Directed Self-Assembly of Hierarchical Supramolecular Block Copolymer Thin Films on Chemical Patterns

Wu, Guang-Peng; Liu, Xiaoying; Chen, Xuanxuan; Suh, Hyo Seon; Li, Xiao; Ren, Jiaxing; Arges, Christopher G.; Li, Faxue; Jiang, Zhang; Nealey, Paul F.

doi:10.1002/admi.201600048

Title: Directed Self-Assembly of Hierarchical Supramolecular Block Copolymer Thin Films on Chemical Patterns

Journal Article · Fri Mar 18 00:00:00 EDT 2016 · Advanced Materials Interfaces

DOI:https://doi.org/10.1002/admi.201600048· OSTI ID:1376725

Wu, Guang-Peng ^[1]; Liu, Xiaoying ^[2]; Chen, Xuanxuan ^[2]; Suh, Hyo Seon ^[3]; Li, Xiao ^[2]; Ren, Jiaxing ^[2]; Arges, Christopher G. ^[3]; Li, Faxue ^[2]; Jiang, Zhang ^[4]; Nealey, Paul F. ^[5]

MOE Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027 China
Institute for Molecular Engineering, University of Chicago, Chicago IL 60637 USA
Materials Science Division, Argonne National Laboratory, 9700 S. Cass Avenue Argonne IL 60439 USA
Advanced Photon Source, Argonne National Laboratory, 9700 S. Cass Avenue Argonne IL 60439 USA
Institute for Molecular Engineering, University of Chicago, Chicago IL 60637 USA; Materials Science Division, Argonne National Laboratory, 9700 S. Cass Avenue Argonne IL 60439 USA

A long-range ordered lamellae-within-lamellae hierarchical structure is reported for the first time through the directed self-assembly of supramolecular polymer-surfactant thin films on chemical patterns with density multiplication. The coassembly of supramolecular system with gold nanoparticles is further achieved to create a hybrid material with well-organized nanoparticle arrays, expanding the palette of morphologies and structures available for nanoscale fabrication.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science - Office of Basic Energy Sciences - Materials Sciences and Engineering Division; USDOE Office of Science - Office of Basic Energy Sciences - Scientific User Facilities Division

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1376725

Journal Information:: Advanced Materials Interfaces, Vol. 3, Issue 13; ISSN 2196-7350

Publisher:: Wiley-VCH

Country of Publication:: United States

Language:: English

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