](C₂₄H₁₈N₆) (7), consist of either uranyl hexagonal bipyramidal or pentagonal bipyramidal coordination geometries. In all structures, structural variations in the local and global structures of 1–7 are influenced by the positions (or number) of methyl groups or pyridyl rings on the N-donor species, thus resulting in a wide diversity of structures ranging from single chains, double chains, or 2-D sheets. Direct coordination of N-donor ligands to uranyl centers is observed in the chain structures of 2–4 using BPY, 4-MeBPY, and 5-MeBPY, whereas the N-donor species participate as guests (as either neutral or charge balancing species) in the chain and sheet structures of 5–7 using 6-MeBPY, 4,6-MeBPY, and TPPZ, respectively. Compound 1 is the only structure that does not contain any N-donor ligands and thus crystallizes as a 2-D interpenetrating sheet. The luminescent properties of 1–7 are influenced by the direct coordination or noncoordination of N-donor species to uranyl centers. Compounds 2–4 exhibit typical UO₂²⁺ emission upon direct coordination of N-donors, but its absence is observed in 1, 5, 6, and 7, when N-donor species participate as guest molecules. These results suggest that direct coordination of N-donor ligands participate as chromophores, thus resulting in possible UO₂²⁺ sensitization. Finally, the lack of emission in 1, 5, 6, and 7 may be explained by the extended conjugation of the TDC ligands within their structures.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001089

OSTI ID:: 1370892

Journal Information:: Crystal Growth and Design, Vol. 15, Issue 7; Related Information: MSA partners with University of Notre Dame (lead); University of California, Davis; Florida State University; George Washington University; University of Michigan; University of Minnesota; Oak Ridge National Laboratory; Oregon state University; Rensselaer Polytechnic Institute; Savannah River National Laboratory; ISSN 1528-7483

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 42 works

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References (81)

Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds Wang, Kai-Xue; Chen, Jie-Sheng Accounts of Chemical Research, Vol. 44, Issue 7 https://doi.org/10.1021/ar200042t	journal	July 2011
Hydrothermal Synthesis of Uranyl Squarates and Squarate-Oxalates: Hydrolysis Trends and in Situ Oxalate Formation Rowland, Clare E.; Cahill, Christopher L. Inorganic Chemistry, Vol. 49, Issue 14 https://doi.org/10.1021/ic100887c	journal	July 2010
Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products Knope, Karah E.; Soderholm, L. Chemical Reviews, Vol. 113, Issue 2 https://doi.org/10.1021/cr300212f	journal	October 2012
Environmental Speciation of Actinides Maher, Kate; Bargar, John R.; Brown, Gordon E. Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic301686d	journal	June 2012
Solution coordination chemistry of actinides: Thermodynamics, structure and reaction mechanisms Szabo, Z.; Toraishi, T.; Vallet, V. Coordination Chemistry Reviews, Vol. 250, Issue 7-8 https://doi.org/10.1016/j.ccr.2005.10.005	journal	April 2006
Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures Andrews, Michael B.; Cahill, Christopher L. Chemical Reviews, Vol. 113, Issue 2 https://doi.org/10.1021/cr300202a	journal	August 2012
The crystal chemistry of uranium carboxylates Loiseau, Thierry; Mihalcea, Ionut; Henry, Natacha Coordination Chemistry Reviews, Vol. 266-267 https://doi.org/10.1016/j.ccr.2013.08.038	journal	May 2014
Uranyl Ion Complexes with all- cis -1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies Thuéry, Pierre; Harrowfield, Jack Crystal Growth & Design, Vol. 14, Issue 8 https://doi.org/10.1021/cg500828s	journal	July 2014
Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules: Crystal Chemistry of Uranyl Carboxylate Coordination Networks Mihalcea, Ionut; Henry, Natacha; Loiseau, Thierry European Journal of Inorganic Chemistry, Vol. 2014, Issue 8 https://doi.org/10.1002/ejic.201301575	journal	February 2014
(6,3)-Honeycomb Structures of Uranium(VI) Benzenedicarboxylate Derivatives: The Use of Noncovalent Interactions to Prevent Interpenetration Go, Yong Bok; Wang, Xiqu; Jacobson, Allan J. Inorganic Chemistry, Vol. 46, Issue 16 https://doi.org/10.1021/ic700693f	journal	August 2007
Structures and luminescent properties of new uranyl-based hybrid materials Severance, Rachel C.; Vaughn, Shae Anne; Smith, Mark D. Solid State Sciences, Vol. 13, Issue 6 https://doi.org/10.1016/j.solidstatesciences.2011.04.004	journal	June 2011
Supramolecular architectures of two novel organic–inorganic hybrid materials containing identical monomeric uranyl units Jenniefer, Samson Jegan; Muthiah, Packianathan Thomas Acta Crystallographica Section C Crystal Structure Communications, Vol. 67, Issue 3 https://doi.org/10.1107/S0108270111004227	journal	February 2011
Synthesis, crystal structure and spectroscopic studies of some organic/inorganic hybrid materials containing isostructural monomeric uranyl complexes bridged by bipyridyl typed ligands Jennifer, Samson Jegan; Muthiah, Packianathan Thomas Inorganica Chimica Acta, Vol. 416 https://doi.org/10.1016/j.ica.2014.03.014	journal	May 2014
Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent Thuéry, Pierre; Harrowfield, Jack Crystal Growth & Design, Vol. 14, Issue 3 https://doi.org/10.1021/cg4018163	journal	January 2014
Complexation of actinides(VI) with furan-2-carboxylic and thiophene-2-carboxylic acids in aqueous solutions and synthesis of crystalline compounds Fedoseev, A. M.; Grigor’ev, M. S.; Yusov, A. B. Radiochemistry, Vol. 54, Issue 5 https://doi.org/10.1134/S1066362212050037	journal	September 2012
Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds Liao, Zuo-Lei; Li, Guo-Dong; Bi, Ming-Hui Inorganic Chemistry, Vol. 47, Issue 11 https://doi.org/10.1021/ic800109y	journal	June 2008
Synthesis, structure characterization and photocatalytic properties of two new uranyl naphthalene-dicarboxylate coordination polymer compounds Xia, Yin; Wang, Kai-Xue; Chen, Jie-Sheng Inorganic Chemistry Communications, Vol. 13, Issue 12 https://doi.org/10.1016/j.inoche.2010.09.008	journal	December 2010
Structural Variation within Homometallic Uranium(VI) Carboxyphosphonates: In Situ Ligand Synthesis, Directed Assembly, Metal−Ligand Coordination and Hydrogen Bonding Knope, Karah E.; Cahill, Christopher L. Inorganic Chemistry, Vol. 47, Issue 17 https://doi.org/10.1021/ic800683m	journal	September 2008
Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines Knope, Karah E.; Cahill, Christopher L. Inorganic Chemistry, Vol. 48, Issue 14 https://doi.org/10.1021/ic9007735	journal	July 2009
Ionothermal and Hydrothermal Flux Syntheses of Five New Uranyl Phosphonates Parker, T. Gannon; Cross, Justin N.; Polinski, Matthew J. Crystal Growth & Design, Vol. 14, Issue 1 https://doi.org/10.1021/cg401435w	journal	December 2013
Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies Yang, Weiting; Tian, Tao; Wu, Hong-Yue Inorganic Chemistry, Vol. 52, Issue 5 https://doi.org/10.1021/ic302847g	journal	February 2013
Syntheses, structures and luminescent properties of two organic templated uranyl phosphonates Wu, Hong-Yue; Ma, Yu-Qin; Zhang, Xiuwu Inorganic Chemistry Communications, Vol. 34 https://doi.org/10.1016/j.inoche.2013.05.004	journal	August 2013
Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands Yang, Weiting; Yi, Fei-Yan; Tian, Tao Crystal Growth & Design, Vol. 14, Issue 3 https://doi.org/10.1021/cg401850v	journal	January 2014
Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril Thuéry, Pierre Crystal Growth & Design, Vol. 11, Issue 12 https://doi.org/10.1021/cg201253z	journal	December 2011
Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate-Containing Ligands: Uranyl and Thorium Complexes with Sulfonate-Containing Ligands Thuéry, Pierre European Journal of Inorganic Chemistry, Vol. 2014, Issue 1 https://doi.org/10.1002/ejic.201301258	journal	November 2013
One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids Thuéry, Pierre CrystEngComm, Vol. 15, Issue 13 https://doi.org/10.1039/c3ce26996e	journal	January 2013
Structural Complexity of Barium Uranyl Arsenates: Synthesis, Structure, and Topology of Ba ₄ [(UO ₂ ) ₂ (As ₂ O ₇ ) ₃ ], Ba ₃ [(UO ₂ ) ₂ (AsO ₄ ) ₂ (As ₂ O ₇ )], and Ba ₅ Ca[(UO ₂ ) ₈ (AsO ₄ ) ₄ O ₈ ] Alekseev, Evgeny V.; Krivovichev, Sergey V.; Depmeier, Wulf Crystal Growth & Design, Vol. 11, Issue 7 https://doi.org/10.1021/cg200592s	journal	July 2011
Novel layered uranyl arsenates, Ag6[(UO2)2(As2O7)(As4O13)] and AI6[(UO2)2(AsO4)2(As2O7)] (AI–Ag and Na): first observation of a linear As4O136− anion and structure type evolution Alekseev, Evgeny V.; Krivovichev, Sergey V.; Depmeier, Wulf Journal of Materials Chemistry, Vol. 19, Issue 17 https://doi.org/10.1039/b818757f	journal	January 2009
Crystal structure of [CH3NH3][(UO2)(H2AsO4)3] Alekseev, E. V.; Krivovichev, S. V.; Depmeier, W. Radiochemistry, Vol. 50, Issue 5 https://doi.org/10.1134/S1066362208050019	journal	October 2008
High-Temperature, High-Pressure Hydrothermal Synthesis, Characterization, and Structural Relationships of Layered Uranyl Arsenates Liu, Hsin-Kuan; Ramachandran, Eswaran; Chen, Yi-Hsin Inorganic Chemistry, Vol. 53, Issue 17 https://doi.org/10.1021/ic501091g	journal	August 2014
Uranyl Ion Complexes with Cucurbit[ n ]urils ( n = 6, 7, and 8): A New Family of Uranyl-Organic Frameworks Thuéry, Pierre Crystal Growth & Design, Vol. 8, Issue 11 https://doi.org/10.1021/cg800594m	journal	November 2008
Uranyl Ion Complexes with Cucurbit[5]uril: from Molecular Capsules to Uranyl-Organic Frameworks Crystal Growth & Design, Vol. 9, Issue 2 https://doi.org/10.1021/cg8011603	journal	February 2009
Uranyl Ion Complexation by Cucurbiturils in the Presence of Perrhenic, Phosphoric, or Polycarboxylic Acids. Novel Mixed-Ligand Uranyl−Organic Frameworks Thuéry, Pierre; Masci, Bernardo Crystal Growth & Design, Vol. 10, Issue 2 https://doi.org/10.1021/cg901121c	journal	February 2010
Uranyl ion complexes of cucurbit[7]uril with zero-, one- and two-dimensionality Thuéry, Pierre CrystEngComm, Vol. 11, Issue 6 https://doi.org/10.1039/b822872h	journal	January 2009
Giant regular polyhedra from calixarene carboxylates and uranyl Pasquale, Sara; Sattin, Sara; Escudero-Adán, Eduardo C. Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1793	journal	January 2012
Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids Yang, Weiting; Dang, Song; Wang, Hao Inorganic Chemistry, Vol. 52, Issue 21 https://doi.org/10.1021/ic4012444	journal	October 2013
2,2′-Bipyridine and 1,10-Phenanthroline as Coligands or Structure-Directing Agents in Uranyl-Organic Assemblies with Polycarboxylic Acids Thuéry, Pierre European Journal of Inorganic Chemistry, Vol. 2013, Issue 26 https://doi.org/10.1002/ejic.201300502	journal	July 2013
Sterically Congested Uranyl Complexes with Seven-Coordination of the UO ₂ Unit: the Peculiar Ligation Mode of Nitrate in [UO ₂ (NO ₃ ) ₂ (Rbtp)] Complexes ^† Berthet, Jean-Claude; Thuéry, Pierre; Dognon, Jean-Pierre Inorganic Chemistry, Vol. 47, Issue 15 https://doi.org/10.1021/ic8004486	journal	August 2008
Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence Kerr, Andrew T.; Cahill, Christopher L. Crystal Growth & Design, Vol. 14, Issue 4 https://doi.org/10.1021/cg500050q	journal	March 2014
CuPYDC Metalloligands and Postsynthetic Rearrangement/Metalation as Routes to Bimetallic Uranyl Containing Hybrid Materials: Syntheses, Structures, and Fluorescence Kerr, Andrew T.; Cahill, Christopher L. Crystal Growth & Design, Vol. 14, Issue 8 https://doi.org/10.1021/cg5007132	journal	July 2014
Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties Kerr, Andrew T.; Kumalah, Sayon A.; Holman, K. T. Journal of Inorganic and Organometallic Polymers and Materials, Vol. 24, Issue 1 https://doi.org/10.1007/s10904-013-9980-0	journal	October 2013
Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers Thangavelu, Sonia G.; Andrews, Michael B.; Pope, Simon J. A. Inorganic Chemistry, Vol. 52, Issue 4 https://doi.org/10.1021/ic3024698	journal	January 2013
A novel coordination geometry for the uranyl ion. Rhombohedral uranium environment in [UO2(OTf)2(bpy)2] and [UO2(phen)3][OTf]2 Berthet, Jean-Claude; Nierlich, Martine; Ephritikhine, Michel Chemical Communications, Issue 14 https://doi.org/10.1039/b303255h	journal	January 2003
Oxygen and nitrogen Lewis base adducts of [UO2(OTf)2]. Crystal structures of polypyridine complexes with out-of-plane uranyl equatorial coordination Berthet, Jean-Claude; Nierlich, Martine; Ephritikhine, M. Dalton Transactions, Issue 17 https://doi.org/10.1039/b405287k	journal	January 2004
Uranium complexes of multidentate N-donor ligands Sessler, J.; Melfi, P.; Pantos, G. Coordination Chemistry Reviews, Vol. 250, Issue 7-8 https://doi.org/10.1016/j.ccr.2005.10.007	journal	April 2006
Crystal structures of 2,2′:6′,2″-terpyridine uranyl chlorides molecular assemblies and their luminescence signatures Lhoste, Jérôme; Henry, Natacha; Loiseau, Thierry Polyhedron, Vol. 50, Issue 1 https://doi.org/10.1016/j.poly.2012.11.026	journal	February 2013
Crystal structure of two new molecular adducts of uranyl nitrate with 2,2′-6,2″-terpyridine Charushnikova, I. A.; Den Auwer, C. Russian Journal of Coordination Chemistry, Vol. 33, Issue 1 https://doi.org/10.1134/S1070328407010083	journal	January 2007
Crystal Structures of Molecular Adducts between Uranyl Nitrate and 2,2 : 6 ,2 -Terpyridine or 2,2′-Bipyridyl Charushnikova, I. A.; Den Auwer, C. Russian Journal of Coordination Chemistry, Vol. 30, Issue 7 https://doi.org/10.1023/B:RUCO.0000034793.14795.72	journal	July 2004
Crystal Engineering with the Uranyl Cation III. Mixed Aliphatic Dicarboxylate/Aromatic Dipyridyl Coordination Polymers: Synthesis, Structures, and Speciation Kerr, Andrew T.; Cahill, Christopher L. Crystal Growth & Design, Vol. 11, Issue 12 https://doi.org/10.1021/cg2011869	journal	December 2011
Solid-State Luminescence and π-Stacking in Crystalline Uranyl Dipicolinates Harrowfield, Jack M.; Lugan, Noël; Shahverdizadeh, Gholam H. European Journal of Inorganic Chemistry, Vol. 2006, Issue 2 https://doi.org/10.1002/ejic.200500671	journal	January 2006
Crystal Engineering with the Uranyl Cation II. Mixed Aliphatic Carboxylate/Aromatic Pyridyl Coordination Polymers: Synthesis, Crystal Structures, and Sensitized Luminescence Borkowski, Lauren A.; Cahill, Christopher L. Crystal Growth & Design, Vol. 6, Issue 10 https://doi.org/10.1021/cg060330g	journal	October 2006
Syntheses, structures and fluorescent properties of two novel coordination polymers in the U–Cu–H ₃ pdc system Frisch, Mark; Cahill, Christopher L. Dalton Trans., Issue 8 https://doi.org/10.1039/B500127G	journal	January 2005
Synthesis, structure and fluorescent studies of novel uranium coordination polymers in the pyridinedicarboxylic acid system Frisch, Mark; Cahill, Christopher L. Dalton Transactions, Issue 39 https://doi.org/10.1039/b608187h	journal	January 2006
Uranyl Sensitization of Samarium(III) Luminescence in a Two-Dimensional Coordination Polymer Knope, Karah E.; de Lill, Daniel T.; Rowland, Clare E. Inorganic Chemistry, Vol. 51, Issue 1 https://doi.org/10.1021/ic201450e	journal	December 2011
Increased Antenna Effect of the Lanthanide Complexes by Control of a Number of Terdentate N-Donor Pyridine Ligands Yip, Yuk-Wang; Wen, Hongli; Wong, Wing-Tak Inorganic Chemistry, Vol. 51, Issue 13 https://doi.org/10.1021/ic300916e	journal	June 2012
Para-Derivatized Pybox Ligands As Sensitizers in Highly Luminescent Ln(III) Complexes de Bettencourt-Dias, Ana; Barber, Patrick S.; Viswanathan, Subha Inorganic Chemistry, Vol. 49, Issue 19 https://doi.org/10.1021/ic101034y	journal	October 2010
Luminescent Functional Metal–Organic Frameworks Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200101d	journal	June 2011
Luminescent metal–organic frameworks Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K. Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b802352m	journal	January 2009
Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye Li, Hao-Hong; Zeng, Xian-Hua; Wu, Hong-Yan Crystal Growth & Design, Vol. 15, Issue 1 https://doi.org/10.1021/cg501252x	journal	December 2014
Coordination behaviour and network formation with 4,4′,6,6′-tetracarboxy-2,2′-bipyridine and 4,4′-dicarboxy-2,2′-bipyridineligands with rare and alkaline earth metals Kelly, Niamh R.; Goetz, Sandrine; Batten, Stuart R. CrystEngComm, Vol. 10, Issue 1 https://doi.org/10.1039/B711469A	journal	January 2008
Crystallography Open Database (COD): an open-access collection of crystal structures and platform for world-wide collaboration Gražulis, Saulius; Daškevič, Adriana; Merkys, Andrius Nucleic Acids Research, Vol. 40, Issue D1 https://doi.org/10.1093/nar/gkr900	journal	November 2011
Completion and refinement of crystal structures with SIR 92 Altomare, A.; Cascarano, G.; Giacovazzo, C. Journal of Applied Crystallography, Vol. 26, Issue 3 https://doi.org/10.1107/S0021889892010331	journal	June 1993
WinGX suite for small-molecule single-crystal crystallography Farrugia, Louis J. Journal of Applied Crystallography, Vol. 32, Issue 4 https://doi.org/10.1107/S0021889899006020	journal	August 1999
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
A critical account on π–π stacking in metal complexes with aromatic nitrogen-containing ligands † Janiak, Christoph Journal of the Chemical Society, Dalton Transactions, Issue 21 https://doi.org/10.1039/b003010o	journal	January 2000
The Cambridge Structural Database: a quarter of a million crystal structures and rising Allen, Frank H. Acta Crystallographica Section B Structural Science, Vol. 58, Issue 3 https://doi.org/10.1107/S0108768102003890	journal	May 2002
Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate Thuéry, Pierre Inorganic Chemistry, Vol. 52, Issue 1 https://doi.org/10.1021/ic3022744	journal	December 2012
A Bond by Any Other Name Desiraju, Gautam R. Angewandte Chemie International Edition, Vol. 50, Issue 1 https://doi.org/10.1002/anie.201002960	journal	October 2010
Hydrogen Bridges in Crystal Engineering: Interactions without Borders Desiraju, Gautam R. Accounts of Chemical Research, Vol. 35, Issue 7 https://doi.org/10.1021/ar010054t	journal	July 2002
New Conformations and Binding Modes in Halogen-Bonded and Ionic Complexes of 2,3,5,6-Tetra(2‘-pyridyl)pyrazine Padgett, Clifford W.; Walsh, Rosa D.; Drake, Gregory W. Crystal Growth & Design, Vol. 5, Issue 2 https://doi.org/10.1021/cg049730z	journal	March 2005
Conformations and Binding Modes of 2,3,5,6-Tetra(2‘-pyridyl)pyrazine Padgett, Clifford W.; Pennington, William T.; Hanks, Timothy W. Crystal Growth & Design, Vol. 5, Issue 2 https://doi.org/10.1021/cg049731r	journal	March 2005
Electronic Structure and Bonding in Actinyl Ions and their Analogs Denning, Robert G. The Journal of Physical Chemistry A, Vol. 111, Issue 20 https://doi.org/10.1021/jp071061n	journal	May 2007
Developments in the photophysics and photochemistry of actinide ions and their coordination compounds Natrajan, Louise S. Coordination Chemistry Reviews, Vol. 256, Issue 15-16 https://doi.org/10.1016/j.ccr.2012.03.029	journal	August 2012
Chiral one- to three-dimensional uranyl–organic assemblies from (1R,3S)-(+)-camphoric acid Thuéry, Pierre; Harrowfield, Jack CrystEngComm, Vol. 16, Issue 14 https://doi.org/10.1039/c3ce42613k	journal	January 2014
Study of uranyl(VI) malonate complexation by time resolved laser-induced fluorescence spectroscopy (TRLFS) Brachmann, A.; Geipel, Gerhard; Bernhard, G. Radiochimica Acta, Vol. 90, Issue 3 https://doi.org/10.1524/ract.2002.90.3_2002.147	journal	January 2002
Uranium(VI) speciation by spectroscopy Meinrath, G. Journal of Radioanalytical and Nuclear Chemistry, Vol. 224, Issue 1-2 https://doi.org/10.1007/BF02034623	journal	October 1997
Charge Transfer Vibronic Transitions in Uranyl Tetrachloride Compounds Liu, Guokui; Deifel, Nicholas P.; Cahill, Christopher L. The Journal of Physical Chemistry A, Vol. 116, Issue 2 https://doi.org/10.1021/jp210046j	journal	January 2012
Theoretical analysis and quantification of the absorption spectra of uranyl complexes with structurally-related tridentate ligands Liu, Guokui; Rao, Linfeng; Tian, Guoxin Physical Chemistry Chemical Physics, Vol. 15, Issue 40 https://doi.org/10.1039/c3cp52900b	journal	January 2013
Anharmonic charge transfer vibronic states and luminescence dynamics of uranyl compounds Liu, G. K.; Vikhnin, V. S. Chemical Physics Letters, Vol. 437, Issue 1-3 https://doi.org/10.1016/j.cplett.2007.02.006	journal	March 2007
The effects of conformation and coordination to zinc(II) ions on the luminescence properties of 2,2′-bipyridine, methyl-substituted 2,2′-bipyridines and 2,2′-biquinoline Yagi, M.; Kaneshima, T.; Wada, Y. Journal of Photochemistry and Photobiology A: Chemistry, Vol. 84, Issue 1 https://doi.org/10.1016/1010-6030(94)03842-2	journal	November 1994
Lanthanide luminescence for functional materials and bio-sciences Eliseeva, Svetlana V.; Bünzli, Jean-Claude G. Chem. Soc. Rev., Vol. 39, Issue 1 https://doi.org/10.1039/B905604C	journal	January 2010

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Crystal structure and fluorescence properties of catena -poly[[(2,2′-bi-1 H -imidazole-κ ² N , N ′)cadmium]-di-μ-chlorido] Liu, Yang; Liu, Hai-Hui Acta Crystallographica Section E Crystallographic Communications, Vol. 72, Issue 10 https://doi.org/10.1107/s2056989016013736	journal	September 2016

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Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
nuclear (including radiation effects)
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)

CCDC 1060072: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Butcher, Ray J.; Cahill, Christopher L. https://doi.org/10.5517/cc14l2wp The current record is supplemented by this dataset	dataset	January 2015
CCDC 1060073: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Butcher, Ray J.; Cahill, Christopher L. https://doi.org/10.5517/cc14l2xq The current record is supplemented by this dataset	dataset	January 2015
CCDC 1060074: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Butcher, Ray J.; Cahill, Christopher L. https://doi.org/10.5517/cc14l2yr The current record is supplemented by this dataset	dataset	January 2015
CCDC 1060075: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Butcher, Ray J.; Cahill, Christopher L. https://doi.org/10.5517/cc14l2zs The current record is supplemented by this dataset	dataset	January 2015
CCDC 1060076: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Butcher, Ray J.; Cahill, Christopher L. https://doi.org/10.5517/cc14l30v The current record is supplemented by this dataset	dataset	January 2015
CCDC 1060077: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Butcher, Ray J.; Cahill, Christopher L. https://doi.org/10.5517/cc14l31w The current record is supplemented by this dataset	dataset	January 2015
CCDC 1060078: Experimental Crystal Structure Determination Thangavelu, Sonia G.; Butcher, Ray J.; Cahill, Christopher L. https://doi.org/10.5517/cc14l32x The current record is supplemented by this dataset	dataset	January 2015