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Micromold methods for fabricating perforated substrates and for preparing solid polymer electrolyte composite membranes

Patent ·
OSTI ID:1374428

In polymer electrolyte membrane (PEM) fuel cells and electrolyzes, attaining and maintaining high membrane conductivity and durability is crucial for performance and efficiency. The use of low equivalent weight (EW) perfluorinated ionomers is one of the few options available to improve membrane conductivity. However, excessive dimensional changes of low EW ionomers upon application of wet/dry or freeze/thaw cycles yield catastrophic losses in membrane integrity. Incorporation of ionomers within porous, dimensionally-stable perforated polymer electrolyte membrane substrates provides improved PEM performance and longevity. The present invention provides novel methods using micromolds to fabricate the perforated polymer electrolyte membrane substrates. These novel methods using micromolds create uniform and well-defined pore structures. In addition, these novel methods using micromolds described herein may be used in batch or continuous processing.

Research Organization:
GINER, INC. Newton, MA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
EE0004533
Assignee:
GINER, INC.
Patent Number(s):
9,728,802
Application Number:
14/120,353
OSTI ID:
1374428
Country of Publication:
United States
Language:
English

References (3)

Perforated polymer membranes fabricated by nanoimprint journal April 2006
Polymer through-hole membrane fabricated by nanoimprinting using metal molds with high aspect ratios
  • Yanagishita, Takashi; Nishio, Kazuyuki; Masuda, Hideki
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 25, Issue 4, Article No. L35 https://doi.org/10.1116/1.2753847
journal January 2007
Modified imprinting process using hollow microneedle array for forming through holes in polymers journal August 2011

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